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OLED & PLED Materials

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48

N,N,N,N-Tetraphenylnaphthalene-2,6-diamine 763578-5G

Empirical Formula (Hill Notation):	C₃₄H₂₆N₂
CAS Number:	111961-87-6
Molecular Weight:	462.58
MDL number:	MFCD22666446
PubChem Substance ID:	329767064

Packaging

5 g in glass bottle

Application

This material is used as a high performance host material for OLED devices showing increased external quantum efficiency of ~11%.

Параметры

Quality Level	100,
assay	98% (HPLC)
mp	272-276 °C
_max	312 nm in dichloromethane, 341 nm in dichloromethane
SMILES string	c1ccc(cc1)N(c2ccccc2)c3ccc4cc(ccc4c3)N(c5ccccc5)c6ccccc6
InChI	1S/C34H26N2/c1-5-13-29(14-6-1)35(30-15-7-2-8-16-30)33-23-21-28-26-34(24-22-27(28)25-33)36(31-17-9-3-10-18-31)32-19-11-4-12-20-32/h1-26H
InChI key	LEXCBRKPOZULQO-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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N,N-Bis(3-methylphenyl)-N,N-diphenylbenzidine

Empirical Formula (Hill Notation):	C₃₈H₃₂N₂
Linear Formula:	[-C₆H₄-4-N(C₆H₄CH₃)C₆H₅]₂
CAS Number:	65181-78-4
Molecular Weight:	516.67
EC Number:	413-810-8
MDL number:	MFCD00144965
PubChem Substance ID:	57650229
NACRES:	NA.23

1, 5 g in glass bottle

Application

Organic photoconductor. Hole transporter.

Параметры

Quality Level	100,
assay	99%
mp	175-177 °C (lit.)
Orbital energy	HOMO 5.5 eV , LUMO 2.3 eV A
OLED Device Performance	ITO/2-TNATA/TPD/Alq₃/Mg:Ag Color: green Max. Luminance: 22200 Cd/m² Turn-On Voltage: 5.5 V , ITO/TPD/Alq₃:DCM (10%)/Alq₃/Mg:Ag Color: red Max. Luminance: 150 Cd/m² , ITO/TPD/Znq/Mg:In Color: yellow Max. Luminance: 16200 Cd/m² , ITO/m-MTDATA/TPD/TTPhPhB/Alq₃/LiF/Al Color: blue Max. Luminance: 2600 Cd/m² Max. EQE: 1.5 % Turn-On Voltage: 3.4 V
SMILES string	Cc1cccc(c1)N(c2ccccc2)c3ccc(cc3)-c4ccc(cc4)N(c5ccccc5)c6cccc(C)c6
InChI	1S/C38H32N2/c1-29-11-9-17-37(27-29)39(33-13-5-3-6-14-33)35-23-19-31(20-24-35)32-21-25-36(26-22-32)40(34-15-7-4-8-16-34)38-18-10-12-30(2)28-38/h3-28H,1-2H3
InChI key	OGGKVJMNFFSDEV-UHFFFAOYSA-N

Safety Information

pictograms	GHS09
hcodes	H411
pcodes	P273
Personal Protective Equipment	Eyeshields,, Gloves,
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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N,N-Di(1-naphthyl)-N,N-diphenyl-(1,1-biphenyl)-4,4-diamine

Empirical Formula (Hill Notation):	C₄₄H₃₂N₂
CAS Number:	123847-85-8
Molecular Weight:	588.74
MDL number:	MFCD03093246
PubChem Substance ID:	57651547
NACRES:	NA.23

TGA/DSC Lot specific traces available upon request

Packaging

1 g in glass bottle
500 mg in glass insert

Application

Hole transporting material for OLED devices

Параметры

grade	sublimed grade
assay	99%
loss	0.5 wt. % loss on heating, 345°C (typical, TGA)
mp	279-283 °C (lit.)
Orbital energy	HOMO 5.5 eV , LUMO 2.4 eV A
OLED Device Performance	ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq₃/LiF/Al Color: red Max. Luminance: 24529 Cd/m² Max. EQE: 17 % Turn-On Voltage: 2.7 V , ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al Color: green Max. Luminance: 207839 Cd/m² Max. EQE: 21.6 % Turn-On Voltage: 2.1 V , ITO/NPD/mCP/BCPO:FIrpic (8%)/TAZ/LiF/Al Color: blue Max. Luminance: 35677 Cd/m² Max. EQE: 23.5 % Turn-On Voltage: 2.8 V , ITO/PEDOT:PSS/NPD/TCTA/m-CBTZ:Ir(Bt)₂(acac) (10%)/TPBI/LiF/Al Color: yellow Max. Luminance: 106000 Cd/m² Max. EQE: 17.5 % Turn-On Voltage: 3 V
SMILES string	c1ccc(cc1)N(c2ccc(cc2)-c3ccc(cc3)N(c4ccccc4)c5cccc6ccccc56)c7cccc8ccccc78
InChI	1S/C44H32N2/c1-3-17-37(18-4-1)45(43-23-11-15-35-13-7-9-21-41(35)43)39-29-25-33(26-30-39)34-27-31-40(32-28-34)46(38-19-5-2-6-20-38)44-24-12-16-36-14-8-10-22-42(36)44/h1-32H
Inchi Key	IBHBKWKFFTZAHE-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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N,N-Di(1-naphthyl)-N,N-diphenyl-(1,1-biphenyl)-4,4-diamine 734594-5G

