Chiral Catalysts &amp; Ligands

Sold in collaboration with Takasago for research purposes only.

optical activity	[]20/D +222°, c = 0.5% in benzene
Quality Level	100,
mp	239-241 °C (lit.)
SMILES string	c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
InChI	1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
Inchi Key	MUALRAIOVNYAIW-UHFFFAOYSA-N

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation,
Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters, cyclic β-(acylamino)acrylates and α-phthalimide ketones.
Packaging
100 mg in clear glass bottle
500 mg in amber glass bottle

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-C3-TunePhos-ruthenium complex

Empirical Formula (Hill Notation):	C₄₉H₄₆Cl₂O₂P₂Ru
CAS Number:	905709-79-7
Molecular Weight:	900.81
MDL number:	MFCD07782001
PubChem Substance ID:	24884439
NACRES:	NA.22

mp	>300 °C
Quality Level	100,
SMILES string	[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2COc3cccc(P(c4ccccc4)c5ccccc5)c3-c6c(OC2)cccc6P(c7ccccc7)c8ccccc8
InChI	1S/C39H32O2P2.C10H14.2ClH.Ru/c1-5-16-30(17-6-1)42(31-18-7-2-8-19-31)36-26-13-24-34-38(36)39-35(41-29-15-28-40-34)25-14-27-37(39)43(32-20-9-3-10-21-32)33-22-11-4-12-23-33;1-8(2)10-6-4-9(3)5-7-10;;;/h1-14,16-27H,15,28-29H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
InChI key	BOERIKXMDOKSHH-UHFFFAOYSA-L

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-C8-TCYP T511579-100MG

Empirical Formula (Hill Notation):	C₈₄H₁₁₃O₄P
Molecular Weight:	1217.77
MDL number:	MFCD26793806
PubChem Substance ID:	329826815

Other Notes

Quality Level	100,
SMILES string	O=P(O1)(O)OC2=C(C3=C(C4CCCCC4)C=C(C5CCCCC5)C=C3C6CCCCC6)C=C7C(C=CC(CCCCCCCC)=C7)=C2C8=C1C(C9=C(C%10CCCCC%10)C=C(C%11CCCCC%11)C=C9C%12CCCCC%12)=CC%13=CC(CCCCCCCC)=CC=C%138
InChI	1S/C84H113O4P/c1-3-5-7-9-11-19-33-59-47-49-71-69(51-59)57-77(79-73(63-39-25-15-26-40-63)53-67(61-35-21-13-22-36-61)54-74(79)64-41-27-16-28-42-64)83-81(71)82-72-50-48-60(34-20-12-10-8-6-4-2)52-70(72)58-78(84(82)88-89(85,86)87-83)80-75(65-43-29-17-30-44-65)55-68(62-37-23-14-24-38-62)56-76(80)66-45-31-18-32-46-66/h47-58,61-66H,3-46H2,1-2H3,(H,85,86)
Inchi Key	PQFDAAYIQUVLDR-UHFFFAOYSA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-C8-TRIP L511579-100MG

Empirical Formula (Hill Notation):	C₆₆H₈₉O₄P
Molecular Weight:	977.38
MDL number:	MFCD26793802
PubChem Substance ID:	329817520

Other Notes

Quality Level	100,
SMILES string	CC(C)C1=CC(C(C)C)=CC(C(C)C)=C1C2=CC3=CC(CCCCCCCC)=CC=C3C(C4=C(C=CC(CCCCCCCC)=C5)C5=CC(C6=C(C(C)C)C=C(C(C)C)C=C6C(C)C)=C4O7)=C2OP7(O)=O
InChI	1S/C66H89O4P/c1-15-17-19-21-23-25-27-47-29-31-53-51(33-47)39-59(61-55(43(7)8)35-49(41(3)4)36-56(61)44(9)10)65-63(53)64-54-32-30-48(28-26-24-22-20-18-16-2)34-52(54)40-60(66(64)70-71(67,68)69-65)62-57(45(11)12)37-50(42(5)6)38-58(62)46(13)14/h29-46H,15-28H2,1-14H3,(H,67,68)
Inchi Key	NQIIXPJAZNVETG-UHFFFAOYSA-N

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-DM-BINAP

Empirical Formula (Hill Notation):	C₅₂H₄₈P₂
CAS Number:	137219-86-4
Molecular Weight:	734.89
MDL number:	MFCD01630821
PubChem Substance ID:	329761489
NACRES:	NA.22

50 mg in glass bottle
100 mg in amber glass bottle

Sold in collaboration with Takasago for research purposes only.

optical activity	[]20/D +169°, c = 1 in chloroform
Quality Level	100,
mp	187-191 °C
InChI	1S/C52H48P2/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46/h9-32H,1-8H3
Inchi Key	MXGXXBYVDMVJAO-UHFFFAOYSA-N

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-DM-SEGPHOS®

Empirical Formula (Hill Notation):	C₄₆H₄₄O₄P₂
CAS Number:	850253-53-1
Molecular Weight:	722.79
MDL number:	MFCD09753008
PubChem Substance ID:	329761500

100 mg in amber glass bottle

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

optical activity	[]20/D +60, c = 0.1 in chloroform
Quality Level	100,
mp	256-261 °C
SMILES string	Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8
InChI	1S/C46H44O4P2/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38/h9-24H,25-26H2,1-8H3
InChI key	XJJVPYMFHXMROQ-UHFFFAOYSA-N

Takasago Ligands and Complexes for Asymmetric Reactions,
Catalyst involved in:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-DTBM-SEGPHOS®

Empirical Formula (Hill Notation):	C₇₄H₁₀₀O₈P₂
CAS Number:	566940-03-2
Molecular Weight:	1179.53
MDL number:	MFCD09753003
PubChem Substance ID:	329761501
NACRES:	NA.22

[3,3]-Sigmatropic rearrangements using cyclopropane probes
Asymmetric intramolecular hydroacylation of ketoaldehydes

Reactant involved in:

The synthesis of gold-diphosphine complexes for use as catalysts
Cycloaddition of allenenes to yield alkylidenecyclobutanes

