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Inorganic Catalysts

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48

Dichlorobis(tributylphosphine)nickel(II)

Empirical Formula (Hill Notation):	C₂₄H₅₄Cl₂NiP₂
Linear Formula:	{[CH₃(CH₂)₃]₃P}₂NiCl₂
CAS Number:	15274-43-8
Molecular Weight:	534.23
MDL number:	MFCD00049260
PubChem Substance ID:	24860021

Wenkert arylations
Regioselective [2+2+2] cycloadditions
Polymerization reactions

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
reaction suitability	core: nickel, reagent type: catalyst
mp	43-45 °C (lit.)
storage temp.	2-8°C
SMILES string	Cl[Ni]Cl.CCCCP(CCCC)CCCC.CCCCP(CCCC)CCCC
InChI	1S/2C12H27P.2ClH.Ni/c21-4-7-10-13(11-8-5-2)12-9-6-3;;;/h24-12H2,1-3H3;2*1H;/q;;;;+2/p-2
InChI key	KPFOFXWYYUNJOZ-UHFFFAOYSA-L

Safety Information

pictograms	GHS05,GHS07,GHS08
signalword	Danger
hcodes	H302 + H312 + H332 - H314 - H317 - H334 - H350
pcodes	P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN 1759 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichlorobis(tricyclohexylphosphine)palladium(II)

Empirical Formula (Hill Notation):	C₃₆H₆₆Cl₂P₂Pd
Linear Formula:	[(C₆H₁₁)₃P]₂PdCl₂
CAS Number:	29934-17-6
Molecular Weight:	738.18
MDL number:	MFCD00191830
PubChem Substance ID:	24864894
NACRES:	NA.22

Dichlorobis(tricyclohexylphosphine)palladium(II) is widely employed as catalyst precursor in various carbon-carbon and carbon-heteroatom bond forming reactions.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions,
Catalyst for C-C and C-N coupling reaction.

Packaging

1, 5 g in glass bottle

Параметры

Quality Level	100,
assay	95%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	270 °C (dec.) (lit.)
SMILES string	Cl[Pd]Cl.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6
InChI	1S/2C18H33P.2ClH.Pd/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h216-18H,1-15H2;2*1H;/q;;;;+2/p-2
InChI key	VUYVXCJTTQJVKJ-UHFFFAOYSA-L

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichlorobis(trimethylphosphine)nickel(II)

Empirical Formula (Hill Notation):	C₆H₁₈Cl₂NiP₂
Linear Formula:	[((CH₃)₃P)]₂NICl₂
CAS Number:	19232-05-4
Molecular Weight:	281.75
MDL number:	MFCD03412128
PubChem Substance ID:	24880384
NACRES:	NA.22

Wenkert arylation of thiophene with aryl Grignard reagents
Regioselective [2+2+2] cycloaddition of carboryne with alkynes to give benzocarborane compounds
Kumada-Corriu cross coupling of Grignard reagents
Borylation of aryl chlorides
Reductive aldol cyclization-lactonization
Arylcyanation of alkynes
Alkynylation of benzonitriles via C-C bond activation

Packaging

1 g in glass bottle

Параметры

assay	97%
reaction suitability	core: nickel, reagent type: catalyst
mp	194-199 °C (lit.)
_max	244 nm
SMILES string	Cl[Ni]Cl.CP(C)C.CP(C)C
InChI	1S/2C3H9P.2ClH.Ni/c21-4(2)3;;;/h21-3H3;2*1H;/q;;;;+2/p-2
Inchi Key	KYHNNWWCXIOTKC-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichlorodi--chlorobis[(1,2,3,6,7,8--2,7-dimethyl-2,6-octadiene-1,8-diyl]diruthenium(IV) 715131-500MG

Empirical Formula (Hill Notation):	C₂₀H₃₂Cl₄Ru₂
CAS Number:	34801-97-3
Molecular Weight:	616.42
PubChem Substance ID:	329762946
NACRES:	NA.22

Application

Catalyst for:

Selective estragole to transanethole isomerization
Regioselective alkylation of indoles with terminal alkynes
Diyne polycyclotrimerization
Deprotection of N-allylic amines
Ring-opening metathesis polymerization of norbornene
Polymerization of cycloalkenes and norbornene

Packaging

500 mg in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: ruthenium, reagent type: catalyst
mp	193-202 °C (dec.)
SMILES string	Cl[Ru]Cl.Cl[Ru]Cl.[CH2][C](C)[CH]CC[CH][C]([CH2])C.[CH2][C](C)[CH]CC[CH][C]([CH2])C
InChI	1S/2C10H16.4ClH.2Ru/c21-9(2)7-5-6-8-10(3)4;;;;;;/h27-8H,1,3,5-6H2,2,4H3;41H;;/q;;;;;;2+2/p-4
InChI key	UILPCDNRMPZVBB-UHFFFAOYSA-J

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)

Empirical Formula (Hill Notation):	C₃₈H₃₆C_l2N₂P₂Ru
CAS Number:	1388712-91-1
MDL number:	MFCD26960800
PubChem Substance ID:	329765760
NACRES:	NA.22

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.

Application

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.
From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts,

Packaging

100, 500 mg in glass bottle

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: ruthenium, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	275-295 °C
SMILES string	Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6
InChI	1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2
InChI key	JFYJJNHKCBDTMZ-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

Empirical Formula (Hill Notation):	C₂₆H₃₄Cl₂NPRuS₂
CAS Number:	1462397-86-9
Molecular Weight:	627.63
MDL number:	MFCD26960799
PubChem Substance ID:	329765759
NACRES:	NA.22

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.
Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters,
Catalyst for the hydrogenation of esters to alcohols.