Empirical Formula (Hill Notation):	C₄₄H₃₂N₂
CAS Number:	123847-85-8
Molecular Weight:	588.74
MDL number:	MFCD03093246
PubChem Substance ID:	329764912
NACRES:	NA.23

Packaging

5 g in glass bottle

Application

Hole transporting material for OLED devices

Параметры

Quality Level	100,
assay	96%
mp	275-280 °C, 279-283 °C (lit.)
Orbital energy	HOMO 5.5 eV , LUMO 2.4 eV A
OLED Device Performance	ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq₃/LiF/Al Color: red Max. Luminance: 24529 Cd/m² Max. EQE: 17 % Turn-On Voltage: 2.7 V , ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al Color: green Max. Luminance: 207839 Cd/m² Max. EQE: 21.6 % Turn-On Voltage: 2.1 V , ITO/NPD/mCP/BCPO:FIrpic (8%)/TAZ/LiF/Al Color: blue Max. Luminance: 35677 Cd/m² Max. EQE: 23.5 % Turn-On Voltage: 2.8 V , ITO/PEDOT:PSS/NPD/TCTA/m-CBTZ:Ir(Bt)₂(acac) (10%)/TPBI/LiF/Al Color: yellow Max. Luminance: 106000 Cd/m² Max. EQE: 17.5 % Turn-On Voltage: 3 V
SMILES string	c1ccc(cc1)N(c2ccc(cc2)-c3ccc(cc3)N(c4ccccc4)c5cccc6ccccc56)c7cccc8ccccc78
InChI	1S/C44H32N2/c1-3-17-37(18-4-1)45(43-23-11-15-35-13-7-9-21-41(35)43)39-29-25-33(26-30-39)34-27-31-40(32-28-34)46(38-19-5-2-6-20-38)44-24-12-16-36-14-8-10-22-42(36)44/h1-32H
Inchi Key	IBHBKWKFFTZAHE-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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N,N-Di(2-naphthyl-N,N-diphenyl)-1,1-biphenyl-4,4-diamine 762903-1G

Empirical Formula (Hill Notation):	C₄₄H₃₂N₂
CAS Number:	139255-17-7
Molecular Weight:	588.74
MDL number:	MFCD03093247
PubChem Substance ID:	329767010
NACRES:	NA.23

Application

Used in organic electronic light emitting devices.
This material is used as a hole transport layer in a variety of OLED devices

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	99% (HPLC)
form	powder
mp	168-175 °C
SMILES string	c1ccc(cc1)N(c2ccc(cc2)-c3ccc(cc3)N(c4ccccc4)c5ccc6ccccc6c5)c7ccc8ccccc8c7
InChI	1S/C44H32N2/c1-3-15-39(16-4-1)45(43-29-23-33-11-7-9-13-37(33)31-43)41-25-19-35(20-26-41)36-21-27-42(28-22-36)46(40-17-5-2-6-18-40)44-30-24-34-12-8-10-14-38(34)32-44/h1-32H
Inchi Key	BLFVVZKSHYCRDR-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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900968-250MG

N,N-Diphenyl-N,N-bis-[4-(phenyl-m-tolylamino)phenyl]biphenyl-4,4-diamine 900968-250MG

Empirical Formula (Hill Notation): C₆₂H₅₀N₄

CAS Number: 260550-65-0

Molecular Weight: 851.09

NACRES: NA.23

Application
Hole transport material with ortho-linked terphenyl core structure for high power efficiency in blue phosphorescent org. light-emitting diodes.
Параметры

assay 95%

Quality Level 100,

form solid

Safety Information

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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N,N-Diphenyl-N,N-di-p-tolylbenzene-1,4-diamine

Empirical Formula (Hill Notation):	C₃₂H₂₈N₂
CAS Number:	138171-14-9
Molecular Weight:	440.58
MDL number:	MFCD01310665
PubChem Substance ID:	24884626
NACRES:	NA.23

1, 5 g in glass bottle

Application

Hole-transport material for blue to yellow emitting OLEDs with aluminum quinolate (Alq3) derivatives.