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
InChI	1S/C74H100O8P2/c1-67(2,3)47-33-43(34-48(61(47)75-25)68(4,5)6)83(44-35-49(69(7,8)9)62(76-26)50(36-44)70(10,11)12)57-31-29-55-65(81-41-79-55)59(57)60-58(32-30-56-66(60)82-42-80-56)84(45-37-51(71(13,14)15)63(77-27)52(38-45)72(16,17)18)46-39-53(73(19,20)21)64(78-28)54(40-46)74(22,23)24/h29-40H,41-42H2,1-28H3
InChI key	ZNORAFJUESSLTM-UHFFFAOYSA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ethyl piperidine-3-carboxylate 696420-1G

Empirical Formula (Hill Notation):	C₈H₁₅NO₂
CAS Number:	25137-01-3
Molecular Weight:	157.21
MDL number:	MFCD03093637
PubChem Substance ID:	329761827
NACRES:	NA.22

Reactant for synthesis of:

DPP-4 inhibitors
Dual H1/5-HT2A receptor antagonists for treatment of sleep disorders
Serotonin and noradrenaline reuptake inhibitors
GABA uptake inhibitors

Reactant for stereocontrolled hydoiodination of alkynes

Used for an orally potent anti-anxiety drug

Quality Level	100,
assay	97%
density	1.092 g/mL at 25 °C
SMILES string	CCOC(=O)[C@@H]1CCCNC1
InChI	1S/C8H15NO2/c1-2-11-8(10)7-4-3-5-9-6-7/h7,9H,2-6H2,1H3/t7-/m1/s1
InChI key	XIWBSOUNZWSFKU-SSDOTTSWSA-N

The product is a diphenylphosphinobenzoic acid (DPPBA) based ligand for the palladium-catalyzed asymmetric allylic alkylation with a high degree of enantioselectivity.

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H315 - H318 - H335
pcodes	P261 - P280 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3

Узнать цену

Подробнее

(R)-H8-BINAP

Empirical Formula (Hill Notation):	C₄₄H₄₀P₂
CAS Number:	139139-86-9
Molecular Weight:	630.74
MDL number:	MFCD01630795
PubChem Substance ID:	329761490
NACRES:	NA.22

Takasago Ligands and Complexes for Asymmetric Reactions,
Catalytic ligand used for:

Enantioselective synthesis of dihydrobenzofurans and dihydronaphthofurans via olefin isomerization/enantioselective intramolecular Alder-ene reaction of enynes catalyzed by Rh
Preparation of axially chiral biaryl compounds by gold-catalyzed stereoselective intramolecular hydroarylation
Preparation of chiral 3-alkyl-substituted indolines by tandem condensation-asymmetric hydrogenation of indoles with aldehydes, catalyzed by Bronsted acids and palladium BINAP complexes
Stereoselective preparation of hydrindanes and decalins containing up to four contiguous stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of ene-allenes with allenes
Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes
Stereoselective preparation of 2,3-substituted indolines via Pd-catalyzed hydrogenation of (-hydroxyalkyl)indoles

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
assay	94%
optical activity	[]20/D +74°, c = 0.5 in toluene
InChI	1S/C44H40P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-12,19-26,29-32H,13-18,27-28H2
Inchi Key	ANSOKCGDSQQISA-UHFFFAOYSA-N

Mixture of branched isomers on the dodecyl chain

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319
pcodes	P302 + P352 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-HuaCat

Empirical Formula (Hill Notation):	C₂₃H₃₈N₂O₃S
CAS Number:	1134192-85-0
Molecular Weight:	422.62
PubChem Substance ID:	329764780
NACRES:	NA.22

100 mg in clear glass bottle
500 mg in amber glass bottle

Quality Level	100,
assay	95%
optical activity	[]/D 102.5°, c = 0.5 in chloroform
mp	201-206 °C
SMILES string	CCCCCCCCCCCCc1ccc(cc1)S(=O)(=O)NC(=O)[C@H]2CCCN2
InChI	1S/C23H38N2O3S/c1-2-3-4-5-6-7-8-9-10-11-13-20-15-17-21(18-16-20)29(27,28)25-23(26)22-14-12-19-24-22/h15-18,22,24H,2-14,19H2,1H3,(H,25,26)/t22-/m1/s1
InChI key	FAGYODAJNLXMRF-JOCHJYFZSA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Mac-H 685429-1G

Linear Formula:	(C₁₃H₁₉NO₄)₆ (C₈H₁₆N₂O · CF₃CO₂H)₁
PubChem Substance ID:	24885839

A mixture of a chiral imidazolidinone with the Hantzsch ethyl ester; formally transfers hydrogen asymmetrically to enals resulting in chiral aldehydes.

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

mp	99-145 °C
Quality Level	100,
SMILES string	OC(=O)C(F)(F)F.CN1[C@@H](NCC1=O)C(C)(C)C.CCOC(=O)C2=C(C)NC(C)=C(C2)C(=O)OCC
InChI	1S/C13H19NO4.C8H16N2O.C2HF3O2/c1-5-17-12(15)10-7-11(13(16)18-6-2)9(4)14-8(10)3;1-8(2,3)7-9-5-6(11)10(7)4;3-2(4,5)1(6)7/h14H,5-7H2,1-4H3;7,9H,5H2,1-4H3;(H,6,7)/t;7-;/m.1./s1
InChI key	VPEIUDRYFWHOML-QABCSGHHSA-N

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-N-Boc-1-oxa-4-azaspiro[4.5]decane-3-carboxaldehyde 762490-1G

Empirical Formula (Hill Notation):	C₁₄H₂₃NO₄
CAS Number:	171623-07-7
Molecular Weight:	269.34
MDL number:	MFCD24849718
PubChem Substance ID:	329766979
NACRES:	NA.22

Quality Level	100,
assay	95%
optical activity	[]22/D +69.0°, c = 1% in chloroform
mp	53-58 °C
storage temp.	20°C
SMILES string	CC(C)(C)OC(=O)N1[C@H](COC12CCCCC2)C=O
InChI	1S/C14H23NO4/c1-13(2,3)19-12(17)15-11(9-16)10-18-14(15)7-5-4-6-8-14/h9,11H,4-8,10H2,1-3H3/t11-/m0/s1
Inchi Key	ZUQSKYAYHQZQFX-NSHDSACASA-N

