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48

(R)-(+)-2-Amino-3-benzyloxy-1-propanol 473758-1G

Empirical Formula (Hill Notation):	C₁₀H₁₅NO₂
Linear Formula:	C₆H₅CH₂OCH₂CH(NH₂)CH₂OH
CAS Number:	58577-87-0
Molecular Weight:	181.23
MDL number:	MFCD00235943
PubChem Substance ID:	24870927
NACRES:	NA.22

Параметры

assay	97%
optical activity	[]20/D +4°, c = 1 in methylene chloride
bp	307 °C (lit.)
mp	34-37 °C (lit.)
SMILES string	N[C@H](CO)COCc1ccccc1
InChI	1S/C10H15NO2/c11-10(6-12)8-13-7-9-4-2-1-3-5-9/h1-5,10,12H,6-8,11H2/t10-/m1/s1
InChI key	ZJUOMDNENVWMPL-SNVBAGLBSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 + P310
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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(R)-(+)-2-Amino-3-methyl-1,1-diphenyl-1-butanol

Empirical Formula (Hill Notation):	C₁₇H₂₁NO
Linear Formula:	(CH₃)₂CHCH(NH₂)C(C₆H₅)₂OH
CAS Number:	86695-06-9
Molecular Weight:	255.35
MDL number:	MFCD01318247
PubChem Substance ID:	24879195

1, 5 g in glass bottle

Legal Information

A Product of Onyx Scientific, U.K.

Параметры

assay	95%
optical activity	[]20/D +132°, c = 1 in chloroform
mp	95-99 °C (lit.)
SMILES string	CC(C)[C@@H](N)C(O)(c1ccccc1)c2ccccc2
InChI	1S/C17H21NO/c1-13(2)16(18)17(19,14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-13,16,19H,18H2,1-2H3/t16-/m1/s1
Inchi Key	LNQVZZGGOZBOQS-MRXNPFEDSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315-H319-H335
pcodes	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	3

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(R)-(+)-2-Amino-3-phenyl-1-propanol

Empirical Formula (Hill Notation):	C₉H₁₃NO
Linear Formula:	C₆H₅CH₂CH(NH₂)CH₂OH
CAS Number:	5267-64-1
Molecular Weight:	151.21
Beilstein/REAXYS Number:	2208239
EC Number:	226-086-1
MDL number:	MFCD00064298
PubChem Substance ID:	24857160
NACRES:	NA.22

Quality Level	100,
assay	98%
optical activity	[]/D +22.8°, c = 1.2 in 1 M HCl
mp	93-95 °C (lit.)
SMILES string	N[C@@H](CO)Cc1ccccc1
InChI	1S/C9H13NO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-5,9,11H,6-7,10H2/t9-/m1/s1
InChI key	STVVMTBJNDTZBF-SECBINFHSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3259PSN1 8 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-2-Amino-4-methyl-1,1-diphenyl-1-pentanol

Empirical Formula (Hill Notation):	C₁₈H₂₃NO
Linear Formula:	(CH₃)₂CHCH₂CH(NH₂)C(C₆H₅)₂OH
CAS Number:	161832-74-2
Molecular Weight:	269.38
MDL number:	MFCD03093530
PubChem Substance ID:	24879412

Quality Level	100,
assay	98%
optical activity	[]20/D +100°, c = 1 in chloroform
optical purity	ee: 99% (HPLC)
mp	144-147 °C (lit.)
SMILES string	CC(C)C[C@@H](N)C(O)(c1ccccc1)c2ccccc2
InChI	1S/C18H23NO/c1-14(2)13-17(19)18(20,15-9-5-3-6-10-15)16-11-7-4-8-12-16/h3-12,14,17,20H,13,19H2,1-2H3/t17-/m1/s1
InChI key	XECSMDWXBMBRDE-QGZVFWFLSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P261 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	118.4 °F - closed cup
Flash Point C	48 °C - closed cup

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(R)-(+)-2-Aminomethyl-1-ethylpyrrolidine 681709-1G

Empirical Formula (Hill Notation):	C₇H₁₆N₂
CAS Number:	22795-97-7
Molecular Weight:	128.22
MDL number:	MFCD00671482
PubChem Substance ID:	329760760
NACRES:	NA.22

Параметры

Quality Level	100,
assay	90%
refractive index	n20/D 1.467
bp	50-52 °C/760 mmHg (lit.)
density	0.929 g/mL (lit.)
SMILES string	CCN1CCC[C@@H]1CN
InChI	1S/C7H16N2/c1-2-9-5-3-4-7(9)6-8/h7H,2-6,8H2,1H3/t7-/m1/s1
InChI key	UNRBEYYLYRXYCG-SSDOTTSWSA-N

Safety Information

pictograms	GHS02,GHS05,GHS07
signalword	Danger
hcodes	H226 - H302 - H315 - H318 - H335
pcodes	P210 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,
RIDADR	UN 1993C 3 / PGIII
WGK Germany	WGK 2
Flash Point F	135.0 °F - closed cup
Flash Point C	57.2 °C - closed cup

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(R)-(+)-2-Bromo--methylbenzyl alcohol

Empirical Formula (Hill Notation):	C₈H₉BrO
Linear Formula:	BrC₆H₄CH(CH₃)OH
CAS Number:	76116-20-6
Molecular Weight:	201.06
MDL number:	MFCD00216591
PubChem Substance ID:	24866890
NACRES:	NA.22

Quality Level	100,
assay	98%
optical activity	[]22/D +54°, c = 1 in chloroform
mp	54-56 °C (lit.)
SMILES string	C[C@@H](O)c1ccccc1Br
InChI	1S/C8H9BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-6,10H,1H3/t6-/m1/s1
Inchi Key	DZLZSFZSPIUINR-ZCFIWIBFSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-2-Bromo-3-methylbutyric acid

Empirical Formula (Hill Notation):	C₅H₉BrO₂
Linear Formula:	(CH₃)₂CHCH(Br)CO₂H
CAS Number:	76792-22-8
Molecular Weight:	181.03
MDL number:	MFCD00210113
PubChem Substance ID:	24870509
NACRES:	NA.22

(R)-(+)-2-Bromo-3-methylbutyric acid can be used:

As an anionic counterpart of morpholinium based chiral ionic liquids applicable in the Heck arylation reaction of 2,3-dihydrofuran.
As a starting material in the synthesis of fructosyl peptide oxidase inhibitors.