Packaging

100, 500 mg in glass bottle

Other Notes

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: ruthenium, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	300-310 °C
SMILES string	CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
InChI	1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
InChI key	ZQGMNGJIEYHKBR-UHFFFAOYSA-L

Safety Information

pictograms	GHS06
signalword	Danger
hcodes	H302 + H312 - H331
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV) 701475-500MG

Empirical Formula (Hill Notation):	C₁₂H₁₈Cl₂Ru
CAS Number:	12170-97-7
Molecular Weight:	334.25
MDL number:	MFCD08459354
PubChem Substance ID:	329762293
NACRES:	NA.22

Application

Catalyst for:

Redox isomerization/transfer hydrogenation
Deprotection of N-allyl amides and lactams
Isomerization of allylamines
Isomerization of allylic alcohols into carbonyl compounds

Catalysts used in the deprotection of N-allyl amides and lactams

Packaging

500 mg in glass bottle

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
mp	190 °C
SMILES string	Cl[Ru]1(Cl)C\C=C\CCC=CCC\C=C\C1
InChI	1S/C12H18.2ClH.Ru/c1-3-5-7-9-11-12-10-8-6-4-2;;;/h3-6,11-12H,1-2,7-10H2;2*1H;/q;;;+2/p-2/b5-3+,6-4+,12-11-;;;
Inchi Key	RSRAKQPWMXANGM-LXALEWKWSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[(±)BINAP]digold(I) 717479-250MG

Empirical Formula (Hill Notation):	C₄₄H₃₂Au₂Cl₂P₂
CAS Number:	685138-48-1
Molecular Weight:	1087.51
MDL number:	MFCD15144870
PubChem Substance ID:	329763494

Application

Catalyst for selective diboration of alkenes via base-assisted heterolytic cleavage
Gold Catalysts — 21st Century ′Gold Rush′,

Packaging

250 mg in glass bottle

Параметры

assay	97%
reaction suitability	core: gold, reagent type: catalyst
mp	335-350 °C
SMILES string	Cl[Au].Cl[Au].P(C1=CC=CC=C1)(C2=C(C3=C(C=CC4=C3C=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6)C7=C(C=CC=C7)C=C2)C8=CC=CC=C8
InChI	1S/C44H32P2.2Au.2ClH/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;;/h1-32H;;;21H/q;2+1;;/p-2
Inchi Key	ALCLMPWXOJPBJG-UHFFFAOYSA-L

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	2

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Dichloro[1,1-bis(diphenylphosphino)ferrocene]palladium(II) acetone adduct

Empirical Formula (Hill Notation):	C₃₄H₂₈Cl₂FeP₂Pd · 0.5C₃H₆O
CAS Number:	138549-82-3
Molecular Weight:	760.74
MDL number:	MFCD11109268
PubChem Substance ID:	329766060
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	176-182 °C
storage temp.	2-8°C
SMILES string	[Fe].Cl[Pd]Cl.CC(C)=O.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI	1S/2C17H14P.C3H6O.2ClH.Fe.Pd/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-3(2)4;;;;/h21-14H;1-2H3;2*1H;;/q;;;;;;+2/p-2
InChI key	WMCRPHRRPFWDES-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H332 - H315 - H319
pcodes	P301 + P312 + P330 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][(2-isopropoxy)(5-pentafluorobenzoylamino)benzylidene]ruthenium(II) 775401-100MG

Empirical Formula (Hill Notation):	C₃₈H₃₈Cl₂F₅N₃O₂Ru
CAS Number:	1030618-02-0
Molecular Weight:	835.70
MDL number:	MFCD27952545
PubChem Substance ID:	329767757

Packaging

100 mg in glass bottle

Legal Information

Umicore M7 catalysts are sold in cooperation with Umicore and OmegaCat Systems for research purposes only.

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
storage temp.	2-8°C
SMILES string	CC(C)OC1=C(C=C(NC(C2=C(F)C(F)=C(F)C(F)=C2F)=O)C=C1)C=[Ru](Cl)(Cl)=C3N(C4=C(C)C=C(C)C=C4C)CCN3C5=C(C)C=C(C)C=C5C
InChI	1S/C21H26N2.C17H12F5NO2.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7(2)25-10-5-4-9(6-8(10)3)23-17(24)11-12(18)14(20)16(22)15(21)13(11)19;;;/h9-12H,7-8H2,1-6H3;3-7H,1-2H3,(H,23,24);2*1H;/q;;;;+2/p-2
InChI key	BEKLYCQNWWQFKP-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H412
pcodes	P273 - P280 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)

Empirical Formula (Hill Notation):	C₃₃H₄₃Cl₂N₃O₃RuS
CAS Number:	918870-76-5
Molecular Weight:	733.75
MDL number:	MFCD08459353
PubChem Substance ID:	329766960

Zhan Catalyst-1B (Hoveyda-Grubbs type catalyst) can be used:

In the preparation of hybrid olefin metathesis catalysts, with increased catalytic activity via immobilization on molecular seives. supports
As a catalyst in the synthesis of divergent dendrimer
In ring-closure metathesis (RCM) reaction.

Packaging

2 g in glass bottle
100, 500 mg in glass bottle

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
InChI	1S/C21H26N2.C12H17NO3S.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-9(2)16-12-7-6-11(8-10(12)3)17(14,15)13(4)5;;;/h9-12H,7-8H2,1-6H3;3,6-9H,1-2,4-5H3;2*1H;/q;;;;+2/p-2
Inchi Key	OXLURKCRXVAJQS-UHFFFAOYSA-L

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]{[5-(2-ethoxy-2-oxoethanamido)]-2-isopropoxybenzylidene}ruthenium(II) 775436-100MG

Empirical Formula (Hill Notation):	C₃₅H₄₃Cl₂N₃O₄Ru
CAS Number:	1030618-11-1
Molecular Weight:	741.71
MDL number:	MFCD26960807
PubChem Substance ID:	329767759

Packaging

100 mg in glass bottle

Legal Information

Umicore M7 catalysts are sold in cooperation with Umicore and OmegaCat Systems for research purposes only.

