Inorganic Catalysts

5, 25 g in glass bottle

Quality Level	100,
assay	98%
reaction suitability	core: yttrium, reagent type: catalyst
SMILES string	[Y+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI	1S/3CHF3O3S.Y/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
Inchi Key	JPJIEXKLJOWQQK-UHFFFAOYSA-K

Reactant for the preparation of flat HfO2 films
In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome. Solutions of the catalyst should be made using anhydrous solvents and used shortly after preparation.

Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Yttrium(III) tris(isopropoxide)

Empirical Formula (Hill Notation):	C₉H₂₁O₃Y
CAS Number:	2172-12-5
Molecular Weight:	266.17
MDL number:	MFCD00015641
PubChem Substance ID:	329760287

Stereoselective conjugate addition reactions
Ring-opening polymerizations
Generation of reactive enolates by enantioselective protonation reactions
Cyano-phosphorylation of enone and allylic substitution
Synthesis of nanocomposites

500 mg in glass bottle

Product of Kojundo Chemical Laboratory Co., Ltd

Quality Level	100,
form	solid
reaction suitability	core: yttrium, reagent type: catalyst
SMILES string	CC(C)O[Y](OC(C)C)OC(C)C
InChI	1S/3C3H7O.Y/c31-3(2)4;/h33H,1-2H3;/q3*-1;+3
InChI key	PYLIDHFYDYRZSC-UHFFFAOYSA-N

Reducing agent; used for preparation of organozinc reagents, Reformatsky reagents, and the Simmons-Smith reagent (cyclopropanation).

pictograms	GHS02,GHS07
signalword	Warning
hcodes	H228 - H315 - H319 - H335
pcodes	P210 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 3

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Zinc

Empirical Formula (Hill Notation):	Zn
CAS Number:	7440-66-6
Molecular Weight:	65.39
MDL number:	MFCD00011291
PubChem Substance ID:	57647890
NACRES:	NA.22

100 g in poly bottle
1, 5 kg in poly bottle

vapor pressure	1 mmHg ( 487 °C)
Quality Level	200,
assay	98%
form	dust
reaction suitability	core: zinc, reagent type: catalyst
resistivity	5.8 µ-cm, 20°C
particle size	<10 µm
bp	907 °C (lit.)
mp	420 °C (lit.)
density	7.133 g/mL at 25 °C (lit.)
SMILES string	[Zn]
InChI	1S/Zn
InChI key	HCHKCACWOHOZIP-UHFFFAOYSA-N

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273 - P391 - P501
Personal Protective Equipment	Eyeshields,, Gloves,
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc 565148-1KG

Empirical Formula (Hill Notation):	Zn
CAS Number:	7440-66-6
Molecular Weight:	65.39
EC Number:	231-175-3
MDL number:	MFCD00011291
PubChem Substance ID:	24879943
NACRES:	NA.22

1 kg in glass bottle

Used as reducing agent; used for preparation of organozinc reagents

vapor pressure	1 mmHg ( 487 °C)
Quality Level	100,
assay	99%
form	granular
reaction suitability	core: zinc, reagent type: catalyst
resistivity	5.8 μΩ-cm, 20°C
particle size	30-100 mesh
bp	907 °C (lit.)
mp	420 °C (lit.)
density	7.133 g/mL at 25 °C (lit.)
SMILES string	[Zn]
InChI	1S/Zn
InChI key	HCHKCACWOHOZIP-UHFFFAOYSA-N

Used as a dietary supplement and in lozenges used to treat the common cold.
Employed in the synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis. Also used in the ultrasonic preparationof zinc sulfide nanoparticles coated on silica particles.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc acetate

Empirical Formula (Hill Notation):	C₄H₆O₄Zn
Linear Formula:	(CH₃CO₂)₂Zn
CAS Number:	557-34-6
Molecular Weight:	183.48
EC Number:	209-170-2
MDL number:	MFCD00012454
PubChem Substance ID:	24863953
NACRES:	NA.22

25, 100, 500 g in poly bottle

Preparation Note

Preparation of ZnSe nanostructures upon thermolysis of zinc acetate and selenourea in a mixture of octadecylamine and trioctylphosphine oxide.

Quality Level	200,
assay	99.99% trace metals basis
reaction suitability	core: zinc, reagent type: catalyst
impurities	<0.2% water
density	1.84 g/mL at 25 °C (lit.)
SMILES string	CC(=O)O[Zn]OC(C)=O
InChI	1S/2C2H4O2.Zn/c21-2(3)4;/h21H3,(H,3,4);/q;;+2/p-2
Inchi Key	DJWUNCQRNNEAKC-UHFFFAOYSA-L

pictograms	GHS05,GHS07,GHS09
signalword	Danger
hcodes	H302 - H318 - H411
pcodes	P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3

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Zinc bis[bis(trimethylsilyl)amide]

Empirical Formula (Hill Notation):	C₁₂H₃₆N₂Si₄Zn
Linear Formula:	[[(CH₃)₃Si]₂N]₂Zn
CAS Number:	14760-26-0
Molecular Weight:	386.16
MDL number:	MFCD01321225
PubChem Substance ID:	24866173
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	core: zinc, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	12.5 °C (lit.)
density	0.957 g/mL at 25 °C (lit.)
greener alternative category	Aligned,
SMILES string	C[Si](C)(C)N([Zn]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI	1S/2C6H18NSi2.Zn/c21-8(2,3)7-9(4,5)6;/h21-6H3;/q2*-1;+2
InChI key	ZCCUYQBZUVUONI-UHFFFAOYSA-N

