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Transition Metal Catalysts

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48

Ruthenium(III) iodide hydrate

Empirical Formula (Hill Notation):	H₂I₃ORu
Linear Formula:	RuI₃· H₂O
CAS Number:	208346-20-7
Molecular Weight:	499.80
EC Number:	237-664-8
MDL number:	MFCD02683102
PubChem Substance ID:	24868466
NACRES:	NA.23

form	powder
Quality Level	100,
reaction suitability	reagent type: catalyst core: ruthenium
mp	590 °C (dec.) (lit.)
storage temp.	2-8°C
SMILES string	O.I[Ru](I)I
InChI	1S/3HI.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
Inchi Key	USLIQGJRXPCWLY-UHFFFAOYSA-K

Safety Information

pictograms	GHS07,GHS08
signalword	Danger
hcodes	H315 - H319 - H335 - H360
pcodes	P201 - P302 + P352 - P305 + P351 + P338 - P308 + P313
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Salicylaldehyde thiosemicarbazone palladium(II) chloride

Empirical Formula (Hill Notation):	C₈H₈ClN₃OPdS
CAS Number:	219954-63-9
Molecular Weight:	336.11
PubChem Substance ID:	329760580

1 g in glass bottle
250 mg in glass bottle

Application

Catalyst used for Suzuki Coupling under aerobic conditions

Параметры

assay	97%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	>300 °C
SMILES string	NC(N)=S.Cl[Pd]1Oc2ccccc2C=N1
InChI	1S/C7H6NO.CH4N2S.ClH.Pd/c8-5-6-3-1-2-4-7(6)9;2-1(3)4;;/h1-5,9H;(H4,2,3,4);1H;/q-1;;;+3/p-2
InChI key	PHBJCXMVMUSQHT-UHFFFAOYSA-L

Safety Information

pictograms	GHS06
signalword	Danger
hcodes	H301-H311-H331
pcodes	P261-P280-P301 + P310-P311
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN 3467 6.1 / PGIII
WGK Germany	3

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Samarium 693731-1EA

Empirical Formula (Hill Notation):	Sm
CAS Number:	7440-19-9
Molecular Weight:	150.36
EC Number:	231-128-7
MDL number:	MFCD00011233
PubChem Substance ID:	329761617
NACRES:	NA.23

Packaging

1 ea in rigid mailer

Application

Used in Physical Vapor Deposition (PVD) processes, including thermal and electron-beam (e-beam) evaporation, for the preparation of thin films.

Quantity

1 ea = 25 x 25 mm

Параметры

assay	99.9% trace rare earth metals basis
form	foil
reaction suitability	reagent type: catalyst core: samarium
resistivity	91.4 µ-cm, 0°C
thickness	1 mm
bp	1794 °C (lit.)
mp	1074 °C (lit.)
density	7.47 g/mL at 25 °C (lit.)
SMILES string	[Sm]
InChI	1S/Sm
InChI key	KZUNJOHGWZRPMI-UHFFFAOYSA-N

Safety Information

pictograms	GHS02
signalword	Warning
hcodes	H228
pcodes	P210
RIDADR	UN2910 Radioactive material, excepted package-limited quantity of material
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Samarium(III) hydroxide hydrate

Empirical Formula (Hill Notation):	H₃O₃Sm · xH₂O
Linear Formula:	Sm(OH)₃ · xH₂O
CAS Number:	20403-06-9
Molecular Weight:	201.38 (anhydrous basis)
EC Number:	243-787-8
MDL number:	MFCD05664263
PubChem Substance ID:	24881174
NACRES:	NA.23

assay	99.99% trace metals basis
form	powder and chunks
reaction suitability	reagent type: catalyst core: samarium
SMILES string	[H]O[H].O[Sm](O)O
InChI	1S/4H2O.Sm/h4*1H2;/q;;;;+3/p-3
InChI key	BJIVKZCSXQGTND-UHFFFAOYSA-K

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Samarium(III) iodide

Empirical Formula (Hill Notation):	I₃Sm
Linear Formula:	SmI₃
CAS Number:	13813-25-7
Molecular Weight:	531.07
EC Number:	237-468-2
MDL number:	MFCD00049541
PubChem Substance ID:	24871932
NACRES:	NA.23

Quality Level	100,
grade	anhydrous
assay	27.7-28.9% (%Sm, EDTA titration)
form	powder
reaction suitability	reagent type: catalyst core: samarium
SMILES string	I[Sm](I)I
InChI	1S/3HI.Sm/h3*1H;/q;;;+3/p-3
InChI key	XQKBFQXWZCFNFF-UHFFFAOYSA-K

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Samarium(III) oxide

Linear Formula:	Sm₂O₃
CAS Number:	12060-58-1
EC Number:	235-043-6
MDL number:	MFCD00011237
PubChem Substance ID:	24882846
NACRES:	NA.23

assay	99% trace metals basis
form	nanopowder
reaction suitability	reagent type: catalyst core: samarium
particle size	<100 nm (BET)
surface area	BET surf. area <10 m²/g
density	8.35 g/mL at 25 °C (lit.)
SMILES string	O=[Sm]O[Sm]=O
InChI	1S/3O.2Sm
InChI key	PRCWVHVINXAFRG-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Samarium(III) oxide dispersion

Empirical Formula (Hill Notation):	O₃Sm₂
Linear Formula:	Sm₂O₃
CAS Number:	12060-58-1
Molecular Weight:	348.72
EC Number:	235-043-6
MDL number:	MFCD00011237
PubChem Substance ID:	24883151
NACRES:	NA.23

form	liquid
composition	H₂O (Solvent)
reaction suitability	reagent type: catalyst core: samarium
particle size	<100 nm (BET), <50 nm (XRD)
SMILES string	O=[Sm]O[Sm]=O
InChI	1S/3O.2Sm
Inchi Key	PRCWVHVINXAFRG-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Samarium(III) phosphate hydrate

Empirical Formula (Hill Notation):	O₄PSm · xH₂O
CAS Number:	13465-57-1
Molecular Weight:	245.33 (anhydrous basis)
EC Number:	236-698-0
MDL number:	MFCD05665148
PubChem Substance ID:	24881173
NACRES:	NA.23

assay	99.99% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: samarium
SMILES string	O.[Sm+3].[O-]P([O-])([O-])=O
InChI	1S/H3O4P.H2O.Sm/c1-5(2,3)4;;/h(H3,1,2,3,4);1H2;/q;;+3/p-3
InChI key	GIUBLDXWAJRBHC-UHFFFAOYSA-K

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Samarium(III) sulfate octahydrate

Empirical Formula (Hill Notation):	O₁₂S₃Sm₂ · 8H₂O
Linear Formula:	Sm₂(SO₄)₃· 8H₂O
CAS Number:	13465-58-2
Molecular Weight:	733.03
MDL number:	MFCD00149862
PubChem Substance ID:	24859542
NACRES:	NA.23

Quality Level	100,
assay	99.9% trace metals basis
form	solid
reaction suitability	reagent type: catalyst core: samarium
impurities	2000 ppm Total rare earth impurities (ICP)
density	2.93 g/mL at 25 °C (lit.)
SMILES string	O.O.O.O.O.O.O.O.[Sm+3].[Sm+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
InChI	1S/3H2O4S.8H2O.2Sm/c31-5(2,3)4;;;;;;;;;;/h3(H2,1,2,3,4);81H2;;/q;;;;;;;;;;;2+3/p-6
InChI key	SICAFVHZPBSARB-UHFFFAOYSA-H

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Scandium(III) hexafluoroacetylacetonate

Empirical Formula (Hill Notation):	C₁₅H₃F₁₈O₆Sc
Linear Formula:	Sc(C₅HF₆O₂)₃
CAS Number:	18990-42-6
Molecular Weight:	666.11
MDL number:	MFCD00070432
PubChem Substance ID:	24878560
NACRES:	NA.23

Quality Level	100,
form	powder (may contain chunks)
composition	Sc, 6.5-7.0% EDTA titration
reaction suitability	core: scandium, reagent type: catalyst
mp	93-96 °C
SMILES string	FC(F)(F)C(=O)\C=C(/O[Sc](O\C(=C/C(=O)C(F)(F)F)C(F)(F)F)O\C(=C/C(=O)C(F)(F)F)C(F)(F)F)C(F)(F)F
InChI	1S/3C5H2F6O2.Sc/c36-4(7,8)2(12)1-3(13)5(9,10)11;/h31,12H;/q;;;+3/p-3/b3*2-1-;
InChI key	DWCYUTXXZMNFLG-JVUUZWNBSA-K

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315-H319-H335
pcodes	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	3

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Scandium(III) isopropoxide

Empirical Formula (Hill Notation):	C₉H₂₁O₃Sc
Linear Formula:	Sc(OCH(CH₃)₂)₃
CAS Number:	60406-93-1
Molecular Weight:	222.22
MDL number:	MFCD00192432
PubChem Substance ID:	24865692
NACRES:	NA.23

Quality Level	100,
form	powder or granules, solid
composition	Sc, 19.5-22.0% EDTA titration
reaction suitability	core: scandium, reagent type: catalyst
SMILES string	CC(C)O[Sc](OC(C)C)OC(C)C
InChI	1S/3C3H7O.Sc/c31-3(2)4;/h33H,1-2H3;/q3*-1;+3
InChI key	SLACPSWSQQIQTG-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H228 - H314
pcodes	P210 - P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 2925 8(4.1) / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Silver sulfate-Sulfuric acid solution

CAS Number:	19287-89-9
MDL number:	MFCD00003407
PubChem Substance ID:	329753636

grade	for COD determination according to DIN 38409, part 41
Quality Level	100,
form	solution (volumetric)
reaction suitability	reagent type: catalyst core: silver
concentration	60 g/L in sulfuric acid
Featured Industry	Environmental General Analytical
SMILES string	[Ag+].[Ag+].[O-]S([O-])(=O)=O
InChI	1S/2Ag.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2
InChI key	YPNVIBVEFVRZPJ-UHFFFAOYSA-L

Safety Information

pictograms	GHS05,GHS09
signalword	Danger
hcodes	H290 - H314 - H410
pcodes	P273 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1830 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Sodium hexafluoroaluminate

Empirical Formula (Hill Notation):	AlF₆Na₃
Linear Formula:	Na₃AlF₆
CAS Number:	13775-53-6
Molecular Weight:	209.94
EC Number:	237-410-6
MDL number:	MFCD00003507
PubChem Substance ID:	24853772
NACRES:	NA.23

Quality Level	100,
assay	99.98% trace metals basis
form	powder and chunks
reaction suitability	reagent type: catalyst core: aluminum
impurities	250.0 ppm Trace Metal Analysis
density	2.9 g/mL at 25 °C (lit.)
SMILES string	F[Al](F)(F)(F)(F)(F)([Na])([Na])[Na]
InChI	1S/Al.6FH.3Na/h;61H;;;/q+3;;;;;;;3+1/p-6
InChI key	REHXRBDMVPYGJX-UHFFFAOYSA-H