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
mp	104-152 °C (decomposition)
storage temp.	2-8°C
SMILES string	CC1=CC(C)=CC(C)=C1N(CCN2C3=C(C)C=C(C)C=C3C)C2=[Ru](Cl)(Cl)=CC4=C(OC(C)C)C=CC(NC(C(OCC)=O)=O)=C4
InChI	1S/C21H26N2.C14H17NO4.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-5-18-14(17)13(16)15-11-6-7-12(10(4)8-11)19-9(2)3;;;/h9-12H,7-8H2,1-6H3;4,6-9H,5H2,1-3H3,(H,15,16);2*1H;/q;;;;+2/p-2
InChI key	JILXLQWXSILBOS-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 - H315 - H319
pcodes	P280 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene][(2-isopropoxy)(5-pentafluorobenzoylamino)benzylidene]ruthenium(II) 775339-100MG

Empirical Formula (Hill Notation):	C₄₄H₅₀Cl₂F₅N₃O₂Ru
CAS Number:	1354710-90-9
Molecular Weight:	919.85
MDL number:	MFCD26960805
PubChem Substance ID:	329767750
NACRES:	NA.22

Packaging

100 mg in glass bottle

Legal Information

Umicore M7 catalysts are sold in cooperation with Umicore and OmegaCat Systems for research purposes only.

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
mp	157-180 °C (decomposition)
storage temp.	2-8°C
SMILES string	Cl[Ru](=CC1=C(OC(C)C)C=CC(NC(C2=C(F)C(F)=C(F)C(F)=C2F)=O)=C1)(Cl)=C3N(C4=C(C(C)C)C=CC=C4C(C)C)CCN3C5=C(C(C)C)C=CC=C5C(C)C
InChI	1S/C27H38N2.C17H12F5NO2.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-7(2)25-10-5-4-9(6-8(10)3)23-17(24)11-12(18)14(20)16(22)15(21)13(11)19;;;/h9-14,18-21H,15-16H2,1-8H3;3-7H,1-2H3,(H,23,24);2*1H;/q;;;;+2/p-2
InChI key	XOFWGECEXOWWQY-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene][(5-(2-ethoxy-2-oxoethanamido))-(2-isopropoxy)benzylidene]ruthenium(II) 775371-100MG

Empirical Formula (Hill Notation):	C₄₁H₅₅Cl₂N₃O₄Ru
CAS Number:	1212009-08-9
Molecular Weight:	825.87
MDL number:	MFCD26142778
PubChem Substance ID:	329767755
NACRES:	NA.22

Packaging

100 mg in glass bottle

Legal Information

Umicore M7 catalysts are sold in cooperation with Umicore and OmegaCat Systems for research purpose only.

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: ruthenium, reagent type: catalyst
mp	229-234 °C
storage temp.	2-8°C
SMILES string	CC(C)OC1=C(C=C(NC(C(OCC)=O)=O)C=C1)C=[Ru](Cl)(Cl)=C2N(C3=C(C(C)C)C=CC=C3C(C)C)CCN2C4=C(C(C)C)C=CC=C4C(C)C
InChI	1S/C27H38N2.C14H17NO4.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-5-18-14(17)13(16)15-11-6-7-12(10(4)8-11)19-9(2)3;;;/h9-14,18-21H,15-16H2,1-8H3;4,6-9H,5H2,1-3H3,(H,15,16);2*1H;/q;;;;+2/p-2
Inchi Key	QCKBDRYJPQMURB-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H412
pcodes	P273 - P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[2,2-bis(diphenylphosphino)-1,1-binaphthyl]palladium(II)

Empirical Formula (Hill Notation):	C₄₄H₃₂Cl₂P₂Pd
CAS Number:	253157-79-8
Molecular Weight:	800.00
MDL number:	MFCD00075254
PubChem Substance ID:	329767357
NACRES:	NA.22

2 g in glass bottle
500 mg in glass bottle

Application

Versatile palladium catalyst for cross-coupling reactions

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	230-300 °C (decomposition)
SMILES string	Cl[Pd]Cl.c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
InChI	1S/C44H32P2.2ClH.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2
InChI key	VDHAUMFISVWIRX-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)

Empirical Formula (Hill Notation):	C₃₉H₃₂Cl₂OP₂Pd
CAS Number:	205319-10-4
Molecular Weight:	755.94
MDL number:	MFCD14155707
PubChem Substance ID:	329767359
NACRES:	NA.22

2 g in glass bottle
500 mg in glass bottle

Application

Effective catalyst for carbonylation of aryl halides

Параметры

Quality Level	100,
assay	95%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	280-287 °C (decomposition)
SMILES string	Cl[Pd]Cl.CC1(C)c2cccc(P(c3ccccc3)c4ccccc4)c2Oc5c(cccc15)P(c6ccccc6)c7ccccc7
InChI	1S/C39H32OP2.2ClH.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;;;/h3-28H,1-2H3;2*1H;/q;;;+2/p-2
InChI key	HEYONDYPXIUDCK-UHFFFAOYSA-L

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)

Empirical Formula (Hill Notation):	C₂₀H₂₄Cl₂Zr
CAS Number:	100163-29-9
Molecular Weight:	426.53
MDL number:	MFCD00672123
PubChem Substance ID:	24877859
NACRES:	NA.22

Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines

Packaging

500 mg in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: zirconium, reagent type: catalyst
mp	267-271 °C (lit.)
SMILES string	Cl[Zr]Cl.[CH]1[CH][C](CC[C]2[CH][CH][C]3CCCC[C]23)[C]4CCCC[C]14
InChI	1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
Inchi Key	AKXWJOYQORUUHS-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dichloro[rac-ethylenebis(indenyl)]zirconium(IV)

Empirical Formula (Hill Notation):	C₂₀H₁₆Cl₂Zr
CAS Number:	100080-82-8
Molecular Weight:	418.47
MDL number:	MFCD01314544
PubChem Substance ID:	24864508
NACRES:	NA.22

Quality Level	200,
reaction suitability	core: zirconium, reagent type: catalyst
impurities	3% dichloromethane
SMILES string	Cl[Zr]Cl.C(CC1C=Cc2ccccc12)C3C=Cc4ccccc34
InChI	1S/C20H18.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h1-12,17-18H,13-14H2;2*1H;/q;;;+2/p-2
Inchi Key	IJSDUKZKUCXMRL-UHFFFAOYSA-L