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H261 - H314
pcodes	P231 + P232 - P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3129 8(4.3) / PGII
WGK Germany	WGK 3
Flash Point F	105.8 °F - closed cup
Flash Point C	41 °C - closed cup

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Zinc chloride tetrahydrofuran complex (1:2)

Empirical Formula (Hill Notation):	Cl₂Zn · 2C₄H₈O
CAS Number:	24640-76-4
Molecular Weight:	280.51
MDL number:	MFCD09751421
PubChem Substance ID:	329764465
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	core: zinc, reagent type: catalyst
mp	113-118 °C
SMILES string	Cl[Zn]Cl.C1CCOC1.C2CCOC2
InChI	1S/2C4H8O.2ClH.Zn/c21-2-4-5-3-1;;;/h21-4H2;2*1H;/q;;;;+2/p-2
InChI key	YKZBFJVZMFIZLW-UHFFFAOYSA-L

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
RIDADR	UN 3261 8 / PGII
WGK Germany	nwg

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Zinc diethyldithiocarbamate

Empirical Formula (Hill Notation):	C₁₀H₂₀N₂S₄Zn
Linear Formula:	[(C₂H₅)₂NCS₂]₂Zn
CAS Number:	14324-55-1
Molecular Weight:	361.93
EC Number:	238-270-9
MDL number:	MFCD00064798
PubChem Substance ID:	24859807
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	core: zinc, reagent type: catalyst
mp	178-181 °C (lit.)
SMILES string	CCN(CC)C(=S)S[Zn]SC(=S)N(CC)CC
InChI	1S/2C5H11NS2.Zn/c21-3-6(4-2)5(7)8;/h23-4H2,1-2H3,(H,7,8);/q;;+2/p-2
InChI key	RKQOSDAEEGPRER-UHFFFAOYSA-L

pictograms	GHS07,GHS08,GHS09
signalword	Warning
hcodes	H302 - H315 - H317 - H319 - H335 - H373 - H410
pcodes	P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P314
Target Organs	Respiratory system
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc dimethyldithiocarbamate

Empirical Formula (Hill Notation):	C₆H₁₂N₂S₄Zn
Linear Formula:	(CH₃)₂NCSSZnSCSN(CH₃)₂
CAS Number:	137-30-4
Molecular Weight:	305.82
Beilstein/REAXYS Number:	3707008
EC Number:	205-288-3
MDL number:	MFCD00064797
PubChem Substance ID:	24859808

Quality Level	200,
assay	97%
reaction suitability	core: zinc, reagent type: catalyst
mp	248-257 °C (lit.)
SMILES string	CN(C)C(=S)S[Zn]SC(=S)N(C)C
InChI	1S/2C3H7NS2.Zn/c21-4(2)3(5)6;/h21-2H3,(H,5,6);/q;;+2/p-2
Inchi Key	DUBNHZYBDBBJHD-UHFFFAOYSA-L

pictograms	GHS05,GHS06,GHS08,GHS09
signalword	Danger
hcodes	H302 - H317 - H318 - H330 - H335 - H373 - H410
pcodes	P273 - P280 - P301 + P312 - P304 + P340 + P310 - P305 + P351 + P338 - P314
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN2811 - class 6.1 - PG 2 - EHS - RQ - Toxic solids, organic, n.o.s. HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc di[bis(trifluoromethylsulfonyl)imide] 720755-1G

Empirical Formula (Hill Notation):	C₄F₁₂N₂O₈S₄Zn
CAS Number:	168106-25-0
Molecular Weight:	625.68
MDL number:	MFCD16621474
PubChem Substance ID:	329763747
NACRES:	NA.22

Catalyst for:

Enantioselective Friedel-Crafts alkylation of pyrroles with -CF3 acrylates
Stereoselective Diels-Alder reaction
Tandem cyclopropane ring-opening / Conia-ene cyclization
Aromatic nitration

Quality Level	100,
assay	95%
reaction suitability	core: zinc, reagent type: catalyst
mp	143-147 °C
SMILES string	FC(F)(F)S(=O)(=O)N([Zn]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
InChI	1S/2C2F6NO4S2.Zn/c23-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q2-1;+2
InChI key	QEORIOGPVTWFMH-UHFFFAOYSA-N

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc methoxide

Empirical Formula (Hill Notation):	C₂H₆O₂Zn
Molecular Weight:	127.46
MDL number:	MFCD00799181
PubChem Substance ID:	329762394
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	core: zinc, reagent type: catalyst
mp	107-113 °C
SMILES string	CO[Zn]OC
InChI	1S/2CH3O.Zn/c21-2;/h21H3;/q2*-1;+2
InChI key	JXNCWJJAQLTWKR-UHFFFAOYSA-N

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc neodecanoate CDS001282-1G

Empirical Formula (Hill Notation):	C₂₀H₃₈O₄Zn
CAS Number:	84282-26-8
Molecular Weight:	407.90
EC Number:	248-370-4
MDL number:	MFCD00014384
PubChem Substance ID:	329778494

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

reaction suitability	core: zinc, reagent type: catalyst
SMILES string	CC(C)(C)CCCCCC(=O)O[Zn]OC(=O)CCCCCC(C)(C)C
InChI	1S/2C10H20O2.Zn/c21-10(2,3)8-6-4-5-7-9(11)12;/h24-8H2,1-3H3,(H,11,12);/q;;+2/p-2
InChI key	LFOXXKXKYHIANI-UHFFFAOYSA-L

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319
pcodes	P302 + P352 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc peroxide 481424-1KG

Empirical Formula (Hill Notation):	O₂Zn
Linear Formula:	ZnO₂
CAS Number:	1314-22-3
Molecular Weight:	97.39
MDL number:	MFCD00137469
PubChem Substance ID:	24871757
NACRES:	NA.23

Solutions of zinc peroxide can be prepared from zinc hydroxide precursors, the sol can be subsequently used to prepare zinc nanoparticles.