Параметры

Quality Level	100,
mp	190-194 °C
SMILES string	Cc1ccc(cc1)N(c2ccccc2)c3ccc(cc3)N(c4ccccc4)c5ccc(C)cc5
InChI	1S/C32H28N2/c1-25-13-17-29(18-14-25)33(27-9-5-3-6-10-27)31-21-23-32(24-22-31)34(28-11-7-4-8-12-28)30-19-15-26(2)16-20-30/h3-24H,1-2H3
InChI key	FQNVFRPAQRVHKO-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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N1,N1,N3,N3,N6,N6,N8,N8-Octakis(4-methoxyphenyl)-1,3,6,8-pyrenetetramine 799076-1G

Empirical Formula (Hill Notation):	C₇₂H₆₂N₄O₈
CAS Number:	1509916-12-4
Molecular Weight:	1111.28
PubChem Substance ID:	329768691
NACRES:	NA.23

Application

Hole transporting material (HTM) for use in inorganic-organic hybrid Perovskite solar cells

Packaging

1 g in glass bottle

Other Notes

Device structure:
TiO2 (mesoporous)/CH3NH3PbI3/Py-C (HTM)/Au
Device performance:

JSC = 20.2 mA/cm2
VOC = 0.89 V
FF = 69.4%
PCE = 12.4%

Параметры

assay	98%
Quality Level	100,
form	powder
mp	174-181 °C (decomposition)
_max	492 nm in chlorobenzene (lit.)
Orbital energy	HOMO 5.11 eV (opt), LUMO 2.74 eV (CV)
SMILES string	COC(C=C1)=CC=C1N(C2=CC=C(OC)C=C2)C3=C(C=C4)C(C(C4=C(N(C5=CC=C(OC)C=C5)C6=CC=C(OC)C=C6)C=C7N(C8=CC=C(OC)C=C8)C9=CC=C(OC)C=C9)=C7C=C%10)=C%10C(N(C%11=CC=C(OC)C=C%11)C%12=CC=C(OC)C=C%12)=C3
InChI	1S/C72H62N4O8/c1-77-55-25-9-47(10-26-55)73(48-11-27-56(78-2)28-12-48)67-45-68(74(49-13-29-57(79-3)30-14-49)50-15-31-58(80-4)32-16-50)64-43-44-66-70(76(53-21-37-61(83-7)38-22-53)54-23-39-62(84-8)40-24-54)46-69(65-42-41-63(67)71(64)72(65)66)75(51-17-33-59(81-5)34-18-51)52-19-35-60(82-6)36-20-52/h9-46H,1-8H3
Inchi Key	JUQSGFMWZQXKJS-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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900440-1G
Orange light-emitting PPV copolymer 900440-1G
CAS Number: 1351337-33-1

NACRES: NA.23

Application
Features:
Soluble orange light-emitting PPV copolymer.
Excellent reproducibility.
Broad emission spectrum.
High efficiency.
Very low operation voltage.
Very long DC and AC lifetime.
High temperature stability (>100 °C).

Typical performance measured in standard device stack (ITO/PEDOT:PSS 20 nm/PDO-123 80 nm/Ba 6 nm/Ag 150 nm):
Max. efficiency: 5.0 Cd/A.
V_on: 2.0 V.
V at 100 cd/m2: 2.6 V.
V at 1000 cd/m2: 3.3 V.
Max. power eff.: 5.5 lm/W.
External quantum eff.: 3.5%.
CIE1931 at 100 cd/m2: (0.60, 0.40).
DC lifetime at 100 cd/m2 at RT: >>25000.

Packaging
1 g in poly bottle
Preparation Note
5 g/L in toluene for spin-coating.
Special formulation needed for Inkjet.
Preparation of device should be in N2 atmosphere.

Legal Information
Product of EMD Performance Materials Corp., an Affiliate of Merck KGaA, Darmstadt, Germany
Livilux is a trademark of Merck KGaA, Darmstadt, Germany
Параметры

mol wt average M_n 340,000, average M_w 1,750,000

Quality Level 100,

Safety Information

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable
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Perylene

Empirical Formula (Hill Notation):	C₂₀H₁₂
CAS Number:	198-55-0
Molecular Weight:	252.31
Beilstein/REAXYS Number:	1911335
EC Number:	205-900-9
MDL number:	MFCD00004142
PubChem Substance ID:	57649900
NACRES:	NA.23

Perylene molecules are fluorescent in nature. Ultraviolet photoemission spectroscopy and low energy electron diffraction of the structure of 4 thick perylene dye layers adsorbed on the surface of Ru (0001) has been investigated.

Application

Perylene was used in the fabrication of gold nanoparticle (AuNP) : poly(ethylene oxide) (PEO) nanocomposite thin films. Perylene nanoparticles doped into poly(acrylonitrile) (PAN) were used to monitor the temperature change caused due to the nanoparticle plasmon-mediated heating within the polymer fibres and films. Ordered epitaxial perylene films may be used to fabricate a multilayered electroluminescent device.