Packaging

5 g in glass bottle

Параметры

assay	96%
optical activity	[]22/D +21°, c = 37 in benzene
bp	90-100 °C/0.5 mmHg (lit.)
mp	35-40 °C (lit.)
SMILES string	CC(C)[C@@H](Br)C(O)=O
InChI	1S/C5H9BrO2/c1-3(2)4(6)5(7)8/h3-4H,1-2H3,(H,7,8)/t4-/m1/s1
Inchi Key	UEBARDWJXBGYEJ-SCSAIBSYSA-N

Safety Information

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H302 - H312 - H314 - H332
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3261 8 / PGII
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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(R)-(+)-2-Bromopropionic acid

Empirical Formula (Hill Notation):	C₃H₅BrO₂
CAS Number:	10009-70-8
Molecular Weight:	152.97
Beilstein/REAXYS Number:	1720262
MDL number:	MFCD00145205
PubChem Substance ID:	57647718
NACRES:	NA.22

10 mL in glass bottle

Caution

may discolor to brownish on storage

Параметры

Quality Level	100,
assay	98.0% (sum of enantiomers, GC)
optical activity	[]20/D +26±2°, neat
refractive index	n20/D 1.475
density	1.692 g/mL at 20 °C (lit.)
storage temp.	2-8°C
SMILES string	C[C@@H](Br)C(O)=O
InChI	1S/C3H5BrO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m1/s1
InChI key	MONMFXREYOKQTI-UWTATZPHSA-N

Safety Information

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H302 - H314
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3265 8 / PGIII
WGK Germany	WGK 3
Flash Point F	212.0 °F - closed cup
Flash Point C	100 °C - closed cup

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(R)-(+)-2-Chloropropionic acid 306800-1G

Empirical Formula (Hill Notation):	C₃H₅ClO₂
Linear Formula:	CH₃CH(Cl)CO₂H
CAS Number:	7474-05-7
Molecular Weight:	108.52
Beilstein/REAXYS Number:	1720258
MDL number:	MFCD00064204
PubChem Substance ID:	24858501
NACRES:	NA.22

Application

(R)-(+)-2-Chloropropionic acid can be used as a starting material in the synthesis of:

Thiolactic acid, a key intermediate, which is used for the preparation of 2(R),5(S)-oxathiolanones by reacting with pivalaldehyde.
(R)-2-chloropropionyl chloride, a key intermediate, which is utilized in the synthesis of (R)-4,5-dihydro-5-methylpyridazin-3(2H)-one derivative with pyrazolopyridine ring as a potential phosphodiesterase inhibitor.
2-Chloropropionamide derivatives as protein disulfide isomerase (PID) inhibitors.

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	99%
optical activity	[]20/D +14°, neat
refractive index	n20/D 1.4345 (lit.)
bp	185-188 °C (lit.)
density	1.258 g/mL at 20 °C (lit.)
SMILES string	C[C@@H](Cl)C(O)=O
InChI	1S/C3H5ClO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m1/s1
InChI key	GAWAYYRQGQZKCR-UWTATZPHSA-N

Safety Information

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H302 - H314
pcodes	P280 - P305 + P351 + P338 - P310
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2511 8 / PGIII
WGK Germany	WGK 3
Flash Point F	213.8 °F - closed cup
Flash Point C	101 °C - closed cup

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(R)-(+)-2-Hydroxy-4-(2-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaphosphorinane 2-oxide

Empirical Formula (Hill Notation):	C₁₂H₁₇O₅P
CAS Number:	98674-82-9
Molecular Weight:	272.23
MDL number:	MFCD00190172
PubChem Substance ID:	24870171

Quality Level	100,
assay	97%
optical activity	[]23/D +58°, c = 1 in methanol
mp	197-200 °C (lit.)
storage temp.	2-8°C
SMILES string	COc1ccccc1[C@@H]2OP(O)(=O)OCC2(C)C
InChI	1S/C12H17O5P/c1-12(2)8-16-18(13,14)17-11(12)9-6-4-5-7-10(9)15-3/h4-7,11H,8H2,1-3H3,(H,13,14)/t11-/m0/s1
InChI key	HNFXKRNIAWHFJN-NSHDSACASA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-2-Methyl-CBS-oxazaborolidine

Empirical Formula (Hill Notation):	C₁₈H₂₀BNO
CAS Number:	112022-83-0
Molecular Weight:	277.17
MDL number:	MFCD00078440
PubChem Substance ID:	24883644
NACRES:	NA.22

The CBS (Corey-Bakshi-Shibata) oxazaborolidine catalyst has been used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of -hydroxy acids, -amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols.
CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis,

Packaging

1, 10 g in glass bottle

Параметры

Quality Level	100,
assay	90%
mp	85-95 °C (lit.)
SMILES string	CB1OC(C2CCCN12)(c3ccccc3)c4ccccc4
InChI	1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m1/s1
Inchi Key	VMKAFJQFKBASMU-QGZVFWFLSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-2-Methyl-CBS-oxazaborolidine solution

Empirical Formula (Hill Notation):	C₁₈H₂₀BNO
CAS Number:	112022-83-0
Molecular Weight:	277.17
MDL number:	MFCD00078440
PubChem Substance ID:	24869385
NACRES:	NA.22

(R)-(+)-2-Methyl-CBS-oxazaborolidine solution [1M in toluene] may be used as a catalyst in the asymmetric borane reduction of perfluoroalkyl ketones.
It may also be used in the preparation of:

(-)-diospongin B
(1R)-2-azido-1-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)ethanol
(S)--deuteriobenzyl alcohol
(3S,4R,5S)-1-(trimethylsilyl)-4,5-epoxyhex-1-yn-3-ol

Excellent catalyst of asymmetric reductions.
The CBS (Corey-Bakshi-Shibata) oxazaborolidine catalyst has been used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of -hydroxy acids, -amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols.
Used in a desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone.
CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis,

Packaging

5 mL in glass bottle
25 mL in Sure/Seal™

Physical form

Precipitate may form in storage, but does not affect product quality. Gently heat product to 80−90 °C under an inert atmosphere to redissolve solids.