Quality Level	200,
assay	50-60%
form	powder
reaction suitability	reagent type: catalyst core: zinc, reagent type: oxidant
mp	212 °C (dec.) (lit.)
density	1.57 g/mL at 25 °C (lit.)
SMILES string	[Zn++].[O-][O-]
InChI	1S/O2.Zn/c1-2;/q-2;+2
InChI key	IPTOGCUGCFHDSS-UHFFFAOYSA-N

pictograms	GHS03,GHS07,GHS09
signalword	Danger
hcodes	H271 - H315 - H319 - H410
pcodes	P210 - P220 - P264 - P273 - P302 + P352 - P305 + P351 + P338
RIDADR	UN 1516 5.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc phosphide

Empirical Formula (Hill Notation):	P₂Zn₃
Linear Formula:	Zn₃P₂
CAS Number:	1314-84-7
Molecular Weight:	258.12
EC Number:	215-244-5
MDL number:	MFCD00049631
PubChem Substance ID:	57646758
NACRES:	NA.22

Quality Level	100,
assay	≥19% active phoshor (P) basis
form	powder
reaction suitability	core: zinc, reagent type: catalyst
storage temp.	2-8°C
SMILES string	[Zn]=P[Zn]P=[Zn]
InChI	1S/2P.3Zn
Inchi Key	NQDYSWQRWWTVJU-UHFFFAOYSA-N

Rieke® Zinc metal can be used to reduce common organic functional groups such as aromatic nitro, conjugated aldehydes, arylacetylenes, and phenylpropiolates.

pictograms	GHS02,GHS06,GHS09
signalword	Danger
hcodes	H260 - H300 - H410
pcodes	P223 - P231 + P232 - P264 - P273 - P370 + P378 - P422
Supp Hazards	EUH029 - EUH032
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P2 (EN 143) respirator cartridges,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 1714 6.1(4.3) / PGI
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc preparation

Empirical Formula (Hill Notation):	Zn
Linear Formula:	Zn
CAS Number:	7440-66-6
Molecular Weight:	65.39
MDL number:	MFCD00011291
PubChem Substance ID:	24873288
NACRES:	NA.22

100 mL in Sure/Seal™

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Quality Level	100,
reaction suitability	core: zinc, reagent type: catalyst
concentration	5 g/dL Zn⁺² in THF
density	0.949 g/mL at 25 °C
storage temp.	2-8°C
SMILES string	[Zn]
InChI	1S/Zn
Inchi Key	HCHKCACWOHOZIP-UHFFFAOYSA-N

Zinc sulfide can be used:

pictograms	GHS02,GHS07,GHS08,GHS09
signalword	Danger
hcodes	H225 - H302 - H319 - H335 - H336 - H351 - H410
pcodes	P201 - P210 - P273 - P301 + P312 + P330 - P305 + P351 + P338 - P308 + P313
Supp Hazards	EUH018 - EUH019
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1993BF 3 / PGII
WGK Germany	WGK 2
Flash Point F	1.0 °F - closed cup
Flash Point C	-17.22 °C - closed cup

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Zinc sulfide

Empirical Formula (Hill Notation):	SZn
Linear Formula:	ZnS
CAS Number:	1314-98-3
Molecular Weight:	97.46
EC Number:	215-251-3
MDL number:	MFCD00011301
eCl@ss:	38150412
PubChem Substance ID:	24854689
NACRES:	NA.22

Preparation of flexible transparent conductive coatings essential for fabrication of a variety of printed electronic devices such as flexible displays and solar cells
Prepare a composite CdS-ZnS/Zirconium-titanium phosphate (ZTP) photocatalyst for hydrogen production under visible light
Prepare light-controlled bioelectrochemical sensors based on CdSe/ZnS quantum dots
Catalyst for photocatalytic degradation of organic pollutants
Preparation of color tunable light-emitting diodes (LEDs)
Prepare (CdS-ZnS)-TiO2 combined photocatalysts for electricity production via photoelectrocatalysis
Catalyst for synthesis of spirooxindole derivatives in aqueous medium via Knoevenagel condensation followed by Michael addition
Prepare CdSe/ZnS q uantum dots for chemiluminescent and chemiluminescence resonance energy transfer (CRET) detection of DNA, metal ions, and aptamer-substrate complexes
Preparation of ZnS nanocrystals for ultrasensitive protein detection in terms of multiphonon resonance Raman scattering

To prepare flexible transparent conductive coatings essential for fabrication of a variety of printed electronic devices such as flexible displays and solar cells.
To prepare a composite CdS-ZnS/zirconium-titanium phosphate (ZTP) photocatalyst for hydrogen production under visible light.
To prepare light-controlled bioelectrochemical sensors based on CdSe/ZnS quantum dots.
As a catalyst for the photocatalytic degradation of organic pollutants.
In the preparation of color tunable light-emitting diodes (LEDs).
To prepare (CdS-ZnS)-TiO2 combined photocatalysts for electricity production via photoelectrocatalysis.
As a catalyst for the synthesis of spirooxindole derivatives in aqueous medium via Knoevenagel condensation followed by Michael addition.
To prepare CdSe/ZnS quantum dots for chemiluminescent and chemiluminescence resonance energy transfer (CRET) detection of DNA, metal ions, and aptamer-substrate complexes.
To prepare ZnS nanocrystals for ultrasensitive protein detection in terms of multiphonon resonance Raman scattering.