Efficient ligand for asymmetric hydrogenation
(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine-rhodium complex can efficiently catalyze the asymmetric hydrogenation of 2-tert-butoxycarbonylamino-3-cyclopropylacrylic acid benzyl ester to form (S)-2-tert-butoxycarbonylamino-3-cyclopropylpropionic acid benzyl ester.

pictograms	GHS05,GHS07,GHS09
signalword	Danger
hcodes	H302 - H315 - H318 - H335 - H400
pcodes	P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
Target Organs	Respiratory system
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine

Empirical Formula (Hill Notation):	C₃₇H₃₅FeNP₂
CAS Number:	406680-94-2
Molecular Weight:	611.47
MDL number:	MFCD05865220
PubChem Substance ID:	329760488
NACRES:	NA.22

100 mg in clear glass bottle
500 mg in amber glass bottle

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.

Quality Level	100,
assay	96%
mp	108.7-113.6 °C
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
InChI	1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
InChI key	ZIAZHUWEJYUGEO-FBHGDYMESA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-N-[(1R,2R)-2-(3-(3,5-Bis(trifluoromethyl)phenyl)ureido)cyclohexyl]-tert-butyl-sulfinamide

Empirical Formula (Hill Notation):	C₁₉H₂₅F₆N₃O₂S
CAS Number:	934762-68-2
Molecular Weight:	473.48
MDL number:	MFCD11656068
PubChem Substance ID:	329762164
NACRES:	NA.22

Quality Level	100,
assay	96%
mp	173-181 °C
SMILES string	CC(C)(C)S(=O)N[C@@H]1CCCC[C@H]1NC(=O)Nc2cc(cc(c2)C(F)(F)F)C(F)(F)F
InChI	1S/C19H25F6N3O2S/c1-17(2,3)31(30)28-15-7-5-4-6-14(15)27-16(29)26-13-9-11(18(20,21)22)8-12(10-13)19(23,24)25/h8-10,14-15,28H,4-7H2,1-3H3,(H2,26,27,29)/t14-,15-,31-/m1/s1
Inchi Key	WMIJNZVQFOPOBW-ZHANGXNJSA-N

Takasago Ligands and Complexes for Asymmetric Reactions,
Catalyst for:

hcodes	H413
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ru(OAc)2(BINAP)

Empirical Formula (Hill Notation):	C₄₈H₃₈O₄P₂Ru
CAS Number:	325146-81-4
Molecular Weight:	841.83
MDL number:	MFCD09753020
PubChem Substance ID:	329761476
NACRES:	NA.22

Asymmetric hydrogenation reactions

(R)-Ru(OAc)2(BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins. It can also catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
SMILES string	CC(=O)O[Ru]OC(C)=O.c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
InChI	1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;21-2(3)4;/h1-32H;21H3,(H,3,4);/q;;;+2/p-2
Inchi Key	NMLZYEWNUCRSRJ-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ru(OAc)2(DM-BINAP)

Empirical Formula (Hill Notation):	C₅₆H₅₄O₄P₂Ru
CAS Number:	374067-50-2
Molecular Weight:	954.04
MDL number:	MFCD09753022
PubChem Substance ID:	329761469
NACRES:	NA.22

250 mg in amber glass bottle
50, 100 mg in glass bottle

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
InChI	1S/C52H48P2.2C2H4O2.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;21-2(3)4;/h9-32H,1-8H3;21H3,(H,3,4);/q;;;+2/p-2
Inchi Key	IFUMNSKQNPECEY-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,
Catalyst for:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ru(OAc)2(DM-SEGPHOS®)

Empirical Formula (Hill Notation):	C₅₀H₅₀O₈P₂Ru
Molecular Weight:	941.94
MDL number:	MFCD09753025
PubChem Substance ID:	329761472
NACRES:	NA.22

Stereoselective preparation of -amino amides via ruthenium segphos complex-catalyzed asymmetric reductive amination of -keto amides

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
storage temp.	2-8°C
SMILES string	CC(=O)O[Ru]OC(C)=O.Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8
InChI	1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;21-2(3)4;/h9-24H,25-26H2,1-8H3;21H3,(H,3,4);/q;;;+2/p-2
Inchi Key	ACKYBTAGKAINOG-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ru(OAc)2(H8-BINAP)

Empirical Formula (Hill Notation):	C₄₈H₄₆O₄P₂Ru
CAS Number:	374067-51-3
Molecular Weight:	849.89
MDL number:	MFCD09753023
PubChem Substance ID:	329761470
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
SMILES string	CC(=O)O[Ru]OC(C)=O.C1CCc2c(C1)ccc(P(c3ccccc3)c4ccccc4)c2-c5c6CCCCc6ccc5P(c7ccccc7)c8ccccc8
InChI	1S/C44H40P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;21-2(3)4;/h1-12,19-26,29-32H,13-18,27-28H2;21H3,(H,3,4);/q;;;+2/p-2
InChI key	HZRBASMTZGJUJU-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ru(OAc)2(SEGPHOS®)

Empirical Formula (Hill Notation):	C₄₂H₃₄O₈P₂Ru
CAS Number:	944450-48-0
Molecular Weight:	829.73
MDL number:	MFCD09753024
PubChem Substance ID:	329761471
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
storage temp.	2-8°C
InChI	1S/C38H28O4P2.2C2H4O2.Ru/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;21-2(3)4;/h1-24H,25-26H2;21H3,(H,3,4);/q;;;+2/p-2
InChI key	BHGLLIGZFQVMBJ-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Ru(OAc)2(T-BINAP)

Empirical Formula (Hill Notation):	C₅₂H₄₆O₄P₂Ru
CAS Number:	116128-29-1
Molecular Weight:	897.94
MDL number:	MFCD09753021
PubChem Substance ID:	329761477
NACRES:	NA.22

100 mg in clear glass bottle
500 mg in amber glass bottle

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
SMILES string	CC(=O)O[Ru]OC(C)=O.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
InChI	1S/C48H40P2.2C2H4O2.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;21-2(3)4;/h5-32H,1-4H3;21H3,(H,3,4);/q;;;+2/p-2
InChI key	HXHQOYKBZFDKSM-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-RuCl[(p-cymene)(BINAP)]Cl

Empirical Formula (Hill Notation):	C₅₄H₄₆Cl₂P₂Ru
Linear Formula:	[C₅₄H₄₆ClP₂Ru]+Cl-
CAS Number:	145926-28-9
Molecular Weight:	928.87
MDL number:	MFCD00134456
PubChem Substance ID:	329761502
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
SMILES string	[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.c2ccc(cc2)P(c3ccccc3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI	1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
Inchi Key	WNHLGYRPKARUHY-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-RuCl[(p-cymene)(DM-SEGPHOS®)]Cl

Empirical Formula (Hill Notation):	C₅₆H₅₈Cl₂O₄P₂Ru
Linear Formula:	[C₅₆H₅₈ClO₄P₂Ru]+Cl⁻
CAS Number:	944451-30-3
Molecular Weight:	1028.98
MDL number:	MFCD09753018
PubChem Substance ID:	329761493
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
storage temp.	2-8°C
SMILES string	Cl[Ru]Cl.CC(C)c1ccc(C)cc1.Cc2cc(C)cc(c2)P(c3cc(C)cc(C)c3)c4ccc5OCOc5c4-c6c7OCOc7ccc6P(c8cc(C)cc(C)c8)c9cc(C)cc(C)c9
InChI	1S/C46H44O4P2.C10H14.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;1-8(2)10-6-4-9(3)5-7-10;;;/h9-24H,25-26H2,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
Inchi Key	LLNJPFQWQJQPEH-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-RuCl[p-cymene)(H8-BINAP)]Cl

Empirical Formula (Hill Notation):	C₅₄H₅₄Cl₂P₂Ru
Linear Formula:	[C₅₄H₅₄ClP₂Ru]+Cl−
CAS Number:	944451-26-7
Molecular Weight:	936.93
PubChem Substance ID:	329761504

Sold in collaboration with Takasago for research purposes only.

storage temp.	2-8°C
Quality Level	100,
SMILES string	[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2CCc3c(C2)ccc(P(c4ccccc4)c5ccccc5)c3-c6c7CCCCc7ccc6P(c8ccccc8)c9ccccc9
InChI	1S/C44H40P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-12,19-26,29-32H,13-18,27-28H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
InChI key	RDVYAXZMACLMGN-UHFFFAOYSA-L

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-SDP 700754-50MG

Empirical Formula (Hill Notation):	C₄₁H₃₄P₂
CAS Number:	917377-74-3
Molecular Weight:	588.66
MDL number:	MFCD08459344
PubChem Substance ID:	329762228
NACRES:	NA.22

optical activity	[]22/D +184°, c = 1 in chloroform
Quality Level	100,
mp	198-203 °C
storage temp.	20°C
InChI	1S/C41H34P2/c1-5-17-33(18-6-1)42(34-19-7-2-8-20-34)37-25-13-15-31-27-29-41(39(31)37)30-28-32-16-14-26-38(40(32)41)43(35-21-9-3-10-22-35)36-23-11-4-12-24-36/h1-26H,27-30H2
InChI key	DKZNVWNOOLQCMJ-UHFFFAOYSA-N

Takasago Ligands and Complexes for Asymmetric Reactions,
Catalytic ligand used for:

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-SEGPHOS®

Empirical Formula (Hill Notation):	C₃₈H₂₈O₄P₂
CAS Number:	244261-66-3
Molecular Weight:	610.57
MDL number:	MFCD09753005
PubChem Substance ID:	329761491
NACRES:	NA.22

Nickel-catalyzed asymmetric -arylation and heteroarylation of ketones with chloroarenes
Enantioselective synthesis of dihydrobenzofurans and dihydronaphthofurans via olefin isomerization/enantioselective intramolecular Alder-ene reaction of enynes catalyzed by Rh
Preparation of axially chiral biaryl compounds by gold-catalyzed stereoselective intramolecular hydroarylation
Preparation of chiral silylated homoallylic alcohols and diols by asymmetric addition of alcohols and aldehydes to silylbutadienes catalyzed by ruthenium complexes
Preparation of chiral 3-alkyl-substituted indolines by tandem condensation-asymmetric hydrogenation of indoles with aldehydes, catalyzed by Bronsted acids and palladium BINAP complexes
Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes

50 mg in glass bottle
100 mg in amber glass bottle

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
assay	94%
optical activity	[]20/D +11°, c = 0.5 in chloroform
mp	168-172 °C
SMILES string	C1Oc2ccc(P(c3ccccc3)c4ccccc4)c(c2O1)-c5c6OCOc6ccc5P(c7ccccc7)c8ccccc8
InChI	1S/C38H28O4P2/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30/h1-24H,25-26H2
Inchi Key	RZZDRSHFIVOQAF-UHFFFAOYSA-N

(R)-SIPHOS-PE can be used as:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-SIPHOS-PE

Empirical Formula (Hill Notation):	C₃₃H₃₂NO₂P
CAS Number:	500997-69-3
Molecular Weight:	505.59
MDL number:	MFCD08459342
PubChem Substance ID:	329762230

A catalyst in the preparation of tricyclic alkaloid (+)-aphanorphine via asymmetric carboamination and FriedelCrafts reaction.
A ligand in the synthesis of chiral ketones via hydroacylation of olefins using salicylaldehyde derivatives.
A ligand in the enantioselective synthesis of substituted pyrrolidine derivatives via Pd-catalyzed alkene aminoarylation reactions.