Параметры

Quality Level	200,
concentration	1 M in toluene
bp	111 °C
density	0.95 g/mL at 25 °C
storage temp.	room temp
SMILES string	[H][C@]12CCCN1B(C)OC2(c3ccccc3)c4ccccc4
InChI	1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m1/s1
Inchi Key	VMKAFJQFKBASMU-QGZVFWFLSA-N

Safety Information

pictograms	GHS02,GHS07,GHS08
signalword	Danger
hcodes	H225 - H304 - H315 - H336 - H361d - H373 - H412
pcodes	P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313
Target Organs	Central nervous system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN1294 - class 3 - PG 2 - Toluene, solution
WGK Germany	WGK 3
Flash Point F	39.2 °F - closed cup
Flash Point C	4 °C - closed cup

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(R)-(+)-2-Phenyl-1-propanol 461407-1G

Empirical Formula (Hill Notation):	C₉H₁₂O
Linear Formula:	CH₃CH(C₆H₅)CH₂OH
CAS Number:	19141-40-3
Molecular Weight:	136.19
Beilstein/REAXYS Number:	2637521
MDL number:	MFCD00145206
PubChem Substance ID:	24869852
NACRES:	NA.22

Параметры

Quality Level	200,
assay	98%
optical activity	[]22/D +17°, neat
refractive index	n20/D 1.526 (lit.)
bp	220 °C (lit.)
density	1 g/mL at 25 °C (lit.)
SMILES string	C[C@@H](CO)c1ccccc1
InChI	1S/C9H12O/c1-8(7-10)9-5-3-2-4-6-9/h2-6,8,10H,7H2,1H3/t8-/m0/s1
InChI key	RNDNSYIPLPAXAZ-QMMMGPOBSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, multi-purpose combination respirator cartridge (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	226.4 °F - closed cup
Flash Point C	108 °C - closed cup

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(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline

Empirical Formula (Hill Notation):	C₂₄H₂₄NOP
CAS Number:	164858-78-0
Molecular Weight:	373.43
Beilstein/REAXYS Number:	8156604
MDL number:	MFCD02684553
PubChem Substance ID:	57652428
NACRES:	NA.22

100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Asymmetric alkylation with an iridium catalyst; Chiral ligand for asymmetric reduction reaction

Параметры

assay	97.0% (CHN)
optical activity	[]20/D +48±3°, c = 1.4% in chloroform
mp	85-90 °C
SMILES string	CC(C)[C@@H]1COC(=N1)c2ccccc2P(c3ccccc3)c4ccccc4
InChI	1S/C24H24NOP/c1-18(2)22-17-26-24(25-22)21-15-9-10-16-23(21)27(19-11-5-3-6-12-19)20-13-7-4-8-14-20/h3-16,18,22H,17H2,1-2H3/t22-/m0/s1
InChI key	OUQSAXROROGQEE-QFIPXVFZSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-3,3,3-Trifluoro-1,2-epoxypropane

Empirical Formula (Hill Notation):	C₃H₃F₃O
CAS Number:	143142-90-9
Molecular Weight:	112.05
MDL number:	MFCD08276876
PubChem Substance ID:	24884878
NACRES:	NA.22

(R)-(+)-3,3,3-Trifluoro-1,2-epoxypropane can be used as a substrate to synthesize:

Substituted trifluoro amino propanols, which are found to be potent inhibitors of cholesteryl ester transfer protein.
(2R) Trifluoro-(methoxybenzyloxy)-propanol (chiral glycol) by reacting with 4-methoxybenzyl alcohol in the presence of NaH. Chiral glycol intermediate is further utilized for the preparation of trifluoromethyl glycol carbamates as potential monoacylglycerol lipase (MAGL) inhibitors.

Packaging

1 g in glass bottle
250 mg in glass bottle

Параметры

Quality Level	100,
assay	97%
refractive index	n20/D <1.300
bp	25-32 °C
density	1.294 g/mL at 25 °C
storage temp.	2-8°C
SMILES string	FC(F)(F)[C@H]1CO1
InChI	1S/C3H3F3O/c4-3(5,6)2-1-7-2/h2H,1H2/t2-/m1/s1
Inchi Key	AQZRARFZZMGLHL-UWTATZPHSA-N

Safety Information

pictograms	GHS02
signalword	Danger
hcodes	H224
pcodes	P210 - P403 + P233
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,
RIDADR	UN 1993A 3 / PGI
WGK Germany	WGK 3
Flash Point F	-14.8 °F
Flash Point C	-26 °C

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(R)-(+)-3,3-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1-bi-2-naphthol 674591-100MG

Empirical Formula (Hill Notation):	C₃₆H₁₈F₁₂O₂
CAS Number:	756491-54-0
Molecular Weight:	710.51
MDL number:	MFCD08689862
PubChem Substance ID:	24885224
NACRES:	NA.22

Packaging

100 mg in clear glass bottle

Application

Precursor to a chiral Bronsted acid (680184) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines.

Параметры

Quality Level	100,
assay	95%
optical activity	[]22/D 45°, c = 1 in chloroform
mp	216-220 °C
InChI	1S/C36H18F12O2/c37-33(38,39)21-9-19(10-22(15-21)34(40,41)42)27-13-17-5-1-3-7-25(17)29(31(27)49)30-26-8-4-2-6-18(26)14-28(32(30)50)20-11-23(35(43,44)45)16-24(12-20)36(46,47)48/h1-16,49-50H
Inchi Key	PGXMYJSTCAQJBY-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3

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(R)-(+)-3,3-Dibromo-1,1-bi-2-naphthol

Empirical Formula (Hill Notation):	C₂₀H₁₂Br₂O₂
CAS Number:	111795-43-8
Molecular Weight:	444.12
MDL number:	MFCD03093629
PubChem Substance ID:	24881599
NACRES:	NA.22

(R)-(+)-3,3-Dibromo-1,1-bi-2-naphthol reacts with zirconium(IV) tert-butoxide to form a chiral zirconium complex, which can efficiently catalyze:

anti-selective catalytic asymmetric aldol reactions of silyl enol ethers with aldehydes
asymmetric intramolecular [3+2] cycloaddition of hydrazone/olefins

Packaging

250 mg in glass insert
1 g in glass bottle

Параметры

Quality Level	100,
assay	97%
mp	256-260 °C
InChI	1S/C20H12Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h1-10,23-24H
Inchi Key	BRTBEAXHUYEXSY-UHFFFAOYSA-N

Safety Information

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273 - P501
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-3,3-Dibromo-5,5,6,6,7,7,8,8-octahydro-1,1-bi-2,2-naphthalenediol

Empirical Formula (Hill Notation):	C₂₀H₂₀Br₂O₂
CAS Number:	65355-08-0
Molecular Weight:	452.18
MDL number:	MFCD03093977
PubChem Substance ID:	24878481
NACRES:	NA.22

Quality Level	100,
assay	97%
optical activity	[]20/D +53°, c = 1 in THF
optical purity	ee: 99% (HPLC)
mp	146-149 °C (lit.)
SMILES string	Oc1c(Br)cc2CCCCc2c1-c3c(O)c(Br)cc4CCCCc34
InChI	1S/C20H20Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h9-10,23-24H,1-8H2
InChI key	WDRTXCNGVVLRSZ-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-3-(Dimethylamino)pyrrolidine 656712-1G

Empirical Formula (Hill Notation):	C₆H₁₄N₂
CAS Number:	132958-72-6
Molecular Weight:	114.19
MDL number:	MFCD00191347
PubChem Substance ID:	24884220
NACRES:	NA.22