25, 100 g in glass bottle

Quality Level	200,
assay	99.99% trace metals basis
form	powder
reaction suitability	core: zinc, reagent type: catalyst
particle size	10 μm
density	4.1 g/mL at 25 °C (lit.)
SMILES string	S=[Zn]
InChI	1S/S.Zn
Inchi Key	WGPCGCOKHWGKJJ-UHFFFAOYSA-N

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	nwg
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc trifluoromethanesulfonate

Empirical Formula (Hill Notation):	C₂F₆O₆S₂Zn
Linear Formula:	(CF₃SO₃)₂Zn
CAS Number:	54010-75-2
Molecular Weight:	363.53
Beilstein/REAXYS Number:	4028195
EC Number:	258-922-6
MDL number:	MFCD00013229
PubChem Substance ID:	24857423
NACRES:	NA.22

10, 50 g in glass bottle

Quality Level	200,
assay	98%
reaction suitability	core: zinc, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	300 °C (lit.)
SMILES string	[Zn++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI	1S/2CHF3O3S.Zn/c22-1(3,4)8(5,6)7;/h2(H,5,6,7);/q;;+2/p-2
Inchi Key	CITILBVTAYEWKR-UHFFFAOYSA-L

Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3261 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zinc(II) dibutyldithiocarbamate CDS000589-1G

Empirical Formula (Hill Notation):	C₁₈H₃₆N₂S₄Zn
CAS Number:	136-23-2
Molecular Weight:	474.14
MDL number:	MFCD00067274
PubChem Substance ID:	329777923

reaction suitability	core: zinc, reagent type: catalyst
SMILES string	CCCCN(CCCC)C(=S)S[Zn]SC(=S)N(CCCC)CCCC
InChI	1S/2C9H19NS2.Zn/c21-3-5-7-10(9(11)12)8-6-4-2;/h23-8H2,1-2H3,(H,11,12);/q;;+2/p-2
Inchi Key	BOXSVZNGTQTENJ-UHFFFAOYSA-L

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H315 - H319 - H410
pcodes	P273 - P302 + P352 - P305 + P351 + P338
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zirconium acrylate 686239-25G

Empirical Formula (Hill Notation):	C₁₂H₁₂O₈Zr
Linear Formula:	Zr(CH₂CHCO₂)₄
CAS Number:	60653-57-8
Molecular Weight:	375.44
MDL number:	MFCD00080386
PubChem Substance ID:	329761031
NACRES:	NA.23

25 g in poly bottle

Zirconium-containing multifunctional acrylate useful for producing cured, transparent films with high refractive indices.
Please see product no. 686204 for additional application and usage information (Aldrich Technical Bulletin AL-238 )

reaction suitability	reagent type: catalyst core: zirconium
Quality Level	100,
SMILES string	C=CC(=O)O[Zr](OC(=O)C=C)(OC(=O)C=C)OC(=O)C=C
InChI	1S/4C3H4O2.Zr/c41-2-3(4)5;/h42H,1H2,(H,4,5);/q;;;;+4/p-4
Inchi Key	CXNQUHPJUJGOHC-UHFFFAOYSA-J

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Zirconium carboxyethyl acrylate 686247-100G

Empirical Formula (Hill Notation):	C₂₄H₂₈O₁₆Zr
Linear Formula:	Zr(CH₂CHCO₂CH₂CH₂CO₂)₄
CAS Number:	123633-53-4
Molecular Weight:	663.69
MDL number:	MFCD10566999
PubChem Substance ID:	329761032
NACRES:	NA.23

100 g in glass bottle

Quality Level	100,
contains	500 ppm methyl hydroquinone as inhibitor
reaction suitability	reagent type: catalyst core: zirconium
concentration	60% (n-propanol)
bp	100-121 °C
density	1.101 g/mL at 25 °C
SMILES string	C=CC(=O)OCCC(=O)O[Zr](OC(=O)CCOC(=O)C=C)(OC(=O)CCOC(=O)C=C)OC(=O)CCOC(=O)C=C
InChI	1S/4C6H8O4.Zr/c41-2-6(9)10-4-3-5(7)8;/h42H,1,3-4H2,(H,7,8);/q;;;;+4/p-4
InChI key	XQEXAYLRUODZQC-UHFFFAOYSA-J

pictograms	GHS02,GHS05,GHS07
signalword	Danger
hcodes	H225 - H315 - H318 - H335 - H336
pcodes	P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1993C 3 / PGIII
WGK Germany	WGK 3
Flash Point F	59.0 °F - closed cup - Solvent
Flash Point C	15 °C - closed cup - Solvent

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Zirconium(IV) chloride tetrahydrofuran complex (1:2) 395420-5G

Empirical Formula (Hill Notation):	C₈H₁₆Cl₄O₂Zr
Linear Formula:	ZrCl₄ · 2OC₄H₈
CAS Number:	21959-01-3
Molecular Weight:	377.25
MDL number:	MFCD00145367
PubChem Substance ID:	24864163
NACRES:	NA.23

vapor pressure	152 mmHg ( 25 °C)(lit.)
Quality Level	100,
assay	99%
form	powder
reaction suitability	reagent type: catalyst core: zirconium
mp	175-177 °C (lit.)
Featured Industry	Battery Manufacturing
storage temp.	2-8°C
SMILES string	Cl[Zr](Cl)(Cl)Cl.C1CCOC1.C2CCOC2
InChI	1S/2C4H8O.4ClH.Zr/c21-2-4-5-3-1;;;;;/h21-4H2;4*1H;/q;;;;;;+4/p-4
InChI key	VDJJKYYENYIHFF-UHFFFAOYSA-J

pictograms	GHS02,GHS05,GHS07
signalword	Danger
hcodes	H228 - H302 + H312 + H332 - H314
pcodes	P210 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 2925 8(4.1) / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[(IPr)AgCl] 732443-1G