Packaging

1, 5 g in glass bottle

Параметры

grade	sublimed grade
Quality Level	100,
assay	99.5%
loss	0.5 wt. % loss on heating, 232°C (TGA)
mp	276-279 °C (lit.)
_max	436 nm
fluorescence	_em 447 nm in THF
Orbital energy	HOMO 5.3 eV , LUMO 2.3 eV A
OLED Device Performance	ITO/NPD/ADN:Perylene/Alq₃/Mg:Ag Color: blue Max. Luminance: 8000 Cd/m² Turn-On Voltage: 3.4 V
SMILES string	c1cc2cccc3c4cccc5cccc(c(c1)c23)c45
InChI	1S/C20H12/c1-5-13-6-2-11-17-18-12-4-8-14-7-3-10-16(20(14)18)15(9-1)19(13)17/h1-12H
Inchi Key	CSHWQDPOILHKBI-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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906980-100MG
PFN-Br 906980-100MG
Linear Formula: (C₅₆H₈₀N₂.Br₂)_n

CAS Number: 889672-99-5

Application
PFN-Br is a solution processible, conjugated polymer electrolyte used as interficial layer in high performance organic photovoltaic cells (OPV) and organic light emitting diodes (OLED) to improve the interfacial properties.
OPV devices with PFN-Br interfacial layer showed overall enhanced short-circuit current density, open-circuit voltage, fill factor and corresponding high efficiency in the inverted OPVs. This was attributed to the good contact between ZnO electron extraction layer and the active layer, good interface adhesion between the electron extraction layer and active layer, and enhanced charge transport via suppressed bimolecular recombination.
Recent report of OPV with a record energy conversion efficiency of 17.3% also utilized PFN-Br, spin-coated on top of ZnO to improve the interfacial properties.
Tandem Cell Device performance:
ITO/ZnO/PFN-Br/PBDB-T:F-M/M-PEDOT/ZnO/PTB7- Th:O6T-4F:PC71BM/MoO3/Ag
Voc=1.642 V
Jsc=14.35 mA/cm2
FF=73.7%
PCE=17.3%
PFN-Br finds application in a wide range of areas:
OPV interficial layer (metalic oxide compact layer)
OLED electron transport layer
Perovskite solar cells
Flexible printed electronics
Cationic polymer electrolyte
Anion exchange material
Light emitting electrochemical cells

Other Notes
Recommend to use 0.2 mg/ml concentration for electron-transport interfacial layer in OPV.
Параметры

form solid

mol wt M_w 30,000-50,000 by GPC

color beige to yellow

solubility DMF: soluble, DMSO: soluble, alcohol: soluble, chloroform: insoluble, water: soluble

PDI 23.2

Safety Information

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable
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PFN-DOF

Linear Formula:	(C₅₂H₇₀N₂)_n
CAS Number:	673474-75-4
NACRES:	NA.23

Phosphorescent host material. Polymer for use in electron transport layer in OPV and OLED applications.

Параметры

Quality Level	100,
form	solid
mol wt	M_w 5,000-10,000
solubility	chloroform: soluble, dichloromethane: soluble, toluene: soluble
_max	378 nm in dichloromethane
fluorescence	_em 414 nm in dichloromethane (PL)

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Phen-NaDPO 913758-100MG

Empirical Formula (Hill Notation):	C₃₄H₂₃N₂OP
CAS Number:	1480371-38-7
Molecular Weight:	506.53
MDL number:	MFCD31811570

Application

Phen-NaDPO is a universal cathode modifier for organic optoelectronics. Phen-NaDPO can significantly lower the work function of the Ag metal as well as ITO and HOPG.
It lowers the energy loss between organic layer and the metal electrode, results in higher acheiveable efficiency for organic solar cells. It is also used as cathode interfacial material for inverted Perovskite solar cells, and electron transport materials for Perovskite solar cells and other organic electronic devices in general.

Параметры

assay	98%
Quality Level	100,
form	powder
transition temp	T_g ~116 °C
solubility	soluble (Soluble in polar and weakly polar solvents such as isopropanol, toluene and xylenes)
semiconductor properties	(mobility=0.0001-0.001 cm²/V·s) (electron)

Safety Information

WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Phenanthrene

Empirical Formula (Hill Notation):	C₁₄H₁₀
CAS Number:	85-01-8
Molecular Weight:	178.23
Beilstein/REAXYS Number:	1905428
EC Number:	201-581-5
MDL number:	MFCD00001168
PubChem Substance ID:	329761717
NACRES:	NA.23

Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) which consists of three benzene rings that are prepared by Bardhan-Sengupta phenanthrene synthesis. Its properties include low volatility, high toxicity and resistance to microbial biodegradation.

Packaging

1, 5 g in glass bottle

Параметры

grade	sublimed grade
Quality Level	100,
assay	≥99.5%
form	crystals, powder and chunks, tubes
bp	340 °C (lit.)
mp	98-100 °C (lit.)
density	1.063 g/mL at 25 °C (lit.)
SMILES string	c1ccc2c(c1)ccc3ccccc23
InChI	1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H
Inchi Key	YNPNZTXNASCQKK-UHFFFAOYSA-N

Safety Information

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P264 - P270 - P273 - P301 + P312 - P391 - P501
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Phenanthridine

Empirical Formula (Hill Notation):	C₁₃H₉N
CAS Number:	229-87-8
Molecular Weight:	179.22
Beilstein/REAXYS Number:	120204
EC Number:	205-934-4
MDL number:	MFCD00004989
PubChem Substance ID:	24855920

assay	≥99%
purified by	sublimation
bp	349 °C/769 mmHg (lit.)
mp	104-107 °C (lit.)
SMILES string	c1ccc2c(c1)cnc3ccccc23
InChI	1S/C13H9N/c1-2-6-11-10(5-1)9-14-13-8-4-3-7-12(11)13/h1-9H
InChI key	RDOWQLZANAYVLL-UHFFFAOYSA-N

Safety Information

pictograms	GHS05, GHS06
signalword	Danger
hcodes	H301-H315-H318-H335
pcodes	P261-P280-P301 + P310-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,
RIDADR	UN 2811 6.1 / PGIII
WGK Germany	3
Flash Point F	212 °F
Flash Point C	100 °C

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Phenazine

Empirical Formula (Hill Notation):	C₁₂H₈N₂
CAS Number:	92-82-0
Molecular Weight:	180.21
Beilstein/REAXYS Number:	126500
EC Number:	202-193-9
MDL number:	MFCD00005023
PubChem Substance ID:	24898186
NACRES:	NA.23

Quality Level	100,
assay	98%
mp	172-176 °C (lit.)
fluorescence	_ex 426 nm; _em 471 nm in ethyl acetate
SMILES string	c1ccc2nc3ccccc3nc2c1
InChI	1S/C12H8N2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H
InChI key	PCNDJXKNXGMECE-UHFFFAOYSA-N
Gene Information	human ... PRNP(5621)

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Phenothiazine

Empirical Formula (Hill Notation):	C₁₂H₉NS
CAS Number:	92-84-2
Molecular Weight:	199.27
Beilstein/REAXYS Number:	143237
EC Number:	202-196-5
MDL number:	MFCD00005015
PubChem Substance ID:	24898205
NACRES:	NA.23

Employed in the preparation of carbazoles and piperazines, and charge-transfer semiconducting complexes.

Packaging

25, 500 g in glass bottle
1 kg in glass bottle

Параметры

Quality Level	200
assay	≥98%
bp	371 °C (lit.)
mp	182-187 °C (lit.)
SMILES string	N1c2ccccc2Sc3ccccc13
InChI	1S/C12H9NS/c1-3-7-11-9(5-1)13-10-6-2-4-8-12(10)14-11/h1-8,13H
InChI key	WJFKNYWRSNBZNX-UHFFFAOYSA-N

Safety Information

pictograms	GHS07,GHS08,GHS09
signalword	Warning
hcodes	H302 - H317 - H373 - H410
pcodes	P260 - P273 - P280 - P301 + P312 - P302 + P352 - P314
Target Organs	Blood
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum octaethylporphyrin 673625-100MG

Empirical Formula (Hill Notation):	C₃₆H₄₄N₄Pt
CAS Number:	31248-39-2
Molecular Weight:	727.84
MDL number:	MFCD00672301
PubChem Substance ID:	24885168
NACRES:	NA.23

General description

PtOEP is an oxygen-quenchable luminescent dye.

Application

Platinum octaethylporphyrin (PtOEP) may be used as a fluorescent dye in the fabrication of polymer- and silica-based oxygen sensors. It is used as a red triplet emitting material with high external quantum yields for OLEDs. PtOEP is used as a dopant in host materials like CBP and Alq3. Its red emission is near 650 nm depending on host material and processing conditions.

Packaging

100 mg in glass insert

Параметры

Quality Level	100
assay	95%
mp	>300 °C
_max	381 nm
Orbital energy	HOMO 5.3 eV , LUMO 3.2 eV A
OLED Device Performance	ITO/NPD/Alq₃:PtOEP (4%)/Mg:Ag Color: red Max. Luminance: 100 Cd/m² Max. EQE: 2.5 % , ITO/NPD/CBP:PtOEP(6%)/Mg:Ag Color: red Max. Luminance: 100 Cd/m² Max. EQE: 0.8 %
SMILES string	CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Pt]n34)c(CC)c5CC
InChI	1S/C36H44N4.Pt/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
InChI key	WAODGUVBNLMTSF-XTPDIVBZSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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PO-T2T, >=99% (HPLC) 907073-250MG

Empirical Formula (Hill Notation):	C₅₇H₄₂N₃O₃P₃
CAS Number:	1646906-26-4
Molecular Weight:	909.88

Application

PO-T2T is an electron transport/hole blocking material in OLED, or an electron acceptor material in organic electronics.
An efficient action of radical-based OLEDs, whose emission originates from a spin doublet, rather than a singlet or triplet exciton was demonstrated in a study published in Nature.
While the emission process is still spin-allowed in these OLEDs, the efficiency limitations imposed by triplet excitons are circumvented for doublets. Using a luminescent radical emitter, an OLED with maximum external quantum efficiency of 27% at a wavelength of 710nm-the highest reported value for deep-red and infrared LEDs was achieved. In this very efficient OLEDs, selective hole injection into the HOMO and electron injection to the SOMO was achieved imploying TAPC as the hole transport layer, and PO-T2T as the electron transport layer to form the fluorescent doublet excited state with near-unity internal quantum efficiency.
Device configuration:
ITO/MoO3 (3 nm)/ TAPC (35 nm)/CBP:TTM-3NCz (3.0 wt%; (40 nm) and CBP:TTM3PCz (3.0 wt%; 25 nm)/B3PYMPM (10 nm)/PO-T2T (70 nm)/LiF (0.8 nm)/Al (100 nm).
The first Tandem, All-exciplex-based WOLED was constructed using PO-T2T for a device structure configured by two parallel blend layers of mCP/PO-T2T and DTAF/PO-T2T, generating blue and yellow exciplex emission, respectively. The resulting device demonstrates for the first time a tandem, all-exciplex-based white-light OLED (WOLED) with excellent efficiencies ext: 11.6%, c: 27.7 cd/A, and p: 15.8 ml/W with CIE(0.29, 0.35) and CRI 70.6 that are nearly independent of EL intensity. The tandem architecture and blend-layer donor/acceptor (1:1) configuration are two key elements that fully utilize the exciplex delay fluorescence, providing a paragon for the use of low-cost, abundant organic compounds en route to commercial WOLEDs.

Параметры

grade	sublimed grade (>99% (HPLC))
description	PL-295, 379 nm (in CH₂Cl₂)
form	solid
mol wt	M_w 909.8 g/mol
color	white
_max	272 nm in dichloromethane
Orbital energy	HOMO -6.8 eV , LUMO -2.8 eV A
storage temp.	15-25°C

Safety Information

WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Poly(2,5-bis(3-sulfonatopropoxy)-1,4-phenylene, disodium salt-alt-1,4-phenylene) 659223-500MG

Linear Formula:	(C₁₈H₁₈Na₂O₈S₂)_n
MDL number:	MFCD07785535
NACRES:	NA.23

General description

Poly(2,5-bis(3-sulfonatopropoxy)-1,4-phenylene, disodium salt-alt-1,4-phenylene) (PPP-OPSO3) is a water soluble conjugating polymer that can be used as a donor molecule. It has a poly(p-phenylene) skeleton with each repeating unit having two phenylene groups. It can be used for a variety of optoelectronic applications.

Application

PPP-OPSO3 is a π-conjugating polymer that can be used in organic light emitting diodes (OLEDs), thin film transistors (TFTs), and flexible organic solar cells.
A water-soluble polyanionic blue-light emitting polymer.

Packaging

500 mg in glass insert

Features and Benefits

Ready to use, water-soluble light, emitting material, more soluble than MPS-PPV.

Параметры

Quality Level	100,
solubility	H₂O: soluble
_max	208 nm (in deoxygenated water)(lit.)
fluorescence	_ex 322 nm; _em 424 nm in H₂O, _ex 363 nm; _em 410 nm in H₂O(lit.), _em 424 nm in H₂O

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Poly(3,4-ethylenedioxythiophene), bis-poly(ethyleneglycol), lauryl terminated 687316-25G

NACRES:

NA.23

General description

Please follow this link for Aedotron/Oligotron selection guide table,.
Aedotron™ polymers are solvent-dispersable forms of PEDOT. These are copolymers of doped PEDOT and a flexible, soluble polymer such as poly(ethylene glycol) (PEG). These colloidal dispersions are stabilized by the highly solvated PEG chains which sterically limit the aggregation of the PEDOT blocks. Aedotron polymers are neither acidic nor corrosive, it easily disperses in polar aprotic solvents. Aedotron™ C3-NM is a triblock copolymer.

Application

Nitromethane dispersions can be used to cast thin films on glass, ITO, silicon wafers and many polymeric substrates. Compatibility of the polymeric substrate with nitromethane should be tested in each case. Coat the substrate with a "pool" of the nitromethane dispersion. Thin transparent films are typically spun at 1000 RPM or higher speeds, but more conducting films can be obtained at lower speeds. A single layer spun at 1000 RPM is typically 75 nm thick.
Conducting polymer dispersion suitable for making conducting films, anti-static layers and transparent electrodes for electroluminescent lamps.

Packaging

25 g in glass bottle

Features and Benefits

The copolymer structure renders the conducting polymer PEDOT highly dispersible in organic solvents. Nitromethane has a suitable volatility for spin coating.

Caution

Store this product at room temperature (do not refrigerate or freeze). Some settling will normally occur. Agitate, sonicate, and filter prior to use. A plug of glass wool in a pipette can be used for easy filtration. The shelf life of this product will vary depending on how it is stored and handled. Product should be discarded if heavy aggregation occurs, or if sonication / filtering are inadequate to produce a good casting solution.

Legal Information

Aedotron is a trademark of TDA Research, Inc.

Параметры

form	liquid (dispersion)
Quality Level	100,
contains	perchlorate as dopant
composition	Acetonitrile, 4-8 wt. % , Aedotron^™- C3 polymer, 0.2-0.7 wt. % , Nitromethane, 90-95 wt. % , proprietary processing additive, 0.1-0.7 wt. % , Propylene glycol, 0.0-0.3 wt. %
concentration	0.5-0.9 wt. % (content of dispersion), 0.7 wt. % (dispersion in nitromethane)
surface resistivity	600-3000 /sq
transmittance	70-85%
particle size	200-600 nm
conductivity	10-60 S/cm

Safety Information

pictograms	GHS02,GHS07,GHS08
signalword	Danger
hcodes	H225 - H302 + H332 - H351 - H361fd
pcodes	P201 - P202 - P210 - P301 + P312 - P304 + P340 + P312 - P308 + P313
RIDADR	UN1261 - class 3 - PG 2 - Nitromethane, solution
WGK Germany	WGK 2
Flash Point F	71.6 °F - closed cup
Flash Point C	22 °C - closed cup

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Poly(3,5 pyridine)

Linear Formula:	(C₅H₃N)_n
CAS Number:	97702-63-1
MDL number:	MFCD05665544

250 mg in glass insert

Application

Light-emitting conjugated polymer.

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Poly(3-decyloxythiophene-2,5-diyl) 693391-500MG

Linear Formula:	(C₁₄H₂₂OS)_n
CAS Number:	150678-86-7
NACRES:	NA.23

General description

Regioregular.

Application

P3DOT may be used in solar cells.1,

Packaging

500 mg in glass bottle

Параметры

mol wt	M_n <10,000
concentration	0.5 % (w/v) in THF
density	0.877 g/mL at 25 °C
fluorescence	_ex 350 nm; _em 427 nm in THF

Safety Information

pictograms	GHS02,GHS07,GHS08
signalword	Danger
hcodes	H225 - H302 - H319 - H335 - H351
pcodes	P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Target Organs	Respiratory system
Supp Hazards	EUH019
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2056 3 / PGII
WGK Germany	WGK 3
Flash Point F	-9.9 °F
Flash Point C	-23.3 °C

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495344-1G

Poly(3-decylthiophene-2,5-diyl) 495344-1G

Linear Formula: (C₁₄H₂₂S)_n

CAS Number: 110851-65-5

MDL number: MFCD00677713

NACRES: NA.23

General description
Poly(3-decylthiophene-2,5-diyl) (P3DT) is a conducting polymer with excellent electrical and optical properties. It is soluble in most of the organic solvents and can be used in a variety of electrochemical applications.
Application
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
P3DT is a conjugated polymer that can be used for a variety of applications, which include anticorrosive additives in paints, organic photovoltaic cells, polymeric solar cells, and field effect transistors.
Conducting polymer. Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
Packaging
1 g in glass bottle
Packaged in glass bottles
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Параметры

Quality Level 100,

mol wt average M_n ~30,000, average M_w ~42,000

color black

fluorescence _ex 441 nm; _em 567 nm in chloroform

Safety Information

Personal Protective Equipment Eyeshields,, Gloves,, type N95 (US),

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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Poly(3-dodecylthiophene-2,5-diyl) 510866-1G

CAS Number:	137191-59-4
MDL number:	MFCD00677714
NACRES:	NA.23

General description

Poly(3-dodecylthiophene-2,5-diyl) (P3DDT) is a poly(3-alkylthiophene) based conducting polymer that shows reversible electrochemistry with high conductivity. It is a regioregular polymer that can be used in the development of a variety of organic electronics based devices.

Application

This material has solid state properties. Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
P3DDT can be used as a conjugating polymer in the fabrication of electrochemical devices, which include polymeric solar cells, chemical sensors and field effect transistors.
Conducting polymer.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.

Packaging

1 g in glass bottle
Packaged in glass bottles

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Параметры

mol wt	average M_n 30,000, average M_w 70,000
solubility	chloroform, methylene chloride, toluene, and THF: soluble
fluorescence	_ex 416 nm; _em 545 nm in chloroform
OPV Device Performance	ITO/PEDOT:PSS/P3DDT/PC61BM (1:3)/LiF/Al Short-circuit current density (J_sc): 2.9 mA/cm² Open-circuit voltage (V_oc): 0.6 V Fill Factor (FF): 0.38 Power Conversion Efficiency (PCE): 0.65 %

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Poly(3-octylthiophene-2,5-diyl) 510831-1G

Linear Formula:	(C₁₂H₁₈S)_n
CAS Number:	104934-51-2
MDL number:	MFCD00241412
NACRES:	NA.23

General description

Poly(3-octylthiophene-2,5-diyl) (P3OT) is an alkylthiophene based conductive polymer with high electroluminescence. It is soluble in most of the organic solvents and can be prepared by the electrochemical polymerization of 3-octylthiophene (3OT). It has hydrophobic properties and can be used as a transducer for ion selective electrodes.
Poly(3-alkylthiophene)s exhibit thermo- and solvatochromism. Regiorandom poly(3-octylthiophene) shows relatively weak red PL in dilute solution. The emission is largely quenched in concentrated solutions and solid thin films.1:1 (head-to-head):(head-to-tail) linkages of regioisomers.

Application

P3OT forms a nanocomposite with carbon nanotubes (CNTs) for devising a high performance semiconducting material. It can also be used as a π-conjugating polymer for the fabrication of organic electronic based devices which include polymeric diodes, solar cells and photovoltaic modules.
Used in organic field-effect transistors and in polymer-based solar cells.
Conducting polymer.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.

Packaging

1 g in glass bottle
Packaged in glass bottles

Features and Benefits

Good processability, environmental stability and electroactivity.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Параметры

Quality Level	100,
mol wt	average M_n 22,000, average M_w 36,600
color	red
mp	198-211 °C
solubility	chloroform, methylene chloride, toluene, and THF: soluble
fluorescence	_ex 419 nm; _em 550 nm in chloroform
OPV Device Performance	ITO/PEDOT:PSS/P3OT:PC61BM (1:2)/LiF/Al Short-circuit current density (J_sc): 5.55 mA/cm² Open-circuit voltage (V_oc): 0.5 V Fill Factor (FF): 0.33 Power Conversion Efficiency (PCE): 0.91 %

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Empirical Formula (Hill Notation):	C₆₂H₅₀N₄
CAS Number:	260550-65-0
Molecular Weight:	851.09
NACRES:	NA.23

mol wt	average M_n 340,000, average M_w 1,750,000
Quality Level	100,

Linear Formula:	(C₅₆H₈₀N₂.Br₂)_n
CAS Number:	889672-99-5

Linear Formula:	(C₂₇H₃₄)_m(C₁₇H₂₄O₂)_n
MDL number:	MFCD07785542
NACRES:	NA.23

mp	>300 °C
solubility	chloroform: soluble, hexane: soluble
fluorescence	_ex 281 nm; _em 499 nm in chloroform

Linear Formula:	[CH₂CH(C₁₀H₇)]_n
CAS Number:	29793-40-6
MDL number:	MFCD00274663
PubChem Substance ID:	24878537
NACRES:	NA.23

MDL number:	MFCD08705354
PubChem Substance ID:	24881221
NACRES:	NA.23

_max	248 nm
SMILES string	c1ccc(nc1)-c2cccnc2
Gene Information	human ... CYP2A6(1548)

Linear Formula:	(C₂₂H₃₄O₈)_n
CAS Number:	221244-49-1
MDL number:	MFCD06798803
NACRES:	NA.23

Linear Formula:	(C₅₈H₉₀N₂O₄)_n
MDL number:	MFCD06798804
NACRES:	NA.23

Linear Formula:	(C₄₂H₅₈N₂O₄)_n
CAS Number:	151897-69-7
MDL number:	MFCD06412341
NACRES:	NA.23

Linear Formula:	(C₂₄H₃₀)_n
CAS Number:	236407-36-6
MDL number:	MFCD06202195

solubility	H₂O: insoluble, THF: slightly soluble, chloroform: slightly soluble, ethanol: insoluble, methanol: insoluble
_max	496 nm
fluorescence	_ex 482 nm; _em 547 nm in chloroform

Linear Formula:	(C₂₄H₃₈)_n
MDL number:	MFCD07785536
NACRES:	NA.23

Linear Formula:	(C₁₂H₈)_n
CAS Number:	124825-04-3
MDL number:	MFCD07785537
NACRES:	NA.23

mol wt	M_w/M_n <1.20, average M_n ~50,000
transition temp	T_g (DSC) 145 °C (onset)
InChI	1S/C12H10/c1-2-10-7-8-11-5-3-4-6-12(11)9-10/h2-9H,1H2
Inchi Key	KXYAVSFOJVUIHT-UHFFFAOYSA-N

mol wt	M_w/M_n 1.15, average M_n ~20,000
transition temp	T_g (DSC) 141 °C (onset)
InChI	1S/C12H10/c1-2-10-7-8-11-5-3-4-6-12(11)9-10/h2-9H,1H2
Inchi Key	KXYAVSFOJVUIHT-UHFFFAOYSA-N

mol wt	M_w 54,000 (typical)
color	black
solubility	chlorinated solvents: soluble (partially soluble in THF, diethylether)
fluorescence	_ex 440 nm; _em 567 nm in chloroform
M_w/M_n	2.3 (typical)

Linear Formula:	(C₁₄H₂₂S)_n
CAS Number:	110851-65-5
MDL number:	MFCD00677713
NACRES:	NA.23

Каталог

OLED & PLED Materials

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