Параметры

Quality Level	100,
assay	95%
optical activity	[]20/D +14°, c = 1 in ethanol
refractive index	n20/D 1.4650 (lit.)
bp	166 °C/760 mmHg (lit.)
density	0.899 g/mL at 25 °C (lit.)
SMILES string	CN(C)[C@@H]1CCNC1
InChI	1S/C6H14N2/c1-8(2)6-3-4-7-5-6/h6-7H,3-5H2,1-2H3/t6-/m1/s1
Inchi Key	AVAWMINJNRAQFS-ZCFIWIBFSA-N

Safety Information

pictograms	GHS02,GHS05,GHS07
signalword	Danger
hcodes	H226 - H302 - H315 - H318 - H335
pcodes	P210 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1993C 3 / PGIII
WGK Germany	WGK 2
Flash Point F	125.1 °F
Flash Point C	51.7 °C

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(R)-(+)-3-Aminopyrrolidine 540781-1G

Empirical Formula (Hill Notation):	C₄H₁₀N₂
CAS Number:	116183-82-5
Molecular Weight:	86.14
MDL number:	MFCD00143190
PubChem Substance ID:	24878496
NACRES:	NA.22

Параметры

Quality Level	100,
assay	98%
optical activity	[]/D +20°, neat
refractive index	n20/D 1.489 (lit.)
bp	164-165 °C (lit.)
density	0.984 g/mL at 25 °C (lit.)
SMILES string	N[C@@H]1CCNC1
InChI	1S/C4H10N2/c5-4-1-2-6-3-4/h4,6H,1-3,5H2/t4-/m1/s1
Inchi Key	NGXSWUFDCSEIOO-SCSAIBSYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Personal Protective Equipment	Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	NA 1993 / PGIII
WGK Germany	WGK 3
Flash Point F	147.2 °F
Flash Point C	64 °C

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(R)-(+)-3-Aminoquinuclidine dihydrochloride

Empirical Formula (Hill Notation):	C₇H₁₄N₂ · 2HCl
CAS Number:	123536-14-1
Molecular Weight:	199.12
MDL number:	MFCD00191752
PubChem Substance ID:	24866027
NACRES:	NA.22

This diamine and its antipode are important building blocks in the synthesis of pharmaceuticals.

Packaging

1 g in glass bottle

Параметры

Quality Level	200,
assay	98%
optical activity	[]20/D +24°, c = 1 in H₂O
mp	>300 °C (lit.)
SMILES string	Cl.Cl.N[C@H]1CN2CC[C@H]1CC2
InChI	1S/C7H14N2.2ClH/c8-7-5-9-3-1-6(7)2-4-9;;/h6-7H,1-5,8H2;2*1H/t7-;;/m0../s1
InChI key	STZHBULOYDCZET-KLXURFKVSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-3-Benzyloxy-2-(Boc-amino)-1-propanol 473766-5G

Empirical Formula (Hill Notation):	C₁₅H₂₃NO₄
Linear Formula:	C₆H₅CH₂OCH₂CH[NHCO₂C(CH₃)₃]CH₂OH
CAS Number:	127559-33-5
Molecular Weight:	281.35
MDL number:	MFCD00235944
PubChem Substance ID:	24870928
NACRES:	NA.22

Параметры

assay	98%
optical activity	[]20/D +14°, c = 1 in chloroform
mp	66-69 °C (lit.)
SMILES string	CC(C)(C)OC(=O)N[C@H](CO)COCc1ccccc1
InChI	1S/C15H23NO4/c1-15(2,3)20-14(18)16-13(9-17)11-19-10-12-7-5-4-6-8-12/h4-8,13,17H,9-11H2,1-3H3,(H,16,18)/t13-/m1/s1
InChI key	MSIDLARYVJJEQY-CYBMUJFWSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-3-Butyn-2-ol

Empirical Formula (Hill Notation):	C₄H₆O
Linear Formula:	HC≡CCH(OH)CH₃
CAS Number:	42969-65-3
Molecular Weight:	70.09
MDL number:	MFCD00211237
PubChem Substance ID:	24870225
NACRES:	NA.22

(R)-(+)-3-Butyn-2-ol may be used as a starting material in the multi-step synthesis of (R)-benzyl 4-hydroxyl-2-pentynoate.
Propargylic alcohols are important starting materials for new classes of second generation 5-lipoxygenase inhibitors.
Used in a ruthenium-catalyzed polymerization providing helical polyacetylenes.

Packaging

1, 5 g in glass bottle

Параметры

Quality Level	100,
assay	98%
optical activity	[]22/D +45°, neat
refractive index	n20/D 1.426 (lit.)
bp	108-111 °C (lit.)
density	0.89 g/mL at 25 °C (lit.)
SMILES string	C[C@@H](O)C#C
InChI	1S/C4H6O/c1-3-4(2)5/h1,4-5H,2H3/t4-/m1/s1
InChI key	GKPOMITUDGXOSB-SCSAIBSYSA-N

Safety Information

pictograms	GHS02,GHS05,GHS06,GHS08
signalword	Danger
hcodes	H226 - H300 + H330 - H315 - H317 - H318 - H335 - H351
pcodes	P201 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2929 3(6.1) / PGII
WGK Germany	WGK 3
Flash Point F	78.8 °F - closed cup
Flash Point C	26 °C - closed cup

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(R)-(+)-3-Chlorostyrene oxide 563382-1G

Empirical Formula (Hill Notation):	C₈H₇ClO
CAS Number:	62600-71-9
Molecular Weight:	154.59
MDL number:	MFCD00673317
PubChem Substance ID:	24880095
NACRES:	NA.22

Application

(R)-(+)-3-Chlorostyrene oxide may be used as an intermediate for the synthesis of 4-aminopiperidine based human 3-adrenergic receptor (AR) agonists.
Reactant involved in:

Diastereoselective Wadsworth-Emmons cyclopropanation for synthesis of quaternaty cyclopropyl esters
Synthesis of phenylethanolamine derivatives as 3-adrenergic receptor agonists
Stereoselective ring-opening for synthesis of -aryloxy-substituted alcohols and amines
Synthesis of Biphenyl benzoic acid derivatives as 3-adrenergic receptor agonists
Synthesis of (S)-2-, 3-, and 4-chlorostyrene oxides with epoxide hydrolase

Packaging

1 g in glass bottle

Параметры

optical activity	[]20/D +19°, neat
Quality Level	100,
refractive index	n20/D 1.551 (lit.)
bp	67-68 °C/1 mmHg (lit.)
density	1.214 g/mL at 25 °C (lit.)
SMILES string	Clc1cccc(c1)[C@@H]2CO2
InChI	1S/C8H7ClO/c9-7-3-1-2-6(4-7)8-5-10-8/h1-4,8H,5H2/t8-/m0/s1
Inchi Key	YVMKRPGFBQGEBF-QMMMGPOBSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H317 - H319 - H335
pcodes	P280 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	206.6 °F - closed cup
Flash Point C	97 °C - closed cup

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(R)-(+)-3-Hydroxypiperidine hydrochloride

Empirical Formula (Hill Notation):	C₅H₁₁NO · HCl
CAS Number:	198976-43-1
Molecular Weight:	137.61
MDL number:	MFCD00192221
PubChem Substance ID:	24865527
NACRES:	NA.22

1, 5 g in glass bottle

Application

Starter for (R)-(+)-3-pyrrolidyl benzilates with pharmaceutical applications.