Empirical Formula (Hill Notation):	C₂₇H₃₆AgClN₂
CAS Number:	873297-19-9
Molecular Weight:	531.91
MDL number:	MFCD15072152
PubChem Substance ID:	329764730
NACRES:	NA.22

Product of Umicore

Additional information available at www.pmc.umicore.com,

Quality Level	100,
assay	97%
reaction suitability	reagent type: catalyst
mp	265-270 °C
SMILES string	CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=[Ag]/Cl)c3c(cccc3C(C)C)C(C)C
InChI	1S/C27H36N2.Ag.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;;1H/q;+1;/p-1
Inchi Key	GNVDTUAJUVJOFQ-UHFFFAOYSA-M

100, 500 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[(IPr)AuCl]

Empirical Formula (Hill Notation):	C₂₇H₃₆AuClN₂
CAS Number:	852445-83-1
Molecular Weight:	621.01
MDL number:	MFCD09839143
PubChem Substance ID:	329761813
NACRES:	NA.22

Gold Catalysts — 21st Century ′Gold Rush′,

Catalyst use in the hydration of alkynes

Product of Umicore

Additional information available at www.pmc.umicore.com,

Quality Level	100,
reaction suitability	core: gold, reagent type: catalyst
mp	298 °C
storage temp.	2-8°C
SMILES string	CC(C)c1cccc(C(C)C)c1N2C=CN(C2[Au]Cl)c3c(cccc3C(C)C)C(C)C
InChI	1S/C27H36N2.Au.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;;1H/q;+1;/p-1
Inchi Key	CNJQLSINQGKZAW-UHFFFAOYSA-M

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[(R,R)-Teth-TsDpen RuCl]

Empirical Formula (Hill Notation):	C₃₀H₃₁ClN₂O₂RuS
CAS Number:	1192620-83-9
Molecular Weight:	620.17
PubChem Substance ID:	329766310
NACRES:	NA.22

Quality Level	100,
optical activity	[]22/D -302°, c = 0.5% in chloroform
reaction suitability	core: ruthenium, reagent type: catalyst
mp	260-268 °C
storage temp.	2-8°C
SMILES string	Cc1ccc(cc1)S(=O)(=O)N2[C@@H]([C@H]([N@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI	1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m1../s1
InChI key	MDABGVLQRDDWLY-SEILFYAJSA-M

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[(S,S)-Teth-TsDpen RuCl]

Empirical Formula (Hill Notation):	C₃₀H₃₁ClN₂O₂RuS
CAS Number:	851051-43-9
Molecular Weight:	620.17
PubChem Substance ID:	329766311
NACRES:	NA.22

In the reduction of a ketone intermediate for the synthesis of esketamine.
In asymmetric hydrogenation of acetylenic ketones.
For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

100 mg in clear glass bottle
500 mg in amber glass bottle

optical activity	[]22/D +339°, c = 0.5% in chloroform
Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
mp	260-268 °C
storage temp.	2-8°C
SMILES string	Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI	1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1
Inchi Key	MDABGVLQRDDWLY-ARDORAJISA-M

1,1-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,1-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

Empirical Formula (Hill Notation):	C₃₄H₅₂Cl₂FeP₂Pd
CAS Number:	917511-90-1
Molecular Weight:	755.90
MDL number:	MFCD11656081
PubChem Substance ID:	329762337

, -unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.
-aryl carbonyl compounds by -arylation of ketones with aryl chlorides and aryl bromides.

1 g in glass bottle
250 mg in glass bottle

Quality Level	100,
assay	98%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	294-300 °C
storage temp.	20°C
SMILES string	[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
InChI	1S/2C17H26P.2ClH.Fe.Pd/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h27-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
Inchi Key	HRAMBTUEZQOQRK-UHFFFAOYSA-L

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here,.
[1,1-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) is an air-stable, highly active and versatile catalyst. It is an efficient catalyst for cross-coupling reactions. It participates as catalyst in various coupling reactions of the fine chemicals and pharmaceutical chemicals. It is commonly employed as homogeneous catalyst in the Suzuki reactions.
[1,1-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) (PdCl2(dtbpf)) participates as catalyst in Suzuki and Heck reactions. It is a preformed catalyst synthesized by a group of researchers at Johnson Mattheys Catalysis and Chiral Technologies. It is an active catalyst for various Pd catalyzed cross-coupling reactions.

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,1-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

Empirical Formula (Hill Notation):	C₂₆H₄₄Cl₂FeP₂Pd
CAS Number:	95408-45-0
Molecular Weight:	651.75
MDL number:	MFCD08064219
PubChem Substance ID:	329762308
NACRES:	NA.22

[1,1-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) (PdCl2(dtbpf)) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives (MIDA boronates) at room temperature (in the absence of organic solvent). It may be employed as catalyst for the synthesis of chalcones, via cross-coupling reactions.
[1,1-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) was used in the preparation of [PdCl2(bisphosphinometallocene)] complexes. These complexes are reported to be the catalyst precursors for the Buchwald-Hartwig reaction.
It is also employed as catalyst for greener Suzuki cross-coupling in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors,
Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

250 mg in glass bottle
1, 5, 50 g in glass bottle

Quality Level	200,
assay	98%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	203-208 °C
storage temp.	20°C
SMILES string	[Fe].Cl[Pd]Cl.CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C
InChI	1S/2C13H22P.2ClH.Fe.Pd/c21-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h27-10H,1-6H3;2*1H;;/q;;;;;+2/p-2
Inchi Key	JQZFOBWXNREQLO-UHFFFAOYSA-L

Reactant for synthesis of homoleptic complexes of cobalt(0) and nickel(0)

Catalyst for Heck-type reactions of 6-halo-1-hexene derivatives

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,1-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II)

Empirical Formula (Hill Notation):	C₃₄H₂₈Cl₂CoFeP₂
Linear Formula:	Cl₂Co(P(C₆H₅)₂C₅H₄)₂Fe
CAS Number:	67292-36-8
Molecular Weight:	684.22
MDL number:	MFCD03427161
PubChem Substance ID:	24879173

Quality Level	100,
assay	97%
reaction suitability	core: cobalt, reagent type: catalyst
mp	224 °C (dec.) (lit.)
SMILES string	[Fe].Cl[Co]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI	1S/2C17H14P.2ClH.Co.Fe/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h21-14H;2*1H;;/q;;;;+2;/p-2
InChI key	GODCBYSHZAJJDR-UHFFFAOYSA-L

Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

Empirical Formula (Hill Notation):	C₃₅H₃₀Cl₄FeP₂Pd
CAS Number:	95464-05-4
Molecular Weight:	816.64
MDL number:	MFCD00792899
PubChem Substance ID:	24863679
NACRES:	NA.22

1, 5, 25, 250 g in glass bottle

Analysis Note

Catalyst employed in the borylation of aryl halides with Bis(pinacolato)diboron(473294) as well as the coupling of the derived arylboronic esters with aryl halides leading to biaryls. Also used in the synthesis of lactams by CO insertion and medium-ring aryl ethers by intramolecular coupling of an aryl halide with an alcohol.

Quality Level	200,
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	275-280 °C
SMILES string	[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI	1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h21-14H;1H2;2*1H;;/q;;;;;;+2/p-2
Inchi Key	CWHRHCATIKFSND-UHFFFAOYSA-L

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II)

Empirical Formula (Hill Notation):	C₂₆H₂₄Cl₂CoP₂
Linear Formula:	[(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]CoCl₂
CAS Number:	18498-01-6
Molecular Weight:	528.26
MDL number:	MFCD00134173
PubChem Substance ID:	24862150
NACRES:	NA.22

Regio- and stereoselective intermolecular enyne coupling
Cross-coupling reactions of alkyl halides with aryl Grignard reagents
Hydrovinylation of styrene
Tandem radical cyclization and cross-coupling
Dimethylation and hydrodechlorination
Addition reactions

Quality Level	100,
reaction suitability	core: cobalt, reagent type: catalyst
mp	260 °C (dec.) (lit.)
SMILES string	Cl[Co]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI	1S/C26H24P2.2ClH.Co/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
Inchi Key	SYTWXWRJCLAZFP-UHFFFAOYSA-L

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

Empirical Formula (Hill Notation):	C₂₆H₂₄Cl₂P₂Pd
Linear Formula:	[(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]PdCl₂
CAS Number:	19978-61-1
Molecular Weight:	575.74
MDL number:	MFCD00015702
PubChem Substance ID:	24861302
NACRES:	NA.22

Quality Level	100,
assay	98%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst core: palladium
SMILES string	Cl[Pd]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI	1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI key	LDJXFZUGZASGIW-UHFFFAOYSA-L

100, 500 mg in glass bottle

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)

Empirical Formula (Hill Notation):	C₂₉H₃₇AuF₆N₃O₄S₂
CAS Number:	951776-24-2
Molecular Weight:	866.71
MDL number:	MFCD22572651
PubChem Substance ID:	329766355
NACRES:	NA.22

Selective Au(I) catalyst for hydroaminations.

Quality Level	100,
assay	95%
reaction suitability	core: gold, reagent type: catalyst
mp	202-287 °C (decomposition)
SMILES string	CC(C)c1cccc(C(C)C)c1N2C=CN(C2=[Au]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F)c3c(cccc3C(C)C)C(C)C
InChI	1S/C27H36N2.C2F6NO4S2.Au/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h9-16,18-21H,1-8H3;;/q;-1;+1
InChI key	FLIVFZVCPOQPDV-UHFFFAOYSA-N

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

Empirical Formula (Hill Notation):	C₂₇H₂₆Cl₂NiP₂
Linear Formula:	[(C₆H₅)₂P(CH₂)₃P(C₆H₅)₂]NiCl₂
CAS Number:	15629-92-2
Molecular Weight:	542.04
MDL number:	MFCD00015318
PubChem Substance ID:	24860309
NACRES:	NA.22

Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers

5, 25 g in glass bottle

Quality Level	100,
reaction suitability	core: nickel, reagent type: catalyst
mp	213 °C (dec.) (lit.)
SMILES string	Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
InChI	1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI key	ZBQUMMFUJLOTQC-UHFFFAOYSA-L

pictograms	GHS07,GHS08
signalword	Danger
hcodes	H315 - H317 - H319 - H334 - H335 - H350
pcodes	P201 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Empirical Formula (Hill Notation):	C₃₆H₄₀BF₄P₂Rh
CAS Number:	79255-71-3
Molecular Weight:	724.36
MDL number:	MFCD00075219
PubChem Substance ID:	24860907
NACRES:	NA.22