50, 250 mg in amber glass bottle

Quality Level	100,
assay	97%
optical activity	[]22/D +337°, c = 1 in chloroform
mp	90-96 °C
storage temp.	20°C
InChI	1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1
Inchi Key	ZXLQLIDJAURBDD-HRPAVAKOSA-N

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P261 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

T511595-100MG

(R)-TCYP T511595-100MG

Empirical Formula (Hill Notation): C₆₈H₈₁O₄P

Molecular Weight: 993.34

Other Notes
Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
Параметры

Quality Level 100,

SMILES string OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)C6CCCCC6)C7CCCCC7

Safety Information

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

Узнать цену Получить предложение
Подробнее

(R)-Tetrahydro-3-furoic acid 712280-500MG

CAS Number:	66838-42-4
Beilstein/REAXYS Number:	1281202
MDL number:	MFCD07369940
PubChem Substance ID:	329763124

assay	97.0% (GC), 97.0%, 97.0-103.0% (T)
optical purity	enantiomeric excess: 95.0%
SMILES string	OC(=O)[C@@H]1CCOC1
InChI	1S/C5H8O3/c6-5(7)4-1-2-8-3-4/h4H,1-3H2,(H,6,7)/t4-/m1/s1
InChI key	BOTREHHXSQGWTR-SCSAIBSYSA-N

pictograms	GHS07
signalword	Warning
hcodes	H319
pcodes	P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Tetrahydrofuran-2-carbonitrile 67948-1G-F

Empirical Formula (Hill Notation):	C₅H₇NO
CAS Number:	164472-78-0
Molecular Weight:	97.12
Beilstein/REAXYS Number:	7197285
MDL number:	MFCD04974569
PubChem Substance ID:	57652114
NACRES:	NA.22

Quality Level	100,
assay	98.0% (sum of enantiomers, GC)
optical purity	enantiomeric ratio: 99:1 (GC)
storage temp.	2-8°C
SMILES string	N#C[C@H]1CCCO1
InChI	1S/C5H7NO/c6-4-5-2-1-3-7-5/h5H,1-3H2/t5-/m1/s1
Inchi Key	RZZIKHSWRWWPAN-RXMQYKEDSA-N

pictograms	GHS02,GHS07
signalword	Danger
hcodes	H225 - H302 + H312 + H332 - H315 - H319 - H335
pcodes	P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3273 6.1(3) / PGII
WGK Germany	WGK 2
Flash Point F	1.4 °F
Flash Point C	-17 °C

Узнать цену

Подробнее

(R)-Tetrahydrofurfuryl alcohol 89095-1G-F

Empirical Formula (Hill Notation):	C₅H₁₀O₂
CAS Number:	22415-59-4
Molecular Weight:	102.13
Beilstein/REAXYS Number:	79846
MDL number:	MFCD03093085
PubChem Substance ID:	57653325
NACRES:	NA.22

(R)-Tetrahydrofurfuryl alcohol can be used:

To prepare (R)-tetrahydrofurfuryl aldehyde, which is employed as a building block to synthesize a fragment of pectenotoxin-4.
As a starting material to synthesize naftidrofuryl isomers, used as potent 5-hydroxytryptamine 2A receptor antagonists.
As a building block for the preparation of (S)-2-tetrahydrofuran methyl ether 6-fluorophenyl ether analog, as an IGF-1R inhibitor.

Quality Level	100,
assay	98.0% (sum of enantiomers, GC)
optical purity	enantiomeric ratio: 97:3% (GC)
bp	178 °C (lit.)
density	1.054 g/mL at 20 °C (lit.)
SMILES string	OC[C@H]1CCCO1
InChI	1S/C5H10O2/c6-4-5-2-1-3-7-5/h5-6H,1-4H2/t5-/m1/s1
Inchi Key	BSYVTEYKTMYBMK-RXMQYKEDSA-N

pictograms	GHS07
signalword	Warning
hcodes	H319
pcodes	P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-VANOL 675156-250MG

Empirical Formula (Hill Notation):	C₃₂H₂₂O₂
CAS Number:	147702-13-4
Molecular Weight:	438.52
MDL number:	MFCD08459338
PubChem Substance ID:	24885264
NACRES:	NA.22

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
(R)-VANOL is a vaulted biaryl ligand that may be used in the following processes:

Transformation of 3-substituted cyclobutanones to enantiopure -butyrolactones via asymmetric Baeyer-Villiger Reaction in the presence of an aluminum catalyst.
Asymmetric aziridination of N-(4-(Methylsulfonyl)benzylidene)diphenylmethanamine to form (2S,3S)-ethyl 1-benzhydryl-3-(4-(methylsulfonyl)phenyl) aziridine-2-carboxylate.
Conjugate addition of terminal alkynes to 2-arylidene-1,3-diketones with high enantioselectivity in the presence of diethyl zinc.

250 mg in amber glass bottle

Quality Level	100,
assay	97%
optical activity	[]20/D +310°, c = 1 in chloroform
mp	200-204 °C
SMILES string	Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
InChI	1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
Inchi Key	NDTDVKKGYBULHF-UHFFFAOYSA-N

100 mg in clear glass bottle
500 mg in amber glass bottle

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H315 - H318 - H335 - H413
pcodes	P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-VAPOL

Empirical Formula (Hill Notation):	C₄₀H₂₆O₂
CAS Number:	147702-16-7
Molecular Weight:	538.63
MDL number:	MFCD11617354
PubChem Substance ID:	24885269
NACRES:	NA.22

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

Quality Level	100,
assay	97%
optical activity	[]20/D -144°, c = 1 in chloroform
mp	225-229 °C
SMILES string	Oc1c(c(cc2ccc3ccccc3c12)-c4ccccc4)-c5c(O)c6c(ccc7ccccc67)cc5-c8ccccc8
InChI	1S/C40H26O2/c41-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)42/h1-24,41-42H
InChI key	UFYXKDMLGBKHIC-UHFFFAOYSA-N

pictograms	GHS05,GHS07,GHS08
signalword	Danger
hcodes	H315 - H318 - H335 - H351
pcodes	P201 - P202 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Xyl-SDP 700843-50MG

Empirical Formula (Hill Notation):	C₄₉H₅₀P₂
CAS Number:	917377-75-4
Molecular Weight:	700.87
MDL number:	MFCD08459343
PubChem Substance ID:	329762237

Quality Level	100,
optical activity	[]22/D +64.0, c = 1 in chloroform
mp	>300 °C
storage temp.	20°C
InChI	1S/C49H50P2/c1-31-19-32(2)24-41(23-31)50(42-25-33(3)20-34(4)26-42)45-13-9-11-39-15-17-49(47(39)45)18-16-40-12-10-14-46(48(40)49)51(43-27-35(5)21-36(6)28-43)44-29-37(7)22-38(8)30-44/h9-14,19-30H,15-18H2,1-8H3
Inchi Key	AZSBNBQMIMQOPG-UHFFFAOYSA-N

pictograms	GHS07
signalword	Warning
hcodes	H302
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-Xyl-SDP(O) 798711-50MG

Empirical Formula (Hill Notation):	C₄₉H₅₀OP₂
CAS Number:	1462321-89-6
Molecular Weight:	716.87
PubChem Substance ID:	329768666

Chiral ligand introduced in collaboration with Prof. Steve Zhou and coworkers, has shown utility in asymmetric Heck reactions for both intra and intermolecular C-C bond formation with various triflates and halides.

Asymmetric Intermolecular Heck Reaction of Aryl Halides,
Palladium-Catalyzed Asymmetric Intermolecular Cyclization,

50 mg in glass bottle

Other Notes

Quality Level	100,
assay	95%
storage temp.	2-8°C
SMILES string	CC1=CC(C)=CC(P(C2=CC(C)=CC(C)=C2)(C3=CC=CC4=C3[C@]5(CCC6=C5C(P(C7=CC(C)=CC(C)=C7)C8=CC(C)=CC(C)=C8)=CC=C6)CC4)=O)=C1
InChI	1S/C49H50OP2/c1-31-19-32(2)24-41(23-31)51(42-25-33(3)20-34(4)26-42)45-13-9-11-39-15-17-49(47(39)45)18-16-40-12-10-14-46(48(40)49)52(50,43-27-35(5)21-36(6)28-43)44-29-37(7)22-38(8)30-44/h9-14,19-30H,15-18H2,1-8H3/t49-/m1/s1
InChI key	ZAQVAUFRFBAVHF-ANFMRNGASA-N

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-[(RuCl(BINAP))2(-Cl)3[NH2Me2]

Empirical Formula (Hill Notation):	C₉₀H₇₂Cl₅NP₄Ru₂
Linear Formula:	(CH₃)₂NH₂+[C₈₈H₆₄Cl₅P₄Ru₂]-
CAS Number:	199684-47-4
Molecular Weight:	1670.84
MDL number:	MFCD09753033
PubChem Substance ID:	329761496
NACRES:	NA.22

Sold in collaboration with Takasago for reseach purposes only. JP Application No. 19960232650

Quality Level	100,
storage temp.	2-8°C
InChI	1S/2C44H32P2.C2H7N.2ClH.3Cl.2Ru/c21-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h21-32H;3H,1-2H3;21H;;;;;/q;;;;;3+1;2*-1/p-1
InChI key	FRRCROPKBKLCMQ-UHFFFAOYSA-M

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-[(RuCl(DM-BINAP))2(-Cl)3][NH2Me2]

Empirical Formula (Hill Notation):	C₁₀₆H₁₀₄Cl₅NP₄Ru₂
Linear Formula:	(CH₃)₂NH₂+[C₁₀₄H₉₆Cl₅P₄Ru₂]-
CAS Number:	944451-08-5
Molecular Weight:	1895.27
MDL number:	MFCD09753035
PubChem Substance ID:	329761499
NACRES:	NA.22

50, 100 mg in glass bottle

Sold in collaboration with Takasago for reseach purposes only. JP Registration No. 3445074

Quality Level	100,
storage temp.	2-8°C
SMILES string	Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10.Cc%11cc(C)cc(c%11)P(c%12cc(C)cc(C)c%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17cc(C)cc(C)c%17)c%18cc(C)cc(C)c%18
InChI	1S/2C52H48P2.C2H7N.2ClH.3Cl.2Ru/c21-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-3-2;;;;;;;/h29-32H,1-8H3;3H,1-2H3;21H;;;;;/q;;;;;3+1;2*-1/p-1
InChI key	LGSCCUXQQTYWAH-UHFFFAOYSA-M

Takasago Ligands and Complexes for Asymmetric Reactions,

pictograms	GHS02
signalword	Warning
hcodes	H228
pcodes	P210
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-[(RuCl(H8-BINAP))2(-Cl)3][NH2Me2]

Empirical Formula (Hill Notation):	C₉₀H₈₈Cl₅NP₄Ru₂
Linear Formula:	(CH₃)₂NH₂+[C₈₈H₈₀Cl₅P₄Ru₂]−
CAS Number:	204933-84-6
Molecular Weight:	1686.97
MDL number:	MFCD09753036
PubChem Substance ID:	329761473
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3445074

Quality Level	100,
storage temp.	2-8°C
SMILES string	Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3CCc4c(C3)ccc(P(c5ccccc5)c6ccccc6)c4-c7c(ccc8CCCCc78)P(c9ccccc9)c%10ccccc%10.C%11CCc%12c(C%11)ccc(P(c%13ccccc%13)c%14ccccc%14)c%12-c%15c(ccc%16CCCCc%15%16)P(c%17ccccc%17)c%18ccccc%18
InChI	1S/2C44H40P2.C2H7N.2ClH.3Cl.2Ru/c21-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h21-12,19-26,29-32H,13-18,27-28H2;3H,1-2H3;21H;;;;;/q;;;;;3+1;2*-1/p-1
Inchi Key	BQQWMTMUAYPPMV-UHFFFAOYSA-M

(R)-[(RuCl(SEGPHOS®))2(µ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS®, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-[(RuCl(SEGPHOS®))2(-Cl)3][NH2Me2]

Empirical Formula (Hill Notation):	C₇₈H₆₄Cl₅NO₈P₄Ru₂
Linear Formula:	(CH₃)₂NH₂+[C₇₆H₅₆Cl₅O₈P₄Ru₂]-
CAS Number:	346457-41-8
Molecular Weight:	1646.64
MDL number:	MFCD09753037
PubChem Substance ID:	329761474
NACRES:	NA.22

Takasago Ligands and Complexes for Asymmetric Reactions,

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136, 3549390
SEGPHOS is a registered trademark of Takasago Intl. Corp.

storage temp.	2-8°C
Quality Level	100,
SMILES string	Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3Oc4ccc(P(c5ccccc5)c6ccccc6)c(c4O3)-c7c8OCOc8ccc7P(c9ccccc9)c%10ccccc%10.C%11Oc%12ccc(P(c%13ccccc%13)c%14ccccc%14)c(c%12O%11)-c%15c%16OCOc%16ccc%15P(c%17ccccc%17)c%18ccccc%18
InChI	1S/2C38H28O4P2.C2H7N.2ClH.3Cl.2Ru/c21-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-3-2;;;;;;;/h21-24H,25-26H2;3H,1-2H3;21H;;;;;/q;;;;;3+1;2*-1/p-1
InChI key	RENFEASRVBXAEN-UHFFFAOYSA-M

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)-[(RuCl(T-BINAP))2(-Cl)3[NH2Me2]

Empirical Formula (Hill Notation):	C₉₈H₈₈Cl₅NP₄Ru₂
Linear Formula:	(CH₃)₂NH₂+[C₉₆H₈₀Cl₅P₄Ru₂]−
CAS Number:	749935-02-2
Molecular Weight:	1783.05
MDL number:	MFCD09753034
PubChem Substance ID:	329761498
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
SMILES string	Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3ccc(cc3)P(c4ccc(C)cc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccc(C)cc9)c%10ccc(C)cc%10.Cc%11ccc(cc%11)P(c%12ccc(C)cc%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17ccc(C)cc%17)c%18ccc(C)cc%18
InChI	1S/2C48H40P2.C2H7N.2ClH.3Cl.2Ru/c21-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-3-2;;;;;;;/h25-32H,1-4H3;3H,1-2H3;21H;;;;;/q;;;;;3+1;2*-1/p-1
InChI key	QGBBTZBFEYSGDQ-UHFFFAOYSA-M

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)RuCl[(pcymene)(DMBINAP)]Cl

Empirical Formula (Hill Notation):	C₆₂H₆₂Cl₂P₂Ru
Linear Formula:	[C₆₂H₆₂ClP₂Ru]+Cl−
CAS Number:	944451-24-5
Molecular Weight:	1041.08
PubChem Substance ID:	329761492
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only.

Quality Level	100,
storage temp.	2-8°C
SMILES string	[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.Cc2cc(C)cc(c2)P(c3cc(C)cc(C)c3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8cc(C)cc(C)c8)c9cc(C)cc(C)c9
InChI	1S/C52H48P2.C10H14.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-8(2)10-6-4-9(3)5-7-10;;;/h9-32H,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
InChI key	CBZXDZCPCDMKJU-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)RuCl[(pcymene)(SEGPHOS®)]Cl

Empirical Formula (Hill Notation):	C₄₈H₄₂Cl₂O₄P₂Ru
Linear Formula:	[C₄₈H₄₂ClO₄P₂Ru]+Cl⁻
CAS Number:	944451-28-9
Molecular Weight:	916.77
PubChem Substance ID:	329761505
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
storage temp.	2-8°C
SMILES string	[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2Oc3ccc(P(c4ccccc4)c5ccccc5)c(c3O2)-c6c7OCOc7ccc6P(c8ccccc8)c9ccccc9
InChI	1S/C38H28O4P2.C10H14.2ClH.Ru/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-8(2)10-6-4-9(3)5-7-10;;;/h1-24H,25-26H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
Inchi Key	HZLSGDCLBWZKRB-UHFFFAOYSA-L

Takasago Ligands and Complexes for Asymmetric Reactions,
(R)-[(RuCl(DM-SEGPHOS®)2(µ-Cl)3][NH2Me2] can be used as a catalyst for the asymmetric hydrogenation of ketones to chiral alcohols. It can also be utilized to prepare (R)-methyl-3-hydroxybutanoate from methyl acetoacetate via stereoselective hydrogenation reaction.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R)[(RuCl(DMSEGPHOS®)2(Cl)3][NH2Me2]

Empirical Formula (Hill Notation):	C₉₄H₉₆Cl₅NO₈P₄Ru₂
Linear Formula:	(CH₃)₂NH₂+[C₉₂H₈₈Cl₅O₈Ru₂]−
CAS Number:	935449-46-0
Molecular Weight:	1871.07
MDL number:	MFCD09753038
PubChem Substance ID:	329761475
NACRES:	NA.22

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136, 3549390
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Quality Level	100,
storage temp.	2-8°C
SMILES string	Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10.Cc%11cc(C)cc(c%11)P(c%12cc(C)cc(C)c%12)c%13ccc%14OCOc%14c%13-c%15c%16OCOc%16ccc%15P(c%17cc(C)cc(C)c%17)c%18cc(C)cc(C)c%18
InChI	1S/2C46H44O4P2.C2H7N.2ClH.3Cl.2Ru/c21-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;1-3-2;;;;;;;/h29-24H,25-26H2,1-8H3;3H,1-2H3;21H;;;;;/q;;;;;3+1;2*-1/p-1
Inchi Key	YOYDPZZYORNKOE-UHFFFAOYSA-M

Acetalization reagent for ketones and -keto esters. Used in the synthesis of optically active polyesters. C2 symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R,R)-()-2,4-Pentanediol

Empirical Formula (Hill Notation):	C₅H₁₂O₂
Linear Formula:	CH₃CH(OH)CH₂CH(OH)CH₃
CAS Number:	42075-32-1
Molecular Weight:	104.15
Beilstein/REAXYS Number:	4290613
MDL number:	MFCD00063893
PubChem Substance ID:	24854603
NACRES:	NA.22

Quality Level	100,
assay	99%
optical activity	[]21/D 40.4°, c = 10 in chloroform
optical purity	ee: 97% (GLC)
bp	111-113 °C/19 mmHg (lit.)
mp	48-50 °C (lit.)
SMILES string	C[C@@H](O)C[C@@H](C)O
InChI	1S/C5H12O2/c1-4(6)3-5(2)7/h4-7H,3H2,1-2H3/t4-,5-/m1/s1
Inchi Key	GTCCGKPBSJZVRZ-RFZPGFLSSA-N

Versatile ligand for asymmetric catalysis. Ligand used for preparing Jacobsens catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.

Lipases are used industrially for the resolution of chiral compounds and the transesterification production of biodiesel.
Amylases from Aspergillus oryzae are used to prevent staling in the baking industry, clarify haze from fruit juices and alcoholic beverages, and produce glucose and maltose syrup products.

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	213.8 °F - closed cup
Flash Point C	101 °C - closed cup

Узнать цену

Подробнее

(R,R)-()-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

Empirical Formula (Hill Notation):	C₃₆H₅₄N₂O₂
Linear Formula:	[[(CH₃)₃C]₂C₆H₂-2-(OH)CH=N]₂C₆H₁₀
CAS Number:	135616-40-9
Molecular Weight:	546.83
Beilstein/REAXYS Number:	5464823
MDL number:	MFCD00191800
PubChem Substance ID:	24865244
NACRES:	NA.22

α-amylase catalyzes the hydrolysis of internal α-1,4-O-glycosidic bonds in starches to release α-anomeric sugars.
Lipases catalyze the hydrolysis of triacylglycerols into glycerol and free fatty acids.

1, 5 g in glass bottle

Biochem/physiol Actions

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

Quality Level	100,
assay	98%
optical activity	[]20/D 315±15°, c = 1 in methylene chloride
mp	205-207 °C (lit.)
SMILES string	CC(C)(C)c1cc(\C=N\[C@@H]2CCCC[C@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C
InChI	1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m1/s1
InChI key	FYNXDGNCEBQLGC-LQWPWIHBSA-N

1, 5, 25 g in glass bottle

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R,R)-()-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

Empirical Formula (Hill Notation):	C₃₆H₅₂CoN₂O₂
Linear Formula:	[[[(CH₃)₃C]₂C₆H₂-2-(O-)CH=N]₂C₆H₁₀]Co
CAS Number:	176763-62-5
Molecular Weight:	603.74
MDL number:	MFCD01631277
PubChem Substance ID:	24871023
NACRES:	NA.22

Catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.

Sold under license from Sterling Pharma Solutions Limited.

Quality Level	100,
mp	>350 °C (lit.)
SMILES string	CC(C)(C)c1cc2C=[N@H]3[C@@H]4CCCC[C@H]4[N@@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI	1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m1./s1
Inchi Key	ZFWPDJKMASHRPT-CITKKJEGSA-L

(R,R)-(-)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.

pictograms	GHS07,GHS08
signalword	Danger
hcodes	H317 - H372 - H412
pcodes	P260 - P264 - P273 - P280 - P302 + P352 - P314
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R,R)-()-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

Empirical Formula (Hill Notation):	C₃₆H₅₂ClMnN₂O₂
Linear Formula:	[[[(CH₃)₃C]₂C₆H₂-2-(O-)CH=N]₂C₆H₁₀]MnCl
CAS Number:	138124-32-0
Molecular Weight:	635.20
MDL number:	MFCD02101664
PubChem Substance ID:	24865246
NACRES:	NA.22

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsens catalyst has also been used in the asymmetric -hydroxylation of silyl enol ethers. Catalyst for the enantioselective epoxidation of a variety of olefins.

1, 5, 25 g in glass bottle

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

Quality Level	100,
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	330-332 °C (lit.)
greener alternative category	Aligned,
SMILES string	CC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Mn](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI	1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1
Inchi Key	LJVAWOSDJSQANR-OHRASPNLSA-K

(R,R)-(-)-N,N-Dimethyl-1,2-cyclohexanediamine is a N,N-dimethylated derivative of enantiopure 1,2-diaminocyclohexane. It can be formed during the hydrolysis of (R3a,R7a)-1,3-(dimethyl)-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide using HCl-methanol.

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

Узнать цену

Подробнее

(R,R)-()-N,N-Dimethyl-1,2-cyclohexanediamine 671274-1G

Empirical Formula (Hill Notation):	C₈H₁₈N₂
CAS Number:	68737-65-5
Molecular Weight:	142.24
MDL number:	MFCD00671527
PubChem Substance ID:	24885095
NACRES:	NA.22

General description

(R,R)-()-N,N-Dimethyl-1,2-cyclohexanediamine can be used:

As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.
In one of the key synthetic steps for the preparation of tricyclic -secretase modulators.
To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.

assay	97.0% (GC)
optical activity	[]/D -145±5°, c = 4.47 in chloroform
mp	39-44 °C
storage temp.	2-8°C
SMILES string	CN[C@@H]1CCCC[C@H]1NC
InChI	1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1
InChI key	JRHPOFJADXHYBR-HTQZYQBOSA-N

(R,R)-(+)-Hydrobenzoin is a chiral 1,2-diol useful as a chiral reagent, building block, ligand or auxiliary in asymmetric synthesis.

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H302 - H314
pcodes	P270 - P280 - P301 + P312 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2735PSN1 8 / PGII
WGK Germany	WGK 3
Flash Point F	165.2 °F - closed cup
Flash Point C	74 °C - closed cup

Узнать цену

Подробнее

(R,R)-(+)-Hydrobenzoin

Empirical Formula (Hill Notation):	C₁₄H₁₄O₂
Linear Formula:	C₆H₅CH(OH)CH(OH)C₆H₅
CAS Number:	52340-78-0
Molecular Weight:	214.26
Beilstein/REAXYS Number:	2050815
MDL number:	MFCD00064254
PubChem Substance ID:	24855514
NACRES:	NA.22

(R,R)-(+)-Hydrobenzoin may be used in the oxyselenenylation step in the multi-step synthesis of cyclopentitols and aminocyclopentitols from cyclopentene. It may also be used as a ligand for the asymmetric addition of diethylzinc to aldehydes in the presence or absence of titanium tetra-isopropoxide to form (R)- or (S)-form of the corresponding secondary alcohol, respectively.

5, 25 g in glass bottle

assay	99%
optical activity	[]28/D +93°, c = 2.5 in ethanol
optical purity	ee: 99% (HPLC)
mp	146-149 °C (lit.)
SMILES string	O[C@@H]([C@H](O)c1ccccc1)c2ccccc2
InChI	1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14-/m1/s1
InChI key	IHPDTPWNFBQHEB-ZIAGYGMSSA-N