Safety Information

pictograms	GHS05,GHS07,GHS08
signalword	Danger
hcodes	H302 - H314 - H351
pcodes	P201 - P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
RIDADR	UN 3261 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Diethylenetriaminepentaacetic acid gadolinium(III) dihydrogen salt hydrate

Empirical Formula (Hill Notation):	C₁₄H₂₀GdN₃O₁₀ · xH₂O
Molecular Weight:	547.57 (anhydrous basis)
MDL number:	MFCD02092653
PubChem Substance ID:	24863829

Widely used metal ion complex for MRI used in the diagnosis of cerebral tumors, CNS diseases, hepatic tumors, pituitary adenomas, multiple sclerosis, and blood-brain barrier impairment.

Packaging

5, 25 g in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: gadolinium, reagent type: catalyst
mp	129 °C (dec.) (lit.)
SMILES string	[Gd+3].[H]O[H].OC(=O)CN(CCN(CCN(CC(O)=O)CC([O-])=O)CC([O-])=O)CC([O-])=O
InChI	1S/C14H23N3O10.Gd.H2O/c18-10(19)5-15(1-3-16(6-11(20)21)7-12(22)23)2-4-17(8-13(24)25)9-14(26)27;;/h1-9H2,(H,18,19)(H,20,21)(H,22,23)(H,24,25)(H,26,27);;1H2/q;+3;/p-3
InChI key	JBUMALASVLVYKI-UHFFFAOYSA-K

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Diethylphosphoramidous dichloride

Empirical Formula (Hill Notation):	C₄H₁₀Cl₂NP
Linear Formula:	(C₂H₅)₂NPCl₂
CAS Number:	1069-08-5
Molecular Weight:	174.01
MDL number:	MFCD00013614
PubChem Substance ID:	24862338
NACRES:	NA.22

Reagent for the preparation of diethylaminophosphine-metal complexes and the phosphitylation of alcohols.

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.497 (lit.)
bp	179 °C (lit.)
density	1.196 g/mL at 25 °C (lit.)
functional group	phosphine
storage temp.	2-8°C
SMILES string	CCN(CC)P(Cl)Cl
InChI	1S/C4H10Cl2NP/c1-3-7(4-2)8(5)6/h3-4H2,1-2H3
InChI key	BPEMCEULJQTJMI-UHFFFAOYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3265 8 / PGII
WGK Germany	WGK 3
Flash Point F	181.4 °F - closed cup
Flash Point C	83 °C - closed cup

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Dihydridotetrakis(triphenylphosphine)ruthenium(II)

Empirical Formula (Hill Notation):	C₇₂H₆₆P₄Ru
Linear Formula:	[(C₆H₅)₃P]₄RuH₂
CAS Number:	19529-00-1
Molecular Weight:	1156.26
MDL number:	MFCD04126429
PubChem Substance ID:	24860280

500 mg in glass bottle

Application

Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
mp	181-183 °C (lit.)
SMILES string	[RuH2].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI	1S/4C18H15P.Ru.2H/c41-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h41-15H;;;
Inchi Key	RXFATFKBDIQXLS-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Diiodo(bis(diphenylphosphino)ethane)cobalt(II)

Empirical Formula (Hill Notation):	C₂₆H₂₄CoI₂P₂
Linear Formula:	CoI₂(P(C₆H₅)₂C₂H₄P(C₆H₅)₂)
CAS Number:	34775-39-8
Molecular Weight:	711.16
MDL number:	MFCD11045354
PubChem Substance ID:	329760987
NACRES:	NA.22

Reductive coupling reactions
Cyclization reactions
Reductive [3 + 2] cycloaddition reactions
Aryl-sulfur bond formation
Dimerization reactions

Catalyst for the mild coupling of thiols with aryl and heteroaryl iodides to give sulfides.
Catalyzes the cyclization of 2-iodobenzoates with aldehydes to give phthalides (isobenzofuranones).

Packaging

1 g in glass bottle
250 mg in glass bottle

Параметры

reaction suitability	core: cobalt, reagent type: catalyst
Quality Level	100,
mp	>300 °C
SMILES string	I[Co]I.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI	1S/C26H24P2.Co.2HI/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;;2*1H/q;+2;;/p-2
Inchi Key	FLTZQBPRANWICZ-UHFFFAOYSA-L

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Diiodo(pentamethylcyclopentadienyl)iridium(III) dimer

Empirical Formula (Hill Notation):	C₂₀H₃₀I₄Ir₂
CAS Number:	33040-12-9
Molecular Weight:	1162.50
PubChem Substance ID:	329766272
NACRES:	NA.22

reaction suitability	core: iridium, reagent type: catalyst
Quality Level	100,
mp	412-420 °C
storage temp.	2-8°C
SMILES string	I[Ir]I.I[Ir]I.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4HI.2Ir/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
Inchi Key	GVAFOFZYINFTHJ-UHFFFAOYSA-J

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Dimethyl phenylphosphonite

Empirical Formula (Hill Notation):	C₈H₁₁O₂P
Linear Formula:	C₆H₅P(OCH₃)₂
CAS Number:	2946-61-4
Molecular Weight:	170.15
EC Number:	220-960-6
MDL number:	MFCD00008352
PubChem Substance ID:	24848956
NACRES:	NA.22

Quality Level	100,
assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.529 (lit.)
density	1.072 g/mL at 25 °C (lit.)
functional group	phosphine
storage temp.	2-8°C
SMILES string	COP(OC)c1ccccc1
InChI	1S/C8H11O2P/c1-9-11(10-2)8-6-4-3-5-7-8/h3-7H,1-2H3
InChI key	LMZLQYYLELWCCW-UHFFFAOYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1760 8 / PGII
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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Diphenyl(trimethylsilyl)phosphine

Empirical Formula (Hill Notation):	C₁₅H₁₉PSi
Linear Formula:	(C₆H₅)₂PSi(CH₃)₃
CAS Number:	17154-34-6
Molecular Weight:	258.37
MDL number:	MFCD00015589
PubChem Substance ID:	24864422
NACRES:	NA.22

grade	technical grade
Quality Level	200,
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.603 (lit.)
bp	119-120 °C/0.2 mmHg (lit.)
density	1.009 g/mL at 25 °C (lit.)
functional group	phosphine
SMILES string	C[Si](C)(C)P(c1ccccc1)c2ccccc2
InChI	1S/C15H19PSi/c1-17(2,3)16(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3
InChI key	WTWVGNUJAAOVSC-UHFFFAOYSA-N

Safety Information

pictograms	GHS02
signalword	Danger
hcodes	H225
pcodes	P210 - P233 - P240 - P241 - P242 - P243
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1993BF 3 / PGII
WGK Germany	WGK 3
Flash Point F	50.0 °F - closed cup
Flash Point C	10 °C - closed cup

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Diphenylphosphine oxide

Empirical Formula (Hill Notation):	C₁₂H₁₁OP
Linear Formula:	(C₆H₅)₂P(O)H
CAS Number:	4559-70-0
Molecular Weight:	202.19
MDL number:	MFCD00002079
PubChem Substance ID:	24857300

Diphenylphosphine oxide can be used as a coupling partner to prepare various organophosphorus compounds via cross-coupling reaction with aryl halides in the presence of Ni/Zn catalyst.
It can also be used as a reactant to synthesize:

Diphenyl(2-phenyl-2H-indazol-3-yl)phosphine oxide derivatives by phosphonylation of 2H-indazoles using rose bengal as a catalyst.
Alkenyldiphenylphosphine oxides by hydrophosphinylation of terminal alkynes in the presence of transition metal catalysts.
Diphenylphosphino-containing chiral ligands for asymmetric catalytic reactions via Pd-catalyzed coupling reaction with aryl triflates.
Triarylphosphine oxides and Horner-Wittig reagents.

Packaging

1, 5 g in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand reaction type: Hydrophosphonylations, reagent type: ligand reaction type: Suzuki-Miyaura Coupling
mp	56-57 °C (lit.)
functional group	phosphine
SMILES string	O=[PH](c1ccccc1)c2ccccc2
InChI	1S/C12H11OP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
InChI key	ASUOLLHGALPRFK-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 - H315 - H319 - H335
pcodes	P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Diphenylphosphinic chloride

Empirical Formula (Hill Notation):	C₁₂H₁₀ClOP
Linear Formula:	(C₆H₅)₂P(O)Cl
CAS Number:	1499-21-4
Molecular Weight:	236.63
Beilstein/REAXYS Number:	975191
EC Number:	216-107-2
MDL number:	MFCD00002077
PubChem Substance ID:	24853787
NACRES:	NA.22

Diphenylphosphinic chloride (Ph2POCl) is widely used as a precursor to synthesize various chiral phosphine bidentate ligands for asymmetric synthesis, in addition to several peptide coupling agents.

Packaging

10, 50 g in glass bottle

Параметры

Quality Level	100,
assay	98%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.609 (lit.)
bp	222 °C/16 mmHg (lit.)
density	1.24 g/mL at 25 °C (lit.)
functional group	phosphine
storage temp.	2-8°C
SMILES string	ClP(=O)(c1ccccc1)c2ccccc2
InChI	1S/C12H10ClOP/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
Inchi Key	QPQGTZMAQRXCJW-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H226 - H314
pcodes	P210 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2920 3(8) / PGII
WGK Germany	WGK 3
Flash Point F	78.8 °F - closed cup
Flash Point C	26 °C - closed cup

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Diphosphoryl chloride

Empirical Formula (Hill Notation):	Cl₄O₃P₂
Linear Formula:	Cl₂P(O)OP(O)Cl₂
CAS Number:	13498-14-1
Molecular Weight:	251.76
EC Number:	236-824-4
MDL number:	MFCD00061542
PubChem Substance ID:	24863841
NACRES:	NA.22

Useful reagent for the Vilsmeier formylation and glyoxylation reactions of nucleophilic aromatic compounds.

Packaging

5, 25 mL in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.475 (lit.)
bp	90 °C/12 mmHg (lit.)
density	1.82 g/mL at 25 °C (lit.)
functional group	phosphine
SMILES string	ClP(Cl)(=O)OP(Cl)(Cl)=O
InChI	1S/Cl4O3P2/c1-8(2,5)7-9(3,4)6
InChI key	CNTIXUGILVWVHR-UHFFFAOYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
Supp Hazards	EUH014
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3264 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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DMT-functionalized silica gel 900680-10G

Application

Metal scavenger: Ir, Ni, Os, Pd, Pt, Rh, Ru, Cd, Co, Cu, Fe, Sc, and Zn.

Packaging

10 g in poly bottle

Other Notes

Removal of Palladium from Organic Reaction Mixtures by Trimercaptotriazine,

Legal Information

SiliaMetS is a registered trademark of Silicycle, Inc.

Параметры

material	silica gel (irregular particle shape)
Quality Level	100,
assay	99%
form	powder
feature	endcapped
reaction suitability	reagent type: catalyst, reagent type: chelator
pore size	60 pore diameter
capacity	0.50 mmol/g loading(molecular loading)
solubility	all common solvents: soluble (aqueous and organic)
bulk density	732 g/L (typical tap density)

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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DOTA-functionalized silica gel 900679-10G

Application

Metal scavenger: Ca, Ce, Cu, Fe, Gd, La, Ni, Pd, Zn.

Packaging

10 g in poly bottle

Caution

For prolonged storage, recommended conditions are to store product in a cool place (<8 °C) under inert atmosphere (argon) when possible.

Legal Information

SiliaMetS is a registered trademark of Silicycle, Inc.