Параметры

Quality Level	100,
assay	98%
optical activity	[]20/D +8.6°, c = 2 in methanol
mp	195-196 °C (lit.)
SMILES string	Cl.O[C@@H]1CCCNC1
InChI	1S/C5H11NO.ClH/c7-5-2-1-3-6-4-5;/h5-7H,1-4H2;1H/t5-;/m1./s1
Inchi Key	VLECDMDGMKPUSK-NUBCRITNSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-3-Methylcyclohexanone

Empirical Formula (Hill Notation):	C₇H₁₂O
Linear Formula:	CH₃C₆H₉(=O)
CAS Number:	13368-65-5
Molecular Weight:	112.17
EC Number:	236-438-6
MDL number:	MFCD00062999
PubChem Substance ID:	24896880
NACRES:	NA.22

(R)-(+)-3-Methylcyclohexanone may be used in the preparation of (R)-5-methyl-2-(1-methylethylidene-d6)-cyclohexanone [(R)-(+)-pulegone-d6].

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
assay	98%
optical activity	[]24/D +13.5°, neat
optical purity	ee: 99% (GLC)
refractive index	n20/D 1.446 (lit.)
bp	168-169 °C (lit.)
density	0.916 g/mL at 25 °C (lit.)
SMILES string	C[C@@H]1CCCC(=O)C1
InChI	1S/C7H12O/c1-6-3-2-4-7(8)5-6/h6H,2-5H2,1H3/t6-/m1/s1
Inchi Key	UJBOOUHRTQVGRU-ZCFIWIBFSA-N

Safety Information

pictograms	GHS02
signalword	Warning
hcodes	H226
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2297 3 / PGIII
WGK Germany	WGK 1
Flash Point F	125.6 °F - closed cup
Flash Point C	52 °C - closed cup

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(R)-(+)-3-Methylcyclopentanone

Empirical Formula (Hill Notation):	C₆H₁₀O
Linear Formula:	CH₃C₅H₇(=O)
CAS Number:	6672-30-6
Molecular Weight:	98.14
EC Number:	229-711-6
MDL number:	MFCD00064147
PubChem Substance ID:	24896891
NACRES:	NA.22

assay	99%
optical activity	[]23/D +148°, c = 4.5 in methanol
refractive index	n20/D 1.434 (lit.)
bp	143-144 °C (lit.)
density	0.914 g/mL at 25 °C (lit.)
SMILES string	C[C@@H]1CCC(=O)C1
InChI	1S/C6H10O/c1-5-2-3-6(7)4-5/h5H,2-4H2,1H3/t5-/m1/s1
Inchi Key	AOKRXIIIYJGNNU-RXMQYKEDSA-N

Safety Information

pictograms	GHS02
signalword	Warning
hcodes	H226
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN1224 - class 3 - PG 3 - Ketones, liquid, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	98.6 °F - closed cup
Flash Point C	37 °C - closed cup

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(R)-(+)-4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane

Empirical Formula (Hill Notation):	C₆H₁₁ClO₂
CAS Number:	57044-24-3
Molecular Weight:	150.60
MDL number:	MFCD00273371
PubChem Substance ID:	24869114
NACRES:	NA.22

Utilized in the preparation of both enantiomers of the orally active antifungal azolic agent ketoconazole.

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
assay	98%
optical activity	[]24/D +42.1°, neat
refractive index	n20/D 1.434 (lit.)
bp	63 °C/37 mmHg (lit.)
density	1.103 g/mL at 25 °C (lit.)
SMILES string	CC1(C)OC[C@H](CCl)O1
InChI	1S/C6H11ClO2/c1-6(2)8-4-5(3-7)9-6/h5H,3-4H2,1-2H3/t5-/m0/s1
Inchi Key	BNPOTXLWPZOESZ-YFKPBYRVSA-N

Safety Information

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H226 - H318
pcodes	P280 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 1993C 3 / PGIII
WGK Germany	WGK 3
Flash Point F	123.8 °F - closed cup
Flash Point C	51 °C - closed cup

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(R)-(+)-4-(Hydroxymethyl)-2-oxazolidinone benzoate 515558-1G

Empirical Formula (Hill Notation):	C₁₁H₁₁NO₄
CAS Number:	136015-44-6
Molecular Weight:	221.21
MDL number:	MFCD06799018
PubChem Substance ID:	24873830
NACRES:	NA.22

Параметры

Quality Level	100,
assay	97%
optical activity	[]20/D +30°, c = 1 in chloroform
mp	114-117 °C (lit.)
SMILES string	O=C1N[C@@H](CO1)COC(=O)c2ccccc2
InChI	1S/C11H11NO4/c13-10(8-4-2-1-3-5-8)15-6-9-7-16-11(14)12-9/h1-5,9H,6-7H2,(H,12,14)/t9-/m1/s1
Inchi Key	AOOQUJMFWHMHRA-SECBINFHSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-4-Chloro-3-hydroxybutyronitrile

Empirical Formula (Hill Notation):	C₄H₆ClNO
Linear Formula:	ClCH₂CH(OH)CH₂CN
CAS Number:	84367-31-7
Molecular Weight:	119.55
Beilstein/REAXYS Number:	1700586
MDL number:	MFCD00273362
PubChem Substance ID:	24869131
NACRES:	NA.22

(-)-Carnitine and (-)-γ-amino-β-hydroxybutyric acid have been prepared using this synthon.

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	97%
optical activity	[]25/D +11.0°, neat
refractive index	n20/D 1.474 (lit.)
bp	110 °C/1 mmHg (lit.)
density	1.250 g/mL at 20 °C (lit.)
SMILES string	O[C@@H](CCl)CC#N
InChI	1S/C4H6ClNO/c5-3-4(7)1-2-6/h4,7H,1,3H2/t4-/m1/s1
Inchi Key	LHBPNZDUNCZWFL-SCSAIBSYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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(R)-(+)-4-Chloromandelonitrile

Empirical Formula (Hill Notation):	C₈H₆ClNO
Linear Formula:	ClC₆H₄CH(OH)CN
CAS Number:	97070-79-6
Molecular Weight:	167.59
MDL number:	MFCD01321260
PubChem Substance ID:	24870480
NACRES:	NA.22

Useful intermediate in the preparation of optically active α-hydroxy carboxylic acids, α-hydroxy aldehydes, α-hydroxy ketones, and 2-amino alcohols.

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
assay	97%
optical activity	[]20/D +39°, c = 1 in chloroform
mp	70-74 °C (lit.)
storage temp.	2-8°C
SMILES string	O[C@@H](C#N)c1ccc(Cl)cc1
InChI	1S/C8H6ClNO/c9-7-3-1-6(2-4-7)8(11)5-10/h1-4,8,11H/t8-/m0/s1
InChI key	LSDSHEPNJSMUTI-QMMMGPOBSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-4-Hydroxy-2-pyrrolidinone

Empirical Formula (Hill Notation):	C₄H₇NO₂
CAS Number:	22677-21-0
Molecular Weight:	101.10
Beilstein/REAXYS Number:	1524193
MDL number:	MFCD00273364
PubChem Substance ID:	24871603
NACRES:	NA.22

Quality Level	100,
assay	97%
optical activity	[]23/D +43°, c = 1 in ethanol
mp	156-159 °C (lit.)
SMILES string	O[C@H]1CNC(=O)C1
InChI	1S/C4H7NO2/c6-3-1-4(7)5-2-3/h3,6H,1-2H2,(H,5,7)/t3-/m1/s1
Inchi Key	IOGISYQVOGVIEU-GSVOUGTGSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-4-Methoxy--methylbenzylamine

Empirical Formula (Hill Notation):	C₉H₁₃NO
CAS Number:	22038-86-4
Molecular Weight:	151.21
Beilstein/REAXYS Number:	2413029
MDL number:	MFCD00671659
PubChem Substance ID:	329764270
NACRES:	NA.22

(R)-(+)-4-Methoxy--methylbenzylamine can be used as a reactant to prepare:

Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N-methylthiourea by reacting with methyl isothiocyanate.

Packaging

25, 100 g in glass bottle

Legal Information

ChiPros is a registered trademark of BASF SE

Параметры

Quality Level	100,
grade	produced by BASF
assay	98.5% (GC), 99%
optical purity	enantiomeric excess: 98.5%
density	1.024 g/mL at 20 °C (lit.)
SMILES string	COc1ccc(cc1)[C@@H](C)N
InChI	1S/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/m1/s1
Inchi Key	JTDGKQNNPKXKII-SSDOTTSWSA-N

Safety Information

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H302 - H314 - H317 - H412
pcodes	P261 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
RIDADR	UN 2735PSN1 8 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-4-Methoxymandelonitrile

Empirical Formula (Hill Notation):	C₉H₉NO₂
Linear Formula:	CH₃OC₆H₄CH(OH)CN
CAS Number:	97070-73-0
Molecular Weight:	163.17
MDL number:	MFCD01321258
PubChem Substance ID:	24870477
NACRES:	NA.22

Useful intermediate in the preparation of optically active α-hydroxy carboxylic acids, α-hydroxy aldehydes, α-hydroxy ketones, and 2-amino alcohols.

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	98%
optical activity	[]20/D +47.5°, c = 1 in chloroform
mp	84-87 °C (lit.)
storage temp.	2-8°C
SMILES string	COc1ccc(cc1)[C@@H](O)C#N
InChI	1S/C9H9NO2/c1-12-8-4-2-7(3-5-8)9(11)6-10/h2-5,9,11H,1H3/t9-/m0/s1
InChI key	WLDAAMXETLHTER-VIFPVBQESA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-4-Methylmandelonitrile

Empirical Formula (Hill Notation):	C₉H₉NO
Linear Formula:	CH₃C₆H₄CH(OH)CN
CAS Number:	10017-04-6
Molecular Weight:	147.17
MDL number:	MFCD01321259
PubChem Substance ID:	24870479
NACRES:	NA.22

Useful intermediate in the preparation of optically active α-hydroxy carboxylic acids, α-hydroxy aldehydes, α-hydroxy ketones, and 2-amino alcohols.

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	97%
optical activity	[]18/D +39°, c = 1 in chloroform
mp	52-58 °C (lit.)
storage temp.	2-8°C
SMILES string	Cc1ccc(cc1)[C@@H](O)C#N
InChI	1S/C9H9NO/c1-7-2-4-8(5-3-7)9(11)6-10/h2-5,9,11H,1H3/t9-/m0/s1
Inchi Key	KKGXJLAWLSJRGK-VIFPVBQESA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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(R)-(+)-4-tert-Butyl-2-oxazolidinone 493767-500MG

Empirical Formula (Hill Notation):	C₇H₁₃NO₂
CAS Number:	142618-93-7
Molecular Weight:	143.18
MDL number:	MFCD00673334
PubChem Substance ID:	24872857
NACRES:	NA.22

Packaging

500 mg in amber glass bottle

Application

Versatile chiral auxiliary for asymmetric synthesis.

Параметры

Quality Level	100,
assay	99%
optical activity	[]23/D +17°, c = 6 in ethanol
mp	119-122 °C (lit.)
SMILES string	CC(C)(C)[C@@H]1COC(=O)N1
InChI	1S/C7H13NO2/c1-7(2,3)5-4-10-6(9)8-5/h5H,4H2,1-3H3,(H,8,9)/t5-/m0/s1
Inchi Key	WKUHGFGTMLOSKM-YFKPBYRVSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-5,5,6,6,7,7,8,8-Octahydro-1,1-2-naphthol

Empirical Formula (Hill Notation):	C₂₀H₂₂O₂
Linear Formula:	(C₁₀H₁₀OH)₂
CAS Number:	65355-14-8
Molecular Weight:	294.39
MDL number:	MFCD02093485
PubChem Substance ID:	24880524
NACRES:	NA.22

(R)-(+)-5,5,6,6,7,7,8,8-octahydro-1,1-2-naphthol can be used:

As a starting material for the preparation of octahydro-binaphthyl based organic light-emitting diodes.
As a ligand in the 1,4-hydrophosphinylation of methyl cyclohexene-1-carboxylate using diphenylphosphine oxide, applicable in the synthesis of CyPHOX ligands.

Packaging

1, 5 g in glass bottle

Параметры

Quality Level	100,
assay	95%
optical activity	[]20/D +73°, c = 1 in THF
mp	160-166 °C (lit.)
InChI	1S/C20H22O2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h9-12,21-22H,1-8H2
Inchi Key	UTXIFKBYNJRJPH-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-5,5-Dichloro-2,2-bis(diphenylphosphino)-6,6-dimethoxy-1,1-biphenyl

Empirical Formula (Hill Notation):	C₃₈H₃₀Cl₂O₂P₂
CAS Number:	185913-97-7
Molecular Weight:	651.50
MDL number:	MFCD03426987
PubChem Substance ID:	57653779
NACRES:	NA.22

250 mg in glass bottle

Other Notes

Transition metal complexes are used as catalysts for asymmetric hydrogenation; Eur Pat Appl 749973, 1995 (20.06.1995); Eur Pat Appl 1160237 (18.05.2001).

Legal Information

produced by Bayer

Параметры

Quality Level	100,
assay	95.0% (H-NMR)
optical activity	[]/D +59±4°, c = 1% in chloroform
InChI	1S/C38H30Cl2O2P2/c1-41-37-31(39)23-25-33(43(27-15-7-3-8-16-27)28-17-9-4-10-18-28)35(37)36-34(26-24-32(40)38(36)42-2)44(29-19-11-5-12-20-29)30-21-13-6-14-22-30/h3-26H,1-2H3
Inchi Key	GCBRCSSVOVNEIX-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-6-Hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid

Empirical Formula (Hill Notation):	C₁₄H₁₈O₄
CAS Number:	53101-49-8
Molecular Weight:	250.29
MDL number:	MFCD00180755
PubChem Substance ID:	24864410
NACRES:	NA.22

(R)-(+)-6-Hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid, a vitamin E analog, is a mushroom tyrosinase inhibitor.

Application

(R)-(+)-6-Hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid may be used to incorporate antioxidant property while designing anti-stress agents based on -aminobutyric acid (GABA).

Packaging

1, 5 g in glass bottle

Параметры

Quality Level	100,
assay	98%
optical activity	[]27/D +65°, c = 1.2 in ethanol
mp	162 °C (dec.) (lit.)
SMILES string	Cc1c(C)c2O[C@](C)(CCc2c(C)c1O)C(O)=O
InChI	1S/C14H18O4/c1-7-8(2)12-10(9(3)11(7)15)5-6-14(4,18-12)13(16)17/h15H,5-6H2,1-4H3,(H,16,17)/t14-/m1/s1
InChI key	GLEVLJDDWXEYCO-CQSZACIVSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Aminoglutethimide 545872-500MG

Empirical Formula (Hill Notation):	C₁₃H₁₆N₂O₂
CAS Number:	55511-44-9
Molecular Weight:	232.28
PubChem Substance ID:	24878857
NACRES:	NA.22

Application

(R)-(+)-Aminoglutethimide can be used:

As a building block for the development of cephalosporin based prodrug for antibody-directed enzyme prodrug therapy (ADEPT).
To prepare (R)-3-ethyl-3-(4-(3,4,5-trimethoxybenzylamino)phenyl)piperidine-2,6-dione by reacting with 3,4,5-trimethoxybenzylamine via deaminative coupling reaction.
To synthesize (R)-2-fluoro-2-(4-methoxyphenyl)-N-(R)-(+)-aminoglutethimide by enantioselective -fluorination.

Packaging

500 mg in amber glass bottle

Параметры

Quality Level	100,
assay	97%
optical activity	[]20/D +160°, c = 1 in methanol
mp	115.5-119.5 °C (lit.)
SMILES string	CC[C@@]1(CCC(=O)NC1=O)c2ccc(N)cc2
InChI	1S/C13H16N2O2/c1-2-13(8-7-11(16)15-12(13)17)9-3-5-10(14)6-4-9/h3-6H,2,7-8,14H2,1H3,(H,15,16,17)/t13-/m1/s1
Inchi Key	ROBVIMPUHSLWNV-CYBMUJFWSA-N
Gene Information	human ... CYP17A1(1586), CYP19A1(1588)

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Atenolol

Empirical Formula (Hill Notation):	C₁₄H₂₂N₂O₃
Linear Formula:	(CH₃)₂CHNHCH₂CH(OH)CH₂OC₆H₄CH₂CONH₂
CAS Number:	56715-13-0
Molecular Weight:	266.34
MDL number:	MFCD00074917
PubChem Substance ID:	24859921
NACRES:	NA.22

Quality Level	100,
assay	99%
optical activity	[]25/D +16°, c = 1 in 1 M HCl
mp	148-152 °C (lit.)
SMILES string	CC(C)NC[C@@H](O)COc1ccc(CC(N)=O)cc1
InChI	1S/C14H22N2O3/c1-10(2)16-8-12(17)9-19-13-5-3-11(4-6-13)7-14(15)18/h3-6,10,12,16-17H,7-9H2,1-2H3,(H2,15,18)/t12-/m1/s1
Inchi Key	METKIMKYRPQLGS-GFCCVEGCSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Bornylamine

Empirical Formula (Hill Notation):	C₁₀H₁₉N
CAS Number:	32511-34-5
Molecular Weight:	153.26
Beilstein/REAXYS Number:	2801831
EC Number:	251-076-9
MDL number:	MFCD00042691
PubChem Substance ID:	24862125
NACRES:	NA.22

(R)-(+)-Bornylamine in the presence of acetonitrile as a solvent and tetraethylammonium bromide as the bromide ion source, may be used in the crystallization-induced chiral inversion of (S)-2-bromo-3-phenylpropanoic acid to its (R)-enantiomer. It may also be used to synthesize trans-bis{(R)-(+)-bornylamino}palladium(II) dichloride, a palladium(II) complex with potent antitumor activity.

Packaging

100, 500 mg in glass bottle

Параметры

Quality Level	200,
assay	97%
optical activity	[]20/D +44°, c = 0.5 in ethanol
mp	160-163 °C (lit.)
storage temp.	2-8°C
SMILES string	CC1(C)[C@@H]2CC[C@@]1(C)[C@@H](N)C2
InChI	1S/C10H19N/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7-8H,4-6,11H2,1-3H3/t7-,8+,10+/m1/s1
Inchi Key	MDFWXZBEVCOVIO-WEDXCCLWSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Citronellic acid

Empirical Formula (Hill Notation):	C₁₀H₁₈O₂
Linear Formula:	(CH₃)₂C=CHCH₂CH₂CH(CH₃)CH₂CO₂H
CAS Number:	18951-85-4
Molecular Weight:	170.25
MDL number:	MFCD00075195
PubChem Substance ID:	24860819
NACRES:	NA.22

Quality Level	100,
assay	98%
optical activity	[]25/D +8°, neat
refractive index	n20/D 1.4534 (lit.)
bp	119 °C/3 mmHg (lit.)
density	0.926 g/mL at 25 °C (lit.)
SMILES string	C[C@H](CC\C=C(/C)C)CC(O)=O
InChI	1S/C10H18O2/c1-8(2)5-4-6-9(3)7-10(11)12/h5,9H,4,6-7H2,1-3H3,(H,11,12)/t9-/m1/s1
InChI key	GJWSUKYXUMVMGX-SECBINFHSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H312 - H315
pcodes	P264 - P280 - P302 + P352 + P312 - P332 + P313 - P362 + P364 - P501
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2810 6.1 / PGIII
WGK Germany	WGK 3
Flash Point F	235.4 °F - closed cup
Flash Point C	113 °C - closed cup

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(R)-(+)-Glycidyl trityl ether

Empirical Formula (Hill Notation):	C₂₂H₂₀O₂
CAS Number:	65291-30-7
Molecular Weight:	316.39
MDL number:	MFCD00273368
PubChem Substance ID:	24868810
NACRES:	NA.22

Nucleotides with activity against herpes simplex virus 1 and 2, lipid ammonium salts, and thio analogs of phospholipids have been prepared recently through ring-opening of this epoxide with cytosine derivatives, amines, and thiols, respectively.
(R)-(+)-Glycidyl trityl ether may be used in the preparation of (R)-trityl(thiiranylmethyl)ether by reacting with thiourea. It may also be used as a starting material in the multi-step synthesis of (+)-actisonitrile.

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
assay	98%
optical activity	[]20/D +10.5°, c = 1 in chloroform
optical purity	ee: 98% (GLC)
mp	99-102 °C (lit.)
SMILES string	C1O[C@H]1COC(c2ccccc2)(c3ccccc3)c4ccccc4
InChI	1S/C22H20O2/c1-4-10-18(11-5-1)22(24-17-21-16-23-21,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-15,21H,16-17H2/t21-/m1/s1
InChI key	XFSXUCMYFWZRAF-OAQYLSRUSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Indoline-2-carboxylic acid

Empirical Formula (Hill Notation):	C₉H₉NO₂
CAS Number:	98167-06-7
Molecular Weight:	163.17
MDL number:	MFCD00792496
PubChem Substance ID:	57651318
NACRES:	NA.22

Quality Level	100,
assay	97.0%
optical activity	[]/D +116±3°, c = 1 in 1 M HCl
SMILES string	OC(=O)[C@H]1Cc2ccccc2N1
InChI	1S/C9H9NO2/c11-9(12)8-5-6-3-1-2-4-7(6)10-8/h1-4,8,10H,5H2,(H,11,12)/t8-/m1/s1
Inchi Key	QNRXNRGSOJZINA-MRVPVSSYSA-N

Safety Information

pictograms	GHS07,GHS08
signalword	Warning
hcodes	H317 - H361
pcodes	P201 - P280 - P302 + P352 - P308 + P313
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Lactamide

Empirical Formula (Hill Notation):	C₃H₇NO₂
Linear Formula:	CH₃CH(OH)CONH₂
CAS Number:	598-81-2
Molecular Weight:	89.09
MDL number:	MFCD00210310
PubChem Substance ID:	24867303

Quality Level	100,
assay	97%
optical activity	[]20/D +21.0°, c = 10 in H₂O
mp	50-53 °C (lit.)
SMILES string	C[C@@H](O)C(N)=O
InChI	1S/C3H7NO2/c1-2(5)3(4)6/h2,5H,1H3,(H2,4,6)/t2-/m1/s1
Inchi Key	SXQFCVDSOLSHOQ-UWTATZPHSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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(R)-(+)-Limonene

Empirical Formula (Hill Notation):	C₁₀H₁₆
CAS Number:	5989-27-5
Molecular Weight:	136.23
Beilstein/REAXYS Number:	2204754
EC Number:	227-813-5
MDL number:	MFCD00062991
PubChem Substance ID:	329759709

(R)-(+)-Limonene is an optically active (R) form of limonene. Limonene is a 10-carbon cyclohexanoid monoterpene. It is widely employed in cosmetic industry.
(R)-(+)-Limonene is present in the peel oil from citrus fruits. It is the most commonly used fragrance materials in technical products and in fine fragrances. It is the major constituent of the essential oil extracted from Anethum sowa Roxb. (Indian dill). Racemic limonene undergoes enantio-selective and enantio-specific conversion to (R)-(+)--terpineol byPenicillium digitatum mycelia. Biotransformation of (R)-(+)- and (S)-(-)-limonene by fungi has been investigated.

Application

(R)-(+)-Limonene has been used to investigate the in vitro and in vivo action of limonene against Leishmania species.

Параметры

vapor density	4.7 (vs air)
Quality Level	100,
vapor pressure	<3 mmHg ( 14.4 °C)
grade	technical
assay	~90% (sum of enantiomers, GC)
optical activity	[]20/D +112±5°, c = 10% in ethanol
expl. lim.	6.1 %
greener alternative product characteristics	Waste Prevention Safer Solvents and Auxiliaries Use of Renewable Feedstocks Learn more about the Principles of Green Chemistry,.
refractive index	n20/D 1.473 (lit.)
bp	176-177 °C (lit.)
solubility	water: insoluble
density	0.842 g/mL at 20 °C (lit.)
greener alternative category	Aligned,
storage temp.	2-8°C
SMILES string	CC(=C)[C@@H]1CCC(C)=CC1
InChI	1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1
InChI key	XMGQYMWWDOXHJM-JTQLQIEISA-N

Safety Information

pictograms	GHS02,GHS07,GHS08,GHS09
signalword	Danger
hcodes	H226 - H304 - H315 - H317 - H410
pcodes	P210 - P273 - P280 - P301 + P310 + P331 - P302 + P352
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2052 3 / PGIII
WGK Germany	WGK 3
Flash Point F	123.8 °F - closed cup
Flash Point C	51 °C - closed cup

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(R)-(+)-Methyl p-tolyl sulfoxide

Empirical Formula (Hill Notation):	C₈H₁₀OS
Linear Formula:	CH₃C₆H₄S(O)CH₃
CAS Number:	1519-39-7
Molecular Weight:	154.23
Beilstein/REAXYS Number:	2040677
MDL number:	MFCD00151502
PubChem Substance ID:	24861180
NACRES:	NA.22

(R)-(+)-Methyl p-tolyl sulfoxide may be used to prepare (R)-(+)-methyl 3,5-dimethoxy-6-[8-oxo-9-(p-tolylsulfinyl) nonyl] benzoate, an intermediate for (R)-lasiodiplodin synthesis. Its anions undergo addition reaction with nitrones to form optically active a-substituted N-hydroxylamines. (R)-(+)-Methyl p-tolyl sulfoxide also reacts with O-mesitylsulfonylhydroxylamine (MSH) to form (-)-(R)-S-methyl-S-p-tolylsulfoximine.

Packaging

1 g in glass bottle

Параметры

assay	99%
optical activity	[]20/D +145°, c = 2 in acetone
optical purity	ee: 99% (HPLC)
mp	73-75 °C (lit.)
SMILES string	Cc1ccc(cc1)S(C)=O
InChI	1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3/t10-/m1/s1
Inchi Key	FEVALTJSQBFLEU-SNVBAGLBSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable