Titanium(IV) isopropoxide
Empirical Formula (Hill Notation): | C12H28O4Ti |
Linear Formula: | Ti[OCH(CH3)2]4 |
CAS Number: | 546-68-9 |
Molecular Weight: | 284.22 |
Beilstein/REAXYS Number: | 3679474 |
EC Number: | 208-909-6 |
MDL number: | MFCD00008871 |
PubChem Substance ID: | 24852318 |
NACRES: | NA.22 |
Кат. номер |
205273-5KG |
205273-1L |
205273-2L |
205273-100ML |
205273-500ML |
205273-2.5L |
205273-4X25ML |
205273-6X500ML |
205273-5ML |
205273-4X10ML |
Titanium(IV) isopropoxide is a titanium-based coordination compound, commonly used in the asymmetric Sharpless epoxidation reaction of allylic alcohols. It is also used as a catalyst in Kulinkovich reaction for the synthesis of cyclopropanes.
100, 500 mL in glass bottle
1, 2, 2.5 L in glass bottle
4×25 mL in Sure/Seal™
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.
Commonly used as a precursor for the preparation of Titania (TiO2)
Product of Dorf Ketal
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Quality Level | 200 |
assay | 97% |
form | liquid |
reaction suitability | core: titanium, reagent type: catalyst |
refractive index | n20/D 1.464 (lit.) |
bp | 232 °C (lit.) |
mp | 14-17 °C (lit.) |
density | 0.96 g/mL at 20 °C (lit.) |
SMILES string | CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C |
InChI | 1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4 |
InChI key | VXUYXOFXAQZZMF-UHFFFAOYSA-N |
Pictograms | GHS02,GHS07 |
Signal Word | Warning |
Hazard Statements | H226 - H319 - H336 |
Precautionary Statements | P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338 |
Target Organs | Central nervous system |
Personal Protective Equipment | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
RIDADR | UN 2413 3 / PGIII |
WGK Germany | WGK 1 |
Flash Point(F) | 105.8 °F - Pensky-Martens closed cup |
Flash Point(C) | 41 °C - Pensky-Martens closed cup |