Quality Level	100,
assay	98%
reaction suitability	core: rhodium, reagent type: catalyst
mp	205 °C (dec.) (lit.)
SMILES string	[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C(CCP(c2ccccc2)c3ccccc3)CP(c4ccccc4)c5ccccc5
InChI	1S/C28H28P2.C8H12.BF4.Rh/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-12,15-22H,13-14,23-24H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;
Inchi Key	YESRLRPURJQQBI-ONEVTFJLSA-N

May contain up to 10% acetone and/or THF.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)

Empirical Formula (Hill Notation):	C₂₀H₃₆ClN₂OPRu
CAS Number:	863971-62-4
Molecular Weight:	488.01
MDL number:	MFCD16038117
PubChem Substance ID:	329765059
NACRES:	NA.22

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.
Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2,

100, 500 mg in glass bottle

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
SMILES string	Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
InChI	1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
InChI key	RZCAJPSOQUIHSH-UHFFFAOYSA-M

Bulky gold pi-acid catalyst used in oxidative cyclization reactions.

pictograms	GHS07,GHS08
signalword	Warning
hcodes	H319 - H351
pcodes	P281 - P305 + P351 + P338
Supp Hazards	EUH019
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[2-(Dicyclohexylphosphino)-3,6-dimethoxy-2,4,6-triisopropyl-1,1-biphenyl]gold(I) bis(trifluoromethanesulfonyl)imide

Empirical Formula (Hill Notation):	C₃₇H₅₃AuF₆NO₆PS₂
CAS Number:	1296269-97-0
Molecular Weight:	1013.88
MDL number:	MFCD22572681
PubChem Substance ID:	329767037
NACRES:	NA.22

1 g in glass bottle
250 mg in glass bottle

Quality Level	100,
reaction suitability	core: gold, reagent type: catalyst
mp	192-209 °C (decomposition)
SMILES string	FC(F)(F)S(=O)(=O)N([Au])S(=O)(=O)C(F)(F)F.COc1ccc(OC)c(c1P(C2CCCCC2)C3CCCCC3)-c4c(cc(cc4C(C)C)C(C)C)C(C)C
InChI	1S/C35H53O2P.C2F6NO4S2.Au/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h19-25,27-28H,9-18H2,1-8H3;;/q;-1;+1
InChI key	SMTGSBLIUQSWAP-UHFFFAOYSA-N

Gold Catalysts — 21st Century ′Gold Rush′,

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct

Empirical Formula (Hill Notation):	C₄₇H₃₈Au₂F₁₂N₂O₈P₂S₄
Linear Formula:	(C₂₀H₁₅AuF₆NO₄PS₂) 2 · C₇H₈
Molecular Weight:	1570.93
MDL number:	MFCD09038445
PubChem Substance ID:	24885406
NACRES:	NA.22

1 g in glass bottle
250 mg in glass bottle

Quality Level	100,
reaction suitability	core: gold, reagent type: catalyst
SMILES string	[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI	1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;23-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h21-15H;2-6H,1H3;;;;/q;;;2-1;2*+1
Inchi Key	SIVCTOVPPFSWEF-UHFFFAOYSA-N

Investigations of the structure and fluorescence of copper hexafluoropentanedionate alkyne clusters

Used in chemical vapor depositing of copper
Used in chemical vapor deposition of copper.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Bis(trimethylsilyl)acetylene](hexafluoroacetylacetonato)copper(I)

Empirical Formula (Hill Notation):	C₁₃H₁₉CuF₆O₂Si₂
Linear Formula:	(CH₃)₃SiC≡CSi(CH₃)₃·[CF₃COCH=C(O-)CF₃]Cu
CAS Number:	137039-38-4
Molecular Weight:	441.00
MDL number:	MFCD00274621
PubChem Substance ID:	24867346
NACRES:	NA.22

reaction suitability	core: copper, reagent type: catalyst
Quality Level	100,
mp	51-54 °C (lit.)
storage temp.	2-8°C
SMILES string	C[Si](C)(C)C#C[Si](C)(C)C.FC(F)(F)C(=O)\C=C(\O[Cu])C(F)(F)F
InChI	1S/C8H18Si2.C5H2F6O2.Cu/c1-9(2,3)7-8-10(4,5)6;6-4(7,8)2(12)1-3(13)5(9,10)11;/h1-6H3;1,12H;/q;;+1/p-1/b;2-1+;
InChI key	YESCMKQKTNVQCY-JITBQSAISA-M

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis,
Precursor for Iridium complexes and catalysts

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Ir(cod)(acac)]

Empirical Formula (Hill Notation):	C₁₃H₁₉IrO₂
CAS Number:	12154-84-6
Molecular Weight:	399.51
MDL number:	MFCD08273779
PubChem Substance ID:	329760791
NACRES:	NA.22

2 g in glass bottle
500 mg in glass bottle

Product of Umicore

Additional information available at www.pmc.umicore.com,

Quality Level	100,
reaction suitability	core: iridium, reagent type: catalyst
mp	150-155 °C (dec.)
SMILES string	CC(=O)\C=C(\C)O[Ir].C1CC=CCCC=C1
InChI	1S/C8H12.C5H8O2.Ir/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;
Inchi Key	JHNBKYKCHXHKET-DWVXZKBMSA-M

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Quality Level	100,
form	powder or crystals
reaction suitability	core: iridium, reagent type: catalyst reaction type: Photocatalysis
mp	>300 °C
photocatalyst activation	465 nm

[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Ir(dtbbpy)(ppy)2]PF6

Empirical Formula (Hill Notation):	C₄₀H₄₀F₆IrN₄P
CAS Number:	676525-77-2
Molecular Weight:	913.95

Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
Aryl-alkyl CC reductive cross-coupling reactions.

50, 100 mg in glass bottle

reaction suitability	core: iridium, reagent type: catalyst
Quality Level	100,
photocatalyst activation	455 nm
storage temp.	2-8°C
SMILES string	CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
InChI	1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;21-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;21-6,8-9H;;
Inchi Key	DZARMRZNOUWGQE-UHFFFAOYSA-N

[Ir(p-F(Me)ppy)2-(4,4-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Ir(p-F(Me)ppy)2-(4,4-dtbbpy)]PF6

Empirical Formula (Hill Notation):	C₄₂H₄₂F₈IrN₄P
CAS Number:	808142-88-3
Molecular Weight:	977.99

Direct, enantioselective -alkylation of aldehydes using simple olefins,

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds,

Decarboxylative sp3 C-N coupling via dual copper and photoredox catalysis,

assay	95%
form	powder or crystals
reaction suitability	reaction type: Photocatalysis, reagent type: catalyst
photocatalyst activation	450 nm

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis,
Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Pd(acac)2]

Empirical Formula (Hill Notation):	C₁₀H₁₄O₄Pd
Linear Formula:	Pd(C₅H₇O₂)₂
CAS Number:	14024-61-4
Molecular Weight:	304.64
Beilstein/REAXYS Number:	4136188
EC Number:	237-859-8
MDL number:	MFCD00000025
PubChem Substance ID:	329760816
NACRES:	NA.22

2 g in glass bottle
500 mg in glass bottle

Product of Umicore

Additional information available at www.pmc.umicore.com,

Quality Level	100,
assay	99%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	200-251 °C (dec.)
SMILES string	CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O
InChI	1S/2C5H8O2.Pd/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChI key	JKDRQYIYVJVOPF-FDGPNNRMSA-L

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis,
Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

pictograms	GHS07
signalword	Warning
hcodes	H319
pcodes	P264 - P280 - P305 + P351 + P338 - P337 + P313
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Pd(allyl)Cl]2

Empirical Formula (Hill Notation):	C₆H₁₀Cl₂Pd₂
CAS Number:	12012-95-2
Molecular Weight:	365.89
Beilstein/REAXYS Number:	4124623
EC Number:	234-579-8
MDL number:	MFCD00044874
PubChem Substance ID:	329760817
NACRES:	NA.22

5 g in glass bottle
500 mg in glass bottle

Product of Umicore

Additional information available at www.pmc.umicore.com,

Quality Level	100,
assay	98.0% (C, elemental analysis)
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
SMILES string	Cl[Pd]CC=C.Cl[Pd]CC=C
InChI	1S/2C3H5.2ClH.2Pd/c21-3-2;;;;/h23H,1-2H2;21H;;/q;;;;2+1/p-2
Inchi Key	TWKVUTXHANJYGH-UHFFFAOYSA-L

Palladium(II) acetate is a homogenous oxidation catalyst. It participates in the activation of alkenic and aromatic compounds towards oxidative inter- and intramolecular nucleophilic reactions. Crystals of palladium(II) acetate have a trimeric structure, having symmetry D3h. Each of the palladium atoms in the crystals are joined to the other two by double acetate bridges. Microencapsulation of palladium(II) acetate in polyurea affords polyurea-encapsulated palladium(II) acetate. It is a versatile heterogeneous catalyst for various phosphine-free cross-coupling reactions. It participates as catalyst in the Heck coupling reaction of pthalides with different alkenes.

pictograms	GHS07
signalword	Warning
hcodes	H315
pcodes	P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3

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[Pd(OAc)2]3

Empirical Formula (Hill Notation):	C₄H₆O₄Pd
Linear Formula:	Pd(OCOCH₃)₂
CAS Number:	3375-31-3
Molecular Weight:	224.51
Beilstein/REAXYS Number:	6086766
EC Number:	222-164-4
MDL number:	MFCD00012453
PubChem Substance ID:	24874166
NACRES:	NA.22

Palladium(II) acetate was employed as a catalyst for the following reactions:

Formation of allylic acetates. (eq. 1)
Hydroselenation of triple bonds. (eq. 2)
Heck arylation of alkenes. (eq. 3)
Cyclocarbonylation. (eq. 4)
Buchwald-Hartwig amination reaction. (eq. 5)

Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

1, 5, 25, 100 g in glass bottle

Quality Level	200,
assay	99.9% trace metals basis
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst reaction type: C-H Activation
mp	216.3-223.7 °C (dec.)
SMILES string	CC(=O)O[Pd]OC(C)=O
InChI	1S/2C2H4O2.Pd/c21-2(3)4;/h21H3,(H,3,4);/q;;+2/p-2
Inchi Key	YJVFFLUZDVXJQI-UHFFFAOYSA-L

[Pd(terpy)(2-Cl-phen)](BF4)2 was developed in the Ritter lab for the elecrophilic fluorination of arenes.

pictograms	GHS05,GHS07,GHS09
signalword	Danger
hcodes	H317 - H318 - H410
pcodes	P261 - P272 - P273 - P280 - P302 + P352 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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[Pd(terpy)(2-Cl-phen)](BF4)2

Empirical Formula (Hill Notation):	C₂₇H₁₈B₂ClF₈N₅Pd
CAS Number:	2133345-76-1
Molecular Weight:	727.95

Palladium-catalysed electrophilic aromatic C-H fluorination,

This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH (US Patent Pending 16/083,160 and PCT/US2017/021563).

assay	95%
form	powder or crystals
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	>300 °C
storage temp.	2-8°C
SMILES string	ClC(C=C1)=NC2=C1C=CC3=CC=C[N]([Pd]45[N]6=C(C7=CC=CC=[N]75)C=CC=C6C8=CC=CC=[N]84)=C32