Параметры

Quality Level	100,
assay	99%
form	powder
shelf life	2 yr (expiration date period)
reaction suitability	reagent type: catalyst, reagent type: chelator
pore size	60 pore diameter
surface area	480-550 m²/g
solubility	all common solvents: soluble (organic and aqueous)
bulk density	679 g/L (typical tap density)

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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DPBP-bidentate phosphine

Empirical Formula (Hill Notation):	C₃₇H₂₈OP₂
CAS Number:	845821-92-3
Molecular Weight:	550.57
MDL number:	MFCD11045384
PubChem Substance ID:	329761486

Reactant for benzophenone-derived catalysts

Packaging

100, 500 mg in glass bottle

Legal Information

Sold in collaboration with Takasago for research purposes only. US7473793

Параметры

assay	95%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp	152-156 °C
functional group	phosphine
SMILES string	O=C(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6
InChI	1S/C37H28OP2/c38-37(33-25-13-15-27-35(33)39(29-17-5-1-6-18-29)30-19-7-2-8-20-30)34-26-14-16-28-36(34)40(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H
InChI key	RKNMFQXZZRUBQH-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	3

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Dysprosium(III) trifluoromethanesulfonate

Empirical Formula (Hill Notation):	C₃DyF₉O₉S₃
Linear Formula:	(CF₃SO₃)₃Dy
CAS Number:	139177-62-1
Molecular Weight:	609.71
MDL number:	MFCD00209583
PubChem Substance ID:	24866655
NACRES:	NA.22

Dysprosium(III) trifluoromethanesulfonate (Dysprosium(III) triflate) is a lanthanide triflate.

Application

Catalyst for:

Aza-Piancatelli rearrangement
Friedel-Crafts alkylation
Ring-opening polymerization reactions
Microwave-assisted Kabachnik-Fields condensation
Cycloaddition reactions (Lewis-acid catalyst)
Fries rearrangement
Enantioselective glyoxalate-ene reactions

Dysprosium(III) trifluoromethanesulfonate, a water-tolerant Lewis acid, has been used in the following studies:

Aldol reaction of silyl enol ethers with aldehydes.
As an effective catalyst for electrophilic substitution reactions of indoles with imines.
As catalyst for the synthesis of 4-aminocyclopentenones and functionalized azaspirocycles, via intramolecular aza-Piancatelli rearrangement.
As new curing initiator to study the curing of diglycidyl ether of bisphenol-A (DGEBA).

Packaging

5, 25 g in glass bottle

Параметры

assay	98%
reaction suitability	core: dysprosium, reagent type: catalyst reaction type: Ring-Opening Polymerization
SMILES string	[Dy+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI	1S/3CHF3O3S.Dy/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
InChI key	XSVCYDUEICANRJ-UHFFFAOYSA-K

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Erbium 693685-1EA

Empirical Formula (Hill Notation):	Er
CAS Number:	7440-52-0
Molecular Weight:	167.26
EC Number:	231-160-1
MDL number:	MFCD00010987
PubChem Substance ID:	329761611
NACRES:	NA.23

Packaging

1 ea in rigid mailer

Application

Used in Physical Vapor Deposition (PVD) processes, including thermal and electron-beam (e-beam) evaporation, for the preparation of thin films.

Quantity

1 ea = 25 x 25 mm

Параметры

assay	99.9% trace rare earth metals basis
form	foil
reaction suitability	reagent type: catalyst core: erbium
resistivity	86 µ-cm, 20°C
thickness	1 mm
bp	2868 °C (lit.)
mp	1529 °C (lit.)
density	9.062 g/mL at 25 °C (lit.)
SMILES string	[Er]
InChI	1S/Er
Inchi Key	UYAHIZSMUZPPFV-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Erbium(III) acetylacetonate hydrate 483990-5G

Empirical Formula (Hill Notation):	C₁₅H₂₁ErO₆ · xH₂O
Linear Formula:	Er(C₅H₇O₂)₃· xH₂O
CAS Number:	70949-24-5
Molecular Weight:	464.58 (anhydrous basis)
MDL number:	MFCD00150165
PubChem Substance ID:	24871928
NACRES:	NA.23

Application

The product may be used as one of the constituents used in the preparation of tris(acetylacetonate)mono(bathophenanthroline)erbium(III), [Er(acac)3(bath)]. It may be be used for the preparation of mono dispersed lanthanide oxide nanodisks.

Packaging

5 g in glass bottle

Параметры

assay	97%
form	powder or crystals
reaction suitability	core: erbium, reagent type: catalyst
mp	125 °C (dec.) (lit.)
SMILES string	[H]O[H].CC(=O)\C=C(\C)O[Er](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
InChI	1S/3C5H8O2.Er.H2O/c31-4(6)3-5(2)7;;/h33,6H,1-2H3;;1H2/q;;;+3;/p-3/b3*4-3-;;
InChI key	FDDVCZNWLBKVFL-KJVLTGTBSA-K

Safety Information

pictograms	GHS07,GHS08
signalword	Warning
hcodes	H302 + H312 - H315 - H319 - H335 - H361
pcodes	P201 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Erbium(III) trifluoromethanesulfonate

Empirical Formula (Hill Notation):	C₃ErF₉O₉S₃
Linear Formula:	(CF₃SO₃)₃Er
CAS Number:	139177-64-3
Molecular Weight:	614.47
MDL number:	MFCD00192126
PubChem Substance ID:	24866656
NACRES:	NA.22

5, 25 g in glass bottle

Application

A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes.

Параметры

Quality Level	100,
assay	98%
reaction suitability	core: erbium, reagent type: catalyst
SMILES string	[Er+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI	1S/3CHF3O3S.Er/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
Inchi Key	GLQOFBCJADYRKR-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Ethyl diphenylphosphinite

Empirical Formula (Hill Notation):	C₁₄H₁₅OP
Linear Formula:	(C₆H₅)₂POC₂H₅
CAS Number:	719-80-2
Molecular Weight:	230.24
EC Number:	211-951-8
MDL number:	MFCD00009087
PubChem Substance ID:	24848957

Quality Level	100,
assay	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.59 (lit.)
density	1.066 g/mL at 25 °C (lit.)
functional group	phosphine
storage temp.	2-8°C
SMILES string	CCOP(c1ccccc1)c2ccccc2
InChI	1S/C14H15OP/c1-2-15-16(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
Inchi Key	JCRCPEDXAHDCAJ-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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Ethylenebis(diphenylphosphine)

Empirical Formula (Hill Notation):	C₂₆H₂₄P₂
Linear Formula:	(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂
CAS Number:	1663-45-2
Molecular Weight:	398.42
Beilstein/REAXYS Number:	761261
EC Number:	216-769-2
MDL number:	MFCD00003047
PubChem Substance ID:	24863460
NACRES:	NA.22

1, 5 g in glass bottle

Application

Ligand for metal-catalyzed allylic alkylation; decarboxylation of allylic esters; 1,3-diene synthesis; cycloaddition reactions; carbonylation reactions.

Параметры

Quality Level	200,
assay	99%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp	137-142 °C (lit.)
functional group	phosphine
SMILES string	C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI	1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2
Inchi Key	QFMZQPDHXULLKC-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H335
pcodes	P261 - P271 - P304 + P340 + P312 - P403 + P233 - P405 - P501
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Ethylenebis(triphenylphosphine)platinum(0)

Empirical Formula (Hill Notation):	C₃₈H₃₄P₂Pt
Linear Formula:	[(C₆H₅)₃P]₂Pt(H₂C=CH₂)
CAS Number:	12120-15-9
Molecular Weight:	747.70
MDL number:	MFCD00012028
PubChem Substance ID:	24855778

Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds

Параметры

Quality Level	100,
reaction suitability	core: platinum, reagent type: catalyst
mp	129-132 °C (dec.) (lit.)
SMILES string	[Pt].C=C.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI	1S/2C18H15P.C2H4.Pt/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h21-15H;1-2H2;
Inchi Key	RZUASTIKPBCXPU-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Ethynylferrocene 442658-1G-A

Empirical Formula (Hill Notation):	C₁₂H₁₀Fe
Linear Formula:	(HC≡CC₅H₄)Fe(C₅H₅)
CAS Number:	1271-47-2
Molecular Weight:	210.05
MDL number:	MFCD03701501
PubChem Substance ID:	24867943
NACRES:	NA.22

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: iron, reagent type: catalyst
mp	50-54 °C (lit.)
storage temp.	2-8°C
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.C#C[C]2[CH][CH][CH][CH]2
InChI	1S/C7H5.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h1,3-6H;1-5H;
Inchi Key	HFWSJSDVVFIFRS-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Europium(III) trifluoromethanesulfonate

Empirical Formula (Hill Notation):	C₃F₉EuO₉S₃
Linear Formula:	(CF₃SO₃)₃Eu
CAS Number:	52093-25-1
Molecular Weight:	599.17
MDL number:	MFCD00209587
PubChem Substance ID:	24866657
NACRES:	NA.22

1, 5 g in glass bottle

Application

A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes.

Параметры

Quality Level	100,
assay	98%
reaction suitability	core: europium, reagent type: catalyst
SMILES string	[Eu+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI	1S/3CHF3O3S.Eu/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
InChI key	TWNOVENTEPVGEJ-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Fe/ppm Pd for nitro group reductions 809330-500MG

MDL number:	MFCD00011005
NACRES:	NA.22

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M,, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Packaging

500 mg in glass bottle

Caution

Handle under nitrogen and store under argon in refrigerator.

Other Notes

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature,
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following natures lead,

Параметры

Quality Level	100,
form	solid
composition	FeCl₂ (372870), 23.3-27.4 wt. % , MgCl₂ (M8266), 15.3-18.8 wt. % , Pd (203939), <0.3 wt. % , THF (186562), 53.5-61.6 wt. %
reaction suitability	core: iron, reagent type: catalyst
storage temp.	2-8°C

Safety Information

pictograms	GHS02,GHS05,GHS07,GHS08
signalword	Danger
hcodes	H225 - H290 - H302 - H318 - H335 - H351
pcodes	P201 - P210 - P233 - P261 - P280 - P305 + P351 + P338 + P310
Target Organs	Respiratory system
Supp Hazards	EUH018 - EUH019
RIDADR	UN 1773 8 / PGIII
WGK Germany	WGK 2
Flash Point F	1.4 °F
Flash Point C	-17 °C

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Fe/ppm Pd for Suzuki-Miyaura Cross-Couplings 799661-500MG

EC Number:

231-729-4

Application

Nanoparticles (NPs) of this material contain parts per million (ppm) levels of Pd. The NPs can catalyze Suzuki-Miyaura (SM) reactions, including cases involving highly challenging reaction partners. Nano micelles are employed to both solubilize and deliver the reaction partners to the Fe/ppm Pd catalyst resulting in C-C bond formation.

Packaging

500 mg in glass bottle

Параметры

Quality Level	100,
form	powder, crystals or chunks
reaction suitability	core: iron, reagent type: catalyst

Safety Information

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H290 - H302 - H315 - H318
pcodes	P234 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
RIDADR	UN 1773 8 / PGIII
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Ferrocene

Empirical Formula (Hill Notation):	C₁₀H₁₀Fe
Linear Formula:	Fe(C₅H₅)₂
CAS Number:	102-54-5
Molecular Weight:	186.03
EC Number:	203-039-3
MDL number:	MFCD00001427
PubChem Substance ID:	24894802
NACRES:	NA.22

Ferrocene (dicyclopentadienyliron) can be used:

As a scaffold for chiral ligands in asymmetric catalysis.
In ferrocene-based electrolytes for dye sensitized solar cells applications.
In the synthesis of unsymmetrical ferrocene ligands used as catalysts in cross-coupling, hydrogenation, allylic substitution, hydroformylation and aldol reactions.
In the synthesis of two-dimensional hexagonally ordered mesoporous carbon (CMK-5) via chemical vapor deposition method, which is used as a catalyst support in oxidation of methanol.
In the synthesis of molecular hybrids of ferrocene and fullerene (Bucky ferrocenes).
In the preparation of ferrocenium salt which is used as a mild oxidant.

Packaging

5, 100, 500 g in glass bottle

Параметры

Quality Level	100,
vapor pressure	0.03 mmHg ( 40 °C)
assay	98%
reaction suitability	core: iron, reagent type: catalyst
bp	249 °C (lit.)
mp	172-174 °C (lit.)
_max	358 nm
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI	1S/2C5H5.Fe/c21-2-4-5-3-1;/h21-5H;
InChI key	DFRHTHSZMBROSH-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS07,GHS08,GHS09
signalword	Danger
hcodes	H228 - H302 + H332 - H361 - H373 - H410
pcodes	P201 - P210 - P273 - P301 + P312 + P330 - P304 + P340 + P312 - P308 + P313
Target Organs	Liver
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN1325 - class 4.1 - PG 2 - EHS - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Ferroceneacetonitrile

Empirical Formula (Hill Notation):	C₁₂H₁₁FeN
CAS Number:	1316-91-2
Molecular Weight:	225.07
MDL number:	MFCD00068572
PubChem Substance ID:	24860283

Preparation of redox-active bis(ferrocenyl-amidine) anion sensor
Electrochemical detection of nucleic acids (DNA sensor)
Reactant in electron-transfer reactions
Reactant in electrooxidation reactions (indirect oxidation of the side chain)

Параметры

reaction suitability	core: iron, reagent type: catalyst
mp	81-83 °C (lit.)
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.N#CC[C]2[CH][CH][CH][CH]2
InChI	1S/C7H6N.C5H5.Fe/c8-6-5-7-3-1-2-4-7;1-2-4-5-3-1;/h1-4H,5H2;1-5H;
InChI key	UBCZLWARZCERJD-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302-H312-H315-H319-H332-H335
pcodes	P261-P280-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	3

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Ferrocenemethanol

Empirical Formula (Hill Notation):	C₁₁H₁₂FeO
CAS Number:	1273-86-5
Molecular Weight:	216.06
MDL number:	MFCD00040878
PubChem Substance ID:	24860285
NACRES:	NA.22

Ferrocenemethanol (FcMeOH) is commonly used as a water soluble ferrocene based reference redox system in electrochemical studies.
It is used in the synthesis of ferrocenylmethoxy-isatins, potent antiproliferative agents.
FcMeOH can be employed in the preparation of ferrocene-carbohydrate conjugates for biosensing applications.

Packaging

5 g in glass bottle
500 mg in glass bottle

Параметры

Quality Level	200,
assay	97%
reaction suitability	core: iron, reagent type: catalyst
mp	79-81 °C (lit.)
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.OC[C]2[CH][CH][CH][CH]2
InChI	1S/C6H7O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-4,7H,5H2;1-5H;
Inchi Key	QETISSZVCNFQBN-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Ferrocenium tetrafluoroborate 482358-5G

Empirical Formula (Hill Notation):	C₁₀H₁₀BF₄Fe
CAS Number:	1282-37-7
Molecular Weight:	272.84
MDL number:	MFCD00192174
PubChem Substance ID:	24871823
NACRES:	NA.22

Параметры

grade	technical grade
Quality Level	100,
reaction suitability	core: iron, reagent type: catalyst
mp	178 °C (dec.) (lit.)
SMILES string	[Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI	1S/2C5H5.BF4.Fe/c21-2-4-5-3-1;2-1(3,4)5;/h21-5H;;/q;;-1;+1
Inchi Key	ZSPXIHLQPWVOQR-UHFFFAOYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3261 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Fro-DO, mixture of diastereomers 804371-250MG

Empirical Formula (Hill Notation):	C₂₄H₂₂N₂O₆S₂
Molecular Weight:	498.57
PubChem Substance ID:	329768865
NACRES:	NA.22

Application

Enables the generation of quaternary centers by Ni-catalyzed cross coupling with aziridines.

Packaging

250 mg in glass bottle

Параметры

Quality Level	100,
assay	97%
form	powder
reaction suitability	core: nickel, reagent type: catalyst
SMILES string	O=C(N([C@H](C(C=CC=C1)=C1C2)[C@H]2C3)S3(=O)=O)/C=C/C(N4[C@H](C(C=CC=C5)=C5C6)[C@H]6CS4(=O)=O)=O
InChI	1S/C24H22N2O6S2/c27-21(25-23-17(13-33(25,29)30)11-15-5-1-3-7-19(15)23)9-10-22(28)26-24-18(14-34(26,31)32)12-16-6-2-4-8-20(16)24/h1-10,17-18,23-24H,11-14H2/b10-9+/t17-,18-,23+,24+/m1/s1
InChI key	CZVFUQRTDAQUQL-SKLQJEMHSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Gadolinium 693723-1EA

Empirical Formula (Hill Notation):	Gd
Linear Formula:	Gd
CAS Number:	7440-54-2
Molecular Weight:	157.25
EC Number:	231-162-2
MDL number:	MFCD00011022
PubChem Substance ID:	329761616
NACRES:	NA.23

Packaging

1 ea in rigid mailer

Application

Used in Physical Vapor Deposition (PVD) processes, including thermal and electron-beam (e-beam) evaporation, for the preparation of thin films.

Quantity

1 ea = 25 x 25 mm

Параметры

Quality Level	100,
assay	99.9% trace rare earth metals basis
form	foil
reaction suitability	reagent type: catalyst core: gadolinium
resistivity	126 µ-cm, 20°C
thickness	1 mm
bp	3273 °C (lit.)
mp	1313 °C (lit.)
density	7.886 g/mL at 25 °C (lit.)
SMILES string	[Gd]
InChI	1S/Gd
Inchi Key	UIWYJDYFSGRHKR-UHFFFAOYSA-N

Safety Information

pictograms	GHS02
signalword	Warning
hcodes	H261
pcodes	P231 + P232 - P422
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3208 4.3 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable