Bis[tris(4-(1H,1H,2H,2H-perfluorodecyl)phenyl)phosphine]palladium(II) dichloride
Empirical Formula (Hill Notation): | C96H48Cl2F102P2Pd |
CAS Number: | 326475-46-1 |
Molecular Weight: | 3378.52 |
MDL number: | MFCD03453279 |
PubChem Substance ID: | 329770462 |
NACRES: | NA.21 |
Кат. номер |
95447-VAR-F |
95447-500MG-F |
95447-100MG-F |
contains up to 20% Tri(4-(1
H,1
H,2
H,2
H-perfluorodecyl)phenyl)phosphine oxide
Packaging
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
Catalyst for Stille and Suzuki couplings in Fluorous Biphase Systems (FBS)
Perfluoro-tagged Pd complexes as catalysts for Stille couplings in a fluorous biphasic system, palladium-catalyzed Suzuki couplings.
Quality Level | 100, |
grade | technical |
assay | 80% (AAS) |
reaction suitability | reagent type: catalyst core: palladium |
mp | 175-180 °C |
SMILES string | Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc1ccc(cc1)P(c2ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc2)c3ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc3.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc4ccc(cc4)P(c5ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc5)c6ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc6 |
InChI | 1S/2C48H24F51P.2ClH.Pd/c2*49-25(50,28(55,56)31(61,62)34(67,68)37(73,74)40(79,80)43(85,86)46(91,92)93)16-13-19-1-7-22(8-2-19)100(23-9-3-20(4-10-23)14-17-26(51,52)29(57,58)32(63,64)35(69,70)38(75,76)41(81,82)44(87,88)47(94,95)96)24-11-5-21(6-12-24)15-18-27(53,54)30(59,60)33(65,66)36(71,72)39(77,78)42(83,84)45(89,90)48(97,98)99;;;/h2*1-12H,13-18H2;2*1H;/q;;;;+2/p-2 |
InChI key | KONKDVXTNQEYIF-UHFFFAOYSA-L |
pictograms | GHS05,GHS07,GHS08 |
signalword | Danger |
hcodes | H302 + H332 - H318 - H351 - H360D - H362 - H372 |
pcodes | P260 - P263 - P280 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313 |
Target Organs | Liver |
Personal Protective Equipment | Eyeshields,, Gloves,, type N95 (US), |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point F | Not applicable |
Flash Point C | Not applicable |