Safety Information

pictograms	GHS07,GHS08,GHS09
signalword	Danger
hcodes	H332 - H362 - H372 - H411
pcodes	P201 - P260 - P263 - P273 - P304 + P340 + P312 - P308 + P313
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Sodium hexafluoroarsenate(V)

Empirical Formula (Hill Notation):	AsF₆Na
Linear Formula:	NaAsF₆
CAS Number:	12005-86-6
Molecular Weight:	211.90
MDL number:	MFCD00014228
PubChem Substance ID:	24853398
NACRES:	NA.23

Quality Level	100,
assay	86.9-91.3% (% AsF6 With Tetraphenylarsonium Chloride, gravimetric)
form	powder
reaction suitability	reagent type: catalyst core: arsenic
SMILES string	[Na+].F[As-](F)(F)(F)(F)F
InChI	1S/AsF6.Na/c2-1(3,4,5,6)7;/q-1;+1
InChI key	NFXMAZFYHDSPPB-UHFFFAOYSA-N

Safety Information

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H301 + H331 - H410
pcodes	P261 - P264 - P270 - P273 - P301 + P310 - P304 + P340 + P311
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Sodium hexafluoroferrate(III)

Empirical Formula (Hill Notation):	F₆FeNa₃
Linear Formula:	Na₃FeF₆
CAS Number:	20955-11-7
Molecular Weight:	238.80
EC Number:	244-124-5
MDL number:	MFCD00042147
PubChem Substance ID:	24852221
NACRES:	NA.23

form	powder
reaction suitability	reagent type: catalyst core: iron
SMILES string	[Na+].[Na+].[Na+].F[Fe-3](F)(F)(F)(F)F
InChI	1S/6FH.Fe.3Na/h61H;;;;/q;;;;;;+3;3+1/p-6
InChI key	NXXJJPQQCLIRPD-UHFFFAOYSA-H

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Sodium hexahydroxyplatinate(IV)

Empirical Formula (Hill Notation):	H₆Na₂O₆Pt
Linear Formula:	Na₂Pt(OH)₆
CAS Number:	12325-31-4
Molecular Weight:	343.10
EC Number:	235-590-0
MDL number:	MFCD00014236
PubChem Substance ID:	24870209

Quality Level	100,
assay	51.2-62.5% Pt basis (gravimetric)
form	powder
reaction suitability	reagent type: catalyst core: platinum
mp	150 °C (dec.) (lit.)
SMILES string	[Na+].[Na+].O[Pt--](O)(O)(O)(O)O
InChI	1S/2Na.6H2O.Pt/h;;61H2;/q2+1;;;;;;;+4/p-6
InChI key	LDMNYTKHBHFXNG-UHFFFAOYSA-H

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H317 - H319 - H335
pcodes	P280 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Sodium orthovanadate

Empirical Formula (Hill Notation):	Na₃O₄V
Linear Formula:	Na₃VO₄
CAS Number:	13721-39-6
Molecular Weight:	183.91
EC Number:	237-287-9
MDL number:	MFCD00003511
PubChem Substance ID:	24899708
NACRES:	NA.77

Sodium orthovandate was used to prepare the stop solution in dephosphorylation assay of insulin receptor kinase.26 It was one of the reagents used in the development of Matrix ChIP that utilizes surface-immobilized antibodies.27

Packaging

10, 50, 250 g in poly bottle

Biochem/physiol Actions

Sodium orthovandate suppresses the activation of p53-mediated apoptosis triggered in response to radiation. It reduces the detrimental effects of hematopoietic syndrome, hematopoiesis and delayed genotoxic effects of induced by total body irradiation of mice.24 In combination with menadione, orthovandate prevents the migration of detached human glioma cells in response to anti-cancer drugs.25
Inhibits ATPase, alkaline phosphatase and tyrosine phosphatase. Decavanadate, which is formed at acidic pH, inhibits inositol 1,4,5-trisphosphate (IP3)-induced Ca2+ release from endocrine cells and blocks IP3 binding to its receptor in brain tissue.

Features and Benefits

This compound is featured on the Phosphoprotein Phosphatases (Tyrosine), page of the Handbook of Receptor Classification and Signal Transduction. To browse other handbook pages, click here,.
This compound is a featured product for Kinase Phosphatase Biology research. Click here, to discover more featured Kinase Phosphatase Biology products. Learn more about bioactive small molecules for other areas of research at sigma.com/discover-bsm,.

Параметры

biological source	synthetic (organic)
Quality Level	200,
assay	90% (titration)
form	crystalline powder
reaction suitability	reagent type: catalyst core: vanadium
color	white to off-white
mp	850-866 °C (lit.)
solubility	H₂O: soluble
SMILES string	[Na+].[Na+].[Na+].[O-][V]([O-])([O-])=O
InChI	1S/3Na.4O.V/q3+1;;3-1;
InChI key	IHIXIJGXTJIKRB-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Sodium tetrachloroaluminate

Empirical Formula (Hill Notation):	AlCl₄Na
Linear Formula:	NaAlCl₄
CAS Number:	7784-16-9
Molecular Weight:	191.78
EC Number:	232-050-6
MDL number:	MFCD00050361
PubChem Substance ID:	24865449
NACRES:	NA.23

Quality Level	100,
assay	98%
form	powder
reaction suitability	reagent type: catalyst core: aluminum
mp	185 °C (lit.)
density	2.01 g/mL at 25 °C (lit.)
SMILES string	[Na+].Cl[Al-](Cl)(Cl)Cl
InChI	1S/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4
InChI key	CMLRNXGMTZKKSR-UHFFFAOYSA-J

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Supp Hazards	EUH014
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3262 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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SPhos-Pd-G2 GT capsule 805483-5EA

Empirical Formula (Hill Notation):	C₃₈H₄₅ClNO₂PPd
Molecular Weight:	720.62
MDL number:	MFCD20264897
PubChem Substance ID:	329768941
NACRES:	NA.22

Application

Convenient dosable form of SPhos-Pd-G2.

Packaging

5 ea in glass bottle

Параметры

form	capsule
Quality Level	100,
feature	generation 2
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reagent type: ligand
functional group	phosphine
InChI	1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
Inchi Key	NOMWEFBAPVZIIP-UHFFFAOYSA-M

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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SPhos-Pd-G3 GT capsule 805645-5EA

Empirical Formula (Hill Notation):	C₃₉H₄₈NO₅PPdS
Molecular Weight:	780.26
PubChem Substance ID:	329768953
NACRES:	NA.22

Application

Convenient dosable form of SPhos-Pd-G3

Packaging

5 ea in glass bottle

Параметры

form	capsule
Quality Level	100,
feature	generation 3
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst reaction type: Cross Couplings, reagent type: ligand
functional group	phosphine
SMILES string	COC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5.C
InChI	1S/C26H35O2P.C12H10N.CH4O3S.CH4.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);1H4;/q;;;;+1/p-1
Inchi Key	MKKSNXJKLSKZMC-UHFFFAOYSA-M

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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StickyCat PF6

Empirical Formula (Hill Notation): C₃₅H₄₈Cl₂F₆N₃OPRu

CAS Number: 2249721-29-5

Molecular Weight: 843.72

Кат. номер

901760-100MG

901760-VAR

Application
StickyCat PF6 is for heterogeneous olefin metathesis that can be performance modulated by ion exchange. The catalyst also has high stability in non-degassed water.
Legal Information
Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com. PCT/EP2013/053967
Параметры

assay 95%

form powder

reaction suitability core: ruthenium, reagent type: catalyst

mp 266 °C (decomposition)

storage temp. 2-8°C

Safety Information

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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Strontium iodide hexahydrate

Linear Formula:	SrI₂ · 6H₂O
CAS Number:	7790-40-1
MDL number:	MFCD00278871
PubChem Substance ID:	329762445

2, 10 g in poly bottle

Application

Melting point decompostition may be due to loss of water molecules

Параметры

Quality Level	100,
assay	99.99% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: strontium
impurities	100.0 ppm Trace Metal Analysis
mp	90 °C (decomposition)
density	2.672 g/mL at 25 °C
SMILES string	O.O.O.O.O.O.I[Sr]I
InChI	1S/2HI.6H2O.Sr/h21H;61H2;/q;;;;;;;;+2/p-2
Inchi Key	PHKVCUKHWRPWMA-UHFFFAOYSA-L

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3260 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Strontium tungsten oxide 709220-10G

Empirical Formula (Hill Notation):	O₄SrW
Linear Formula:	SrWO₄
CAS Number:	13451-05-3
Molecular Weight:	335.46
EC Number:	236-617-9
MDL number:	MFCD00049562
PubChem Substance ID:	329762858
NACRES:	NA.23

Параметры

assay	99.9% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: strontium, reagent type: catalyst core: tungsten
particle size	200 mesh
mp	>400 °C
density	6.187 g/cm³ at 25 °C
SMILES string	[Sr++].[O-][W]([O-])(=O)=O
InChI	1S/4O.Sr.W/q;;2*-1;+2;
Inchi Key	KXELQHMRKFESFN-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tantalum(V) methoxide

Empirical Formula (Hill Notation):	C₅H₁₅O₅Ta
Linear Formula:	Ta(OCH₃)₅
CAS Number:	865-35-0
Molecular Weight:	336.12
Beilstein/REAXYS Number:	3675458
MDL number:	MFCD00058817
PubChem Substance ID:	24863946
NACRES:	NA.23

Quality Level	100,
form	solid
composition	Ta, 52.4-55.7% gravimetric
reaction suitability	core: tantalum, reagent type: catalyst
impurities	≤2% Cl
SMILES string	CO[Ta](OC)(OC)(OC)OC
InChI	1S/5CH3O.Ta/c51-2;/h51H3;/q5*-1;+5
InChI key	QASMZJKUEABJNR-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS07
signalword	Danger
hcodes	H228 - H315 - H319 - H335
pcodes	P210 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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tBuDavePhos Pd G3

Linear Formula:

C₃₅H₄₅N₂O₃PPdS · C₄H₈O

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Application

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids., It may also be used for a variety of C-C and C-N cross-coupling reactions.

Other Notes

Technology Spotlight: G3 and G4 Buchwald Precatalysts,
Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids,
Design and preparation of new palladium precatalysts for C-C and C-N cross-coupling reactions,

Параметры

form	powder or crystals
feature	generation 3
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst reaction type: Cross Couplings
functional group	phosphine
SMILES string	CN(C1=C(C2=C(P(C(C)(C)C)C(C)(C)C)C=CC=C2)C=CC=C1)C.NC3=C(C4=C([Pd]OS(C)(=O)=O)C=CC=C4)C=CC=C3.C5COCC5

Safety Information

WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Terbium(III) sulfate octahydrate

Empirical Formula (Hill Notation):	O₁₂S₃Tb₂ · 8H₂O
Linear Formula:	Tb₂(SO₄)₃·8H₂O
CAS Number:	13842-67-6
Molecular Weight:	750.16
MDL number:	MFCD00149872
PubChem Substance ID:	24859548
NACRES:	NA.23

assay	99.9% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: terbium
impurities	2000.0 ppm Trace Metal Analysis
SMILES string	[Tb+3].[Tb+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
InChI	1S/3H2O4S.8H2O.2Tb/c31-5(2,3)4;;;;;;;;;;/h3(H2,1,2,3,4);81H2;;/q;;;;;;;;;;;2+3/p-6
InChI key	SRSFZSUHOIHUFR-UHFFFAOYSA-H

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Terbium(III) tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

Empirical Formula (Hill Notation):	C₃₃H₅₇O₆Tb
Linear Formula:	Tb(OCC(CH₃)₃CHCOC(CH₃)₃)₃
CAS Number:	15492-51-0
Molecular Weight:	708.73
MDL number:	MFCD00064752
PubChem Substance ID:	24867167
NACRES:	NA.23

assay	98%
form	solid
reaction suitability	core: terbium, reagent type: catalyst
mp	163-164 °C (lit.)
SMILES string	CC(C)(C)C(=O)\C=C(/O[Tb](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI	1S/3C11H20O2.Tb/c31-10(2,3)8(12)7-9(13)11(4,5)6;/h37,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InChI key	JSAHJYGCYOFNGW-LWTKGLMZSA-K

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Terbium(III,IV) oxide

Empirical Formula (Hill Notation):	O₇Tb₄
Linear Formula:	Tb₄O₇
CAS Number:	12037-01-3
Molecular Weight:	747.70
EC Number:	234-856-3
MDL number:	MFCD00083151
PubChem Substance ID:	24852278
NACRES:	NA.23

Quality Level	100,
assay	99.999% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: terbium
density	7.3 g/mL at 25 °C (lit.)
SMILES string	O=[Tb]O[Tb](=O)O[Tb](=O)O[Tb]=O
InChI	1S/7O.4Tb
Inchi Key	UWZVBPNIJCKCMC-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Terbium(III,IV) oxide 634255-25G

Empirical Formula (Hill Notation):	O₇Tb₄
Linear Formula:	Tb₄O₇
CAS Number:	12037-01-3
Molecular Weight:	747.70
EC Number:	234-856-3
MDL number:	MFCD00083151
PubChem Substance ID:	24882615
NACRES:	NA.23

Параметры

Quality Level	100,
assay	99.5% trace metals basis
form	nanopowder
reaction suitability	reagent type: catalyst core: terbium
particle size	<100 nm (BET)
density	7.3 g/mL at 25 °C (lit.)
SMILES string	O=[Tb]O[Tb](=O)O[Tb](=O)O[Tb]=O
InChI	1S/7O.4Tb
InChI key	UWZVBPNIJCKCMC-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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tert-Butyldiisopropylphosphine

Empirical Formula (Hill Notation):	C₁₀H₂₃P
CAS Number:	51567-05-6
Molecular Weight:	174.26
MDL number:	MFCD06200720
PubChem Substance ID:	24883018

tert-Butyldiisopropylphosphine is a phosphine ligand that can be utilized in C-C bond forming reactions.

Application

Monodentate P-Donor Ligand
Catalyst for selective propylene dimerization to dimethylbutenes

Packaging

1, 5 g in glass bottle

Параметры

assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
bp	77-79 °C/10 mmHg (lit.)
density	0.837 g/mL at 25 °C (lit.)
functional group	phosphine
SMILES string	CC(C)P(C(C)C)C(C)(C)C
InChI	1S/C10H23P/c1-8(2)11(9(3)4)10(5,6)7/h8-9H,1-7H3
InChI key	OLSMQSZDUXXYAY-UHFFFAOYSA-N

Safety Information

pictograms	GHS02, GHS05
signalword	Danger
hcodes	H250-H314
pcodes	P222-P231-P280-P305 + P351 + P338-P310-P422
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2845 4.2
WGK Germany	3

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tert-Butyldimethylphosphine borane

Empirical Formula (Hill Notation):	C₆H₁₈BP
Linear Formula:	C₆H₁₅P · BH₃
CAS Number:	203000-43-5
Molecular Weight:	131.99
PubChem Substance ID:	24885386
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp	159-168 °C
functional group	phosphine
SMILES string	B.CP(C)C(C)(C)C
InChI	1S/C6H15P.BH3/c1-6(2,3)7(4)5;/h1-5H3;1H3
InChI key	MHAGKNYBOOCWIH-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS07
signalword	Danger
hcodes	H261 - H302
pcodes	P231 + P232 - P301 + P312 + P330
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 2813 4.3 / PGII
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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tert-Butylphenylphosphine

Empirical Formula (Hill Notation):	C₁₀H₁₅P
Linear Formula:	C₆H₅PHC(CH₃)₃
CAS Number:	6002-31-9
Molecular Weight:	166.20
MDL number:	MFCD00761896
PubChem Substance ID:	24881634

Reacts with electron deficient boranes
Reactant in platinum-catalyzed asymmetric alkylation of secondary phosphines
Reactant for preparation of "chiral-at-Ru" secondary phosphine complex

Packaging
1 g in glass bottle

Параметры

assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
bp	99-100 °C/17 mmHg (lit.)
density	0.928 g/mL at 25 °C (lit.)
functional group	phosphine
SMILES string	CC(C)(C)Pc1ccccc1
InChI	1S/C10H15P/c1-10(2,3)11-9-7-5-4-6-8-9/h4-8,11H,1-3H3
InChI key	ZSSMIQURWRIOCN-UHFFFAOYSA-N

Safety Information

pictograms	GHS02
signalword	Danger
hcodes	H250
pcodes	P222-P231-P422
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2845 4.2
WGK Germany	3

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tert-Butylphosphonic dichloride

Empirical Formula (Hill Notation):	C₄H₉Cl₂OP
Linear Formula:	(CH₃)₃CP(O)Cl₂
CAS Number:	4707-95-3
Molecular Weight:	174.99
MDL number:	MFCD00012289
PubChem Substance ID:	24858442
NACRES:	NA.22

Quality Level	100,
assay	98%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp	121-123 °C (lit.)
functional group	phosphine
SMILES string	CC(C)(C)P(Cl)(Cl)=O
InChI	1S/C4H9Cl2OP/c1-4(2,3)8(5,6)7/h1-3H3
InChI key	OQUGNSMOWJIYMO-UHFFFAOYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3261 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetraamminepalladium(II) acetate

Empirical Formula (Hill Notation):	C₄H₁₈N₄O₄Pd
Linear Formula:	Pd(NH₃)₄(CH₃CO₂)₂
CAS Number:	61495-96-3
Molecular Weight:	292.63
EC Number:	262-819-1
MDL number:	MFCD00274619
PubChem Substance ID:	24867297
NACRES:	NA.23

form	solid
reaction suitability	core: aluminum, reagent type: catalyst
mp	183-186 °C (dec.) (lit.)
SMILES string	N.N.N.N.O.O.CC(=O)O[Pd]OC(C)=O
InChI	1S/2C2H4O2.4H3N.2H2O.Pd/c21-2(3)4;;;;;;;/h21H3,(H,3,4);41H3;21H2;/q;;;;;;;;+2/p-2
InChI key	TXKHLAUDWHNZBC-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetraamminepalladium(II) bromide

Empirical Formula (Hill Notation):	H₁₂Br₂N₄Pd
Linear Formula:	Pd(NH₃)₄Br₂
CAS Number:	44463-62-9
Molecular Weight:	334.35
MDL number:	MFCD00797352
PubChem Substance ID:	24871742
NACRES:	NA.23

assay	99.99% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: palladium
mp	>150 °C (dec.) (lit.)
SMILES string	N.N.N.N.Br[Pd]Br
InChI	1S/2BrH.4H3N.Pd/h21H;41H3;/q;;;;;;+2/p-2
InChI key	BLPSMPASLSGGOC-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P261 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetrabutylammonium hexachloroplatinate(IV)

Empirical Formula (Hill Notation):	C₃₂H₇₂Cl₆N₂Pt
Linear Formula:	{[CH₃(CH₂)₃]₄N}₂PtCl₆
CAS Number:	18129-78-7
Molecular Weight:	892.72
MDL number:	MFCD00075248
PubChem Substance ID:	24861031
NACRES:	NA.22

reaction suitability	core: platinum, reagent type: catalyst
mp	225 °C (dec.) (lit.)
SMILES string	Cl[Pt--](Cl)(Cl)(Cl)(Cl)Cl.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
InChI	1S/2C16H36N.6ClH.Pt/c21-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;;/h25-16H2,1-4H3;61H;/q2+1;;;;;;;+4/p-6
InChI key	SSHOYKZPYIRFFY-UHFFFAOYSA-H

Safety Information

pictograms	GHS05,GHS06,GHS08
signalword	Danger
hcodes	H301 - H317 - H318 - H334
pcodes	P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310
RIDADR	UN 3467 6.1 / PGIII
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetrabutylammonium octachlorodirhenate(III)

Empirical Formula (Hill Notation):	C₃₂H₇₂Cl₈N₂Re₂
Linear Formula:	{[CH₃(CH₂)₃]₄N}₂Re₂Cl₈
CAS Number:	14023-10-0
Molecular Weight:	1140.97
MDL number:	MFCD00064731
PubChem Substance ID:	24855041
NACRES:	NA.22

Quality Level	100,
assay	98%
reaction suitability	core: rhenium, reagent type: catalyst
SMILES string	Cl[Re-](Cl)(Cl)Cl.Cl[Re-](Cl)(Cl)Cl.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
InChI	1S/2C16H36N.8ClH.2Re/c21-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;;;;;/h25-16H2,1-4H3;81H;;/q2+1;;;;;;;;;2*+3/p-8
InChI key	DSDHKKNVLJDBNO-UHFFFAOYSA-F

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetrabutylammonium tetrachlorooxorhenate(V)

Empirical Formula (Hill Notation):	C₁₆H₃₆Cl₄NORe
Linear Formula:	[CH₃(CH₂)₃]₄N(ReOCl₄)
CAS Number:	53675-30-2
Molecular Weight:	586.48
PubChem Substance ID:	24871363
NACRES:	NA.22

Olefin epoxidation
Assembly of noncyclic selective integrin antagonists
Cyclic trinuclear Oxorhenium(V) core compounds
Pharmacophore Re-cyclized octreotide analogues (somatostatin subtype 2 receptor ligands)

Packaging
1 g in glass bottle

Параметры

reaction suitability	core: rhenium, reagent type: catalyst
Quality Level	100,
mp	154.4 °C (dec.) (lit.)
SMILES string	Cl[Re-](Cl)(Cl)(Cl)=O.CCCC[N+](CCCC)(CCCC)CCCC
InChI	1S/C16H36N.4ClH.O.Re/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;/h5-16H2,1-4H3;4*1H;;/q+1;;;;;;+3/p-4
InChI key	RWOTWQYSOOLNQP-UHFFFAOYSA-J

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetracarbonyl(1,5-cyclooctadiene)tungsten(0) 511285-5G

Empirical Formula (Hill Notation):	C₁₂H₁₂O₄W
CAS Number:	12129-70-3
Molecular Weight:	404.06
MDL number:	MFCD01863670
PubChem Substance ID:	24873436
NACRES:	NA.23

Параметры

form	powder or crystals
reaction suitability	core: tungsten, reagent type: catalyst
mp	155-161 °C (lit.)
SMILES string	[W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1CC=CCCC=C1
InChI	1S/C8H12.4CO.W/c1-2-4-6-8-7-5-3-1;4*1-2;/h1-2,7-8H,3-6H2;;;;;/b2-1-,8-7-;;;;;
InChI key	URZAVABIRGHJEB-XRGHXPOKSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetraisopropyl vinylidenediphosphonate

Empirical Formula (Hill Notation):	C₁₄H₃₀O₆P₂
CAS Number:	48074-47-1
Molecular Weight:	356.33
MDL number:	MFCD00408348
PubChem Substance ID:	329766307
NACRES:	NA.22

grade	technical grade
Quality Level	100,
assay	70%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
functional group	phosphine
SMILES string	CC(C)OP(=O)(OC(C)C)C(=C)P(=O)(OC(C)C)OC(C)C
InChI	1S/C14H30O6P2/c1-10(2)17-21(15,18-11(3)4)14(9)22(16,19-12(5)6)20-13(7)8/h10-13H,9H2,1-8H3
InChI key	IPUAADANTWKVJD-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	No data available
Flash Point C	No data available

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Tetrakis(diethylamido)titanium(IV) 725536-10G

Empirical Formula (Hill Notation):	C₁₆H₄₀N₄Ti
Linear Formula:	[(C₂H₅)₂N]₄Ti
CAS Number:	4419-47-0
Molecular Weight:	336.38
Beilstein/REAXYS Number:	3621431
MDL number:	MFCD00015648
PubChem Substance ID:	329764167
NACRES:	NA.23

General description

Atomic number of base material: 22 Titanium

Application

Precursors Packaged for Depositions Systems

Packaging

10 g in stainless steel cylinder

Параметры

Quality Level	100,
form	liquid
reaction suitability	core: titanium, reagent type: catalyst
refractive index	n20/D 1.536 (lit.)
bp	112 °C/0.1 mmHg (lit.)
density	0.931 g/mL at 25 °C (lit.)
SMILES string	CCN(CC)[Ti](N(CC)CC)(N(CC)CC)N(CC)CC
InChI	1S/4C4H10N.Ti/c41-3-5-4-2;/h43-4H2,1-2H3;/q4*-1;+4
InChI key	VJDVOZLYDLHLSM-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H225 - H260 - H314
pcodes	P210 - P223 - P231 + P232 - P280 - P370 + P378 - P422
RIDADR	UN3398 - DOT UN3399 class 4.3 - PG 1 - Organometallic substance, liquid, water-reactive, HI: all (not BR)
WGK Germany	WGK 3
Flash Point F	-19.8 °F - closed cup
Flash Point C	-28.8 °C - closed cup

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Tetrakis(ethylmethylamido)hafnium(IV) 725544-10G

Empirical Formula (Hill Notation):	C₁₂H₃₂HfN₄
Linear Formula:	[(CH₃)(C₂H₅)N]₄Hf
CAS Number:	352535-01-4
Molecular Weight:	410.90
MDL number:	MFCD03427130
PubChem Substance ID:	329764168
NACRES:	NA.23

General description

Atomic number of base material: 72 Hafnium

Application

Precursors Packaged for Depositions Systems

Packaging

10 g in stainless steel cylinder

Параметры

Quality Level	100,
form	liquid
reaction suitability	core: hafnium, reagent type: catalyst
bp	78 °C/0.01 mmHg (lit.)
mp	<-50 °C
density	1.324 g/mL at 25 °C (lit.)
storage temp.	2-8°C
SMILES string	CCN(C)[Hf](N(C)CC)(N(C)CC)N(C)CC
InChI	1S/4C3H8N.Hf/c41-3-4-2;/h43H2,1-2H3;/q4*-1;+4
Inchi Key	NPEOKFBCHNGLJD-UHFFFAOYSA-N

Safety Information

pictograms	GHS02
signalword	Danger
hcodes	H225 - H261
pcodes	P210 - P223 - P231 + P232 - P233 - P240 - P241
Supp Hazards	EUH014
RIDADR	UN3398 - DOT UN3399 class 4.3 - PG 1 - Organometallic substance, liquid, water-reactive, HI: all (not BR)
WGK Germany	WGK 3
Flash Point F	51.8 °F - closed cup
Flash Point C	11 °C - closed cup

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Tetrakis(ethylmethylamido)zirconium(IV) 725528-10G

Empirical Formula (Hill Notation):	C₁₂H₃₂N₄Zr
Linear Formula:	Zr(NCH₃C₂H₅)₄
CAS Number:	175923-04-3
Molecular Weight:	323.63
MDL number:	MFCD03427131
PubChem Substance ID:	329764166

General description

Atomic number of base material: 40 Zirconium

Application

Precursors Packaged for Depositions Systems

Packaging

10 g in stainless steel cylinder

Параметры

form	liquid
reaction suitability	core: zirconium, reagent type: catalyst
bp	81 °C/0.1 mmHg (lit.)
density	1.049 g/mL at 25 °C (lit.)
SMILES string	CCN(C)[Zr](N(C)CC)(N(C)CC)N(C)CC
InChI	1S/4C3H8N.Zr/c41-3-4-2;/h43H2,1-2H3;/q4*-1;+4
InChI key	SRLSISLWUNZOOB-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS07
signalword	Danger
hcodes	H225 - H261 - H315 - H319 - H335
pcodes	P210 - P231 + P232 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	UN3398 - DOT UN3399 class 4.3 - PG 2 - Organometallic substance, liquid, water-reactive, HI: all (not BR)
WGK Germany	WGK 3
Flash Point F	50.0 °F - closed cup
Flash Point C	10 °C - closed cup

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Tetrakis(hexahydro-2H-pyrimido[1,2-a]pyrimidinato)ditungsten(III) dichloride

Empirical Formula (Hill Notation):	C₂₈H₄₈Cl₂N₁₂W₂
Linear Formula:	W₂(C₇H₁₂N₃)₄Cl₂
CAS Number:	280107-73-5
Molecular Weight:	991.35
MDL number:	MFCD22200483
PubChem Substance ID:	329760604
NACRES:	NA.22

reaction suitability	core: tungsten, reagent type: catalyst
Quality Level	100,
mp	233-235 °C
SMILES string	C12=NCCCN1CCCN2[W-]3([Cl+][W-](N4C5=NCCCN5CCC4)(N6C7=NCCCN7CCC6)[Cl+]3)N8C9=NCCCN9CCC8
InChI	1S/4C7H12N3.2Cl.2W/c41-3-8-7-9-4-2-6-10(7)5-1;;;;/h41-6H2;;;;/q4-1;4+1
Inchi Key	ULSLYQPHFUUSFQ-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetraphenylarsonium(V) chloride hydrochloride hydrate

Empirical Formula (Hill Notation):	C₂₄H₂₀AsCl · HCl · xH₂O
Linear Formula:	(C₆H₅)₄AsCl·HCl·xH₂O
CAS Number:	123334-18-9
Molecular Weight:	455.25 (anhydrous basis)
EC Number:	208-070-6
MDL number:	MFCD00150049
PubChem Substance ID:	24848554
NACRES:	NA.22

Quality Level	100,
reaction suitability	core: arsenic, reagent type: catalyst
mp	211-213 °C (lit.)
SMILES string	O.Cl.[Cl-].c1ccc(cc1)[As+](c2ccccc2)(c3ccccc3)c4ccccc4
InChI	1S/C24H20As.2ClH.H2O/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;;/h1-20H;2*1H;1H2/q+1;;;/p-1
InChI key	HRCBNZHNCWEFFR-UHFFFAOYSA-M

Safety Information

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H301 + H331 - H410
pcodes	P273 - P301 + P310 + P330 - P304 + P340 + P311
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetraphenylgermane

Empirical Formula (Hill Notation):	C₂₄H₂₀Ge
Linear Formula:	Ge(C₆H₅)₄
CAS Number:	1048-05-1
Molecular Weight:	381.06
EC Number:	213-880-8
MDL number:	MFCD00002997
PubChem Substance ID:	329765895
NACRES:	NA.22

Quality Level	100,
assay	96%
reaction suitability	core: germanium, reagent type: catalyst
mp	230-235 °C (lit.)
SMILES string	c1ccc(cc1)[Ge](c2ccccc2)(c3ccccc3)c4ccccc4
InChI	1S/C24H20Ge/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H
InChI key	ILEXMONMGUVLRM-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetrapropylphosphonium bromide 804428-500MG

Empirical Formula (Hill Notation):	C₁₂H₂₈BrP
CAS Number:	63462-98-6
Molecular Weight:	283.23
PubChem Substance ID:	329768869
NACRES:	NA.22

Параметры

Quality Level	100,
assay	95%
form	powder and chunks
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp	221-226 °C
functional group	phosphine
SMILES string	CCC[P+](CCC)(CCC)CCC.[Br-]
InChI	1S/C12H28P.BrH/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H/q+1;/p-1
InChI key	SMGSPBKMKYMJPQ-UHFFFAOYSA-M

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Tetrarhodium dodecacarbonyl

Empirical Formula (Hill Notation):	C₁₂O₁₂Rh₄
Linear Formula:	Rh₄(CO)₁₂
CAS Number:	19584-30-6
Molecular Weight:	747.74
EC Number:	243-171-9
MDL number:	MFCD00016310
PubChem Substance ID:	24863783
NACRES:	NA.22

Кат. номер

381012-250MG

381012-50MG

Packaging
250 mg in glass bottle

Other Notes

Contains a trace amount of Rh6(CO)16

Параметры

reaction suitability	core: rhodium, reagent type: catalyst
Quality Level	100,
storage temp.	2-8°C
SMILES string	[Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI	1S/12CO.4Rh/c12*1-2;;;;
InChI key	LVGLLYVYRZMJIN-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 - H312 - H332
pcodes	P280
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable