Chiral Catalysts & Ligands
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(S)--Methoxy-2-naphthylacetic acid
Empirical Formula (Hill Notation): C13H12O3 CAS Number: 157134-51-5 Molecular Weight: 216.23 MDL number: MFCD10000872 PubChem Substance ID: 329760364 NACRES: NA.22
Кат. номер 669989-500MG 669989-100MG ПараметрыQuality Level 100, assay 97.0% (HPLC), 97% optical activity []/D +177±5°, c = 0.1 in methanol optical purity enantiomeric excess: 99% (HPLC) mp 111-114 °C SMILES string CO[C@H](C(O)=O)c1ccc2ccccc2c1 InChI 1S/C13H12O3/c1-16-12(13(14)15)11-7-6-9-4-2-3-5-10(9)8-11/h2-8,12H,1H3,(H,14,15)/t12-/m0/s1 Inchi Key OQVFHDWREDKUCW-LBPRGKRZSA-N
Safety Informationpictograms GHS06 signalword Danger hcodes H301 pcodes P301 + P310 + P330 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves, RIDADR UN 2811 6.1 / PGIII WGK Germany 3 Узнать цену -
(S)--Methyl-4-nitrobenzylamine hydrochloride
Empirical Formula (Hill Notation): C8H10N2O2 · HCl Linear Formula: O2NC6H4CH(CH3)NH2 · HCl CAS Number: 132873-57-5 Molecular Weight: 202.64 MDL number: MFCD00066312 PubChem Substance ID: 24860686 NACRES: NA.22
Кат. номер 339822-1G 339822-250MG Application(S)--Methyl-4-nitrobenzylamine hydrochloride can be used as:- A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
- A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.
Packaging1 g in glass bottleПараметрыQuality Level 200, assay 97% optical activity []25/D 6.5°, c = 1 in 0.05 M NaOH mp 248-250 °C (lit.) SMILES string Cl.C[C@H](N)c1ccc(cc1)[N+]([O-])=O InChI 1S/C8H10N2O2.ClH/c1-6(9)7-2-4-8(5-3-7)10(11)12;/h2-6H,9H2,1H3;1H/t6-;/m0./s1 InChI key CZQQGVFHLSBEDV-RGMNGODLSA-N
Safety InformationPersonal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)--Methylphenethylamine 461393-1G
Empirical Formula (Hill Notation): C9H13N Linear Formula: C6H5CH(CH3)CH2NH2 CAS Number: 17596-79-1 Molecular Weight: 135.21 Beilstein/REAXYS Number: 3195645 MDL number: MFCD00216741 PubChem Substance ID: 24869850 NACRES: NA.22 General descriptionBacteriorhodopsin is the prototypical "seven-helix" transmembrane protein (with seven α-helical domains), whose study led to advances in understanding G protein-coupled receptors (GPCRs). In Halobacteria, it acts as a light-harvesting protein, producing a proton gradient across the cell wall that is then used to drive biosynthetic processes.Packaging1 g in glass bottleApplicationBuilding block for the enantioselective synthesis of pyrizinostatin, a pyroglutamyl peptidase inhibitor.ПараметрыQuality Level 100, assay 99% optical activity []22/D 35°, c = 1 in ethanol refractive index n20/D 1.525 (lit.) mp 207 °C (lit.) density 0.945 g/mL at 25 °C (lit.) SMILES string C[C@H](CN)c1ccccc1 InChI 1S/C9H13N/c1-8(7-10)9-5-3-2-4-6-9/h2-6,8H,7,10H2,1H3/t8-/m1/s1 InChI key AXORVIZLPOGIRG-MRVPVSSYSA-N
Safety Informationpictograms GHS05 signalword Danger hcodes H314 pcodes P280 - P305 + P351 + P338 - P310 Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 2735PSN1 8 / PGIII WGK Germany WGK 3 Flash Point F 177.8 °F - closed cup Flash Point C 81 °C - closed cup Узнать цену -
(S)-1-Boc-2-piperidineacetic acid
Empirical Formula (Hill Notation): C12H21NO4 CAS Number: 159898-10-9 Molecular Weight: 243.30 MDL number: MFCD06656439 PubChem Substance ID: 329760349 NACRES: NA.22
Кат. номер 669725-1G 669725-250MG ПараметрыQuality Level 100, assay 99.0% (HPLC) optical activity []/D -12.0±2°, c = 1.5 in methanol SMILES string CC(C)(C)OC(=O)N1CCCC[C@H]1CC(O)=O InChI 1S/C12H21NO4/c1-12(2,3)17-11(16)13-7-5-4-6-9(13)8-10(14)15/h9H,4-8H2,1-3H3,(H,14,15)/t9-/m0/s1 Inchi Key CKAXJDBTNNEENW-VIFPVBQESA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-Boc-3-(methylamino)piperidine 735833-500MG
Empirical Formula (Hill Notation): C11H22N2O2 CAS Number: 912368-73-1 Molecular Weight: 214.30 MDL number: MFCD09752964 PubChem Substance ID: 329765061 NACRES: NA.22 ПараметрыQuality Level 100, assay 97% refractive index n20/D 1.467 density 0.985 at 25 °C storage temp. 2-8°C SMILES string CN[C@H]1CCCN(C1)C(=O)OC(C)(C)C InChI 1S/C11H22N2O2/c1-11(2,3)15-10(14)13-7-5-6-9(8-13)12-4/h9,12H,5-8H2,1-4H3/t9-/m0/s1 InChI key XRRRUOWSHGFPTI-VIFPVBQESA-N
Safety Informationpictograms GHS06,GHS09 signalword Danger hcodes H301 - H319 - H400 pcodes P273 - P301 + P310 + P330 - P305 + P351 + P338 RIDADR UN 2811 6.1 / PGIII WGK Germany WGK 3 Flash Point F No data available Flash Point C No data available Узнать цену -
(S)-1-Boc-3-cyanopyrrolidine 779504-500MG
Empirical Formula (Hill Notation): C10H16N2O2 CAS Number: 132945-78-9 Molecular Weight: 196.25 MDL number: MFCD03419277 PubChem Substance ID: 329768044 NACRES: NA.22 ПараметрыQuality Level 100, assay 95.5% (HPLC), 96% optical activity []/D +24.0±2.0°, c = 1 in methanol SMILES string CC(C)(C)OC(=O)N1CC[C@@H](C1)C#N InChI 1S/C10H16N2O2/c1-10(2,3)14-9(13)12-5-4-8(6-11)7-12/h8H,4-5,7H2,1-3H3/t8-/m1/s1 Inchi Key VDDMCMFPUSCJNA-MRVPVSSYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-Boc-3-hydroxypiperidine 687367-1G
Empirical Formula (Hill Notation): C10H19NO3 CAS Number: 143900-44-1 Molecular Weight: 201.26 MDL number: MFCD04115307 PubChem Substance ID: 329761124 NACRES: NA.22 ПараметрыQuality Level 100, assay 97% optical activity []22/D +10.0°, c = 1 in chloroform mp 34-40 °C SMILES string CC(C)(C)OC(=O)N1CCC[C@H](O)C1 InChI 1S/C10H19NO3/c1-10(2,3)14-9(13)11-6-4-5-8(12)7-11/h8,12H,4-7H2,1-3H3/t8-/m0/s1 Inchi Key UIJXHKXIOCDSEB-QMMMGPOBSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 230.0 °F - closed cup Flash Point C > 110 °C - closed cup Узнать цену -
(S)-1-Boc-3-methylpiperazine
Empirical Formula (Hill Notation): C10H20N2O2 CAS Number: 147081-29-6 Molecular Weight: 200.28 MDL number: MFCD02683204 PubChem Substance ID: 57651931 NACRES: NA.22
Кат. номер 63207-5G-F 63207-1G-F 63207-1G ApplicationReactant involved in the synthesis of biologically activy molecules including:- CCR5 antagonists with anti-HIV-1 activity
- Opioid receptor antagonists
- Human growth hormone secretagogue receptor antagonists for treatment of obesity
- Fatty acid oxidation inhibitors
Packaging5 g in poly bottle
1 g in poly tubeПараметрыQuality Level 100, assay 98% optical activity []/D -16±2°, c = 1 in dioxane SMILES string C[C@H]1CN(CCN1)C(=O)OC(C)(C)C InChI 1S/C10H20N2O2/c1-8-7-12(6-5-11-8)9(13)14-10(2,3)4/h8,11H,5-7H2,1-4H3/t8-/m0/s1 InChI key FMLPQHJYUZTHQS-QMMMGPOBSA-N
Safety Informationpictograms GHS05,GHS07 signalword Danger hcodes H315 - H318 - H335 pcodes P280 - P302 + P352 - P305 + P351 + P338 + P310 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-Boc-piperidine-3-carboxylic acid 681229-500MG
Empirical Formula (Hill Notation): C11H19NO4 CAS Number: 88495-54-9 Molecular Weight: 229.27 MDL number: MFCD02179172 PubChem Substance ID: 329760751 NACRES: NA.22 ПараметрыQuality Level 100, assay 97% optical activity []22/D +57°, c = 1 in chloroform mp 165-169 °C SMILES string CC(C)(C)OC(=O)N1CCC[C@@H](C1)C(O)=O InChI 1S/C11H19NO4/c1-11(2,3)16-10(15)12-6-4-5-8(7-12)9(13)14/h8H,4-7H2,1-3H3,(H,13,14)/t8-/m0/s1 InChI key NXILIHONWRXHFA-QMMMGPOBSA-N
Safety Informationpictograms GHS07,GHS09 signalword Warning hcodes H319 - H400 pcodes P273 - P305 + P351 + P338 Personal Protective Equipment Eyeshields,, Gloves, RIDADR UN 3077 9 / PGIII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-Cyclopropylethylamine
Empirical Formula (Hill Notation): C5H11N CAS Number: 195604-39-8 Molecular Weight: 85.15 MDL number: MFCD08064289 PubChem Substance ID: 329764309 NACRES: NA.22
Кат. номер 727245-25G 727245-5G Legal InformationChiPros is a registered trademark of BASF SEПараметрыQuality Level 100, grade produced by BASF assay 98.5% (GC), 99% optical purity enantiomeric excess: 98.5% SMILES string C[C@H](N)C1CC1 InChI 1S/C5H11N/c1-4(6)5-2-3-5/h4-5H,2-3,6H2,1H3/t4-/m0/s1 Inchi Key IXCXVGWKYIDNOS-BYPYZUCNSA-N
Safety Informationpictograms GHS02,GHS05 signalword Danger hcodes H225 - H314 pcodes P210 - P280 - P305 + P351 + P338 - P310 RIDADR UN 2733PSN1 8(3) / PGII WGK Germany WGK 3 Flash Point F 69.8 °F Flash Point C < 21 °C Узнать цену -
(S)-1-Fmoc-4-oxopiperidine-2-carboxylic acid 735574-500MG
Empirical Formula (Hill Notation): C21H19NO5 CAS Number: 1221793-43-6 Molecular Weight: 365.38 MDL number: MFCD03094868 PubChem Substance ID: 329765036 NACRES: NA.22 ПараметрыQuality Level 100, mp 228-233 °C functional group Fmoc storage temp. 2-8°C SMILES string OC(=O)[C@@H]1CC(=O)CCN1C(=O)OCC2c3ccccc3-c4ccccc24 InChI 1S/C21H19NO5/c23-13-9-10-22(19(11-13)20(24)25)21(26)27-12-18-16-7-3-1-5-14(16)15-6-2-4-8-17(15)18/h1-8,18-19H,9-12H2,(H,24,25)/t19-/m0/s1 InChI key YGAHCGORXONSSM-IBGZPJMESA-N
Safety Informationpictograms GHS09 signalword Warning hcodes H400 pcodes P273 RIDADR UN 3077 9 / PGIII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-N-Boc-3-methylaminopiperidine CDS019342-100MG
Empirical Formula (Hill Notation): C11H22N2O2 Molecular Weight: 214.30 MDL number: MFCD09752964 PubChem Substance ID: 329792712 Other NotesPlease note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.ПараметрыSMILES string CN[C@H]1CCCN(C1)C(=O)OC(C)(C)C InChI 1S/C11H22N2O2/c1-11(2,3)15-10(14)13-7-5-6-9(8-13)12-4/h9,12H,5-8H2,1-4H3/t9-/m0/s1 InChI key XRRRUOWSHGFPTI-VIFPVBQESA-N
Safety Informationpictograms GHS06 signalword Danger hcodes H301 pcodes P301 + P310 RIDADR UN 2811 6.1 / PGIII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-Octen-3-ol 40577-1G-F
Empirical Formula (Hill Notation): C8H16O CAS Number: 24587-53-9 Molecular Weight: 128.21 MDL number: MFCD04972323 PubChem Substance ID: 57650004 NACRES: NA.22 Application(S)-1-Octen-3-ol can be used:- As an odorant in the study of an olfactory sensory map of the Anopheles gambiae maxillary palp.
- As an intermediate in the synthesis of natural product polyporolide and a prostaglandin named 8-aza-prostaglandin E1.
- As a substrate in the preparation of trienols by reacting with 1-iodo-1,3-dienes using Pd(OAc)2/AgOAc.
Packaging1 g in glass bottleПараметрыQuality Level 100, assay 95% (sum of enantiomers, GC) optical purity enantiomeric ratio: 99:1 (GC) SMILES string CCCCC[C@H](O)C=C InChI 1S/C8H16O/c1-3-5-6-7-8(9)4-2/h4,8-9H,2-3,5-7H2,1H3/t8-/m1/s1 Inchi Key VSMOENVRRABVKN-MRVPVSSYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 - H315 - H319 pcodes P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 154.4 °F - closed cup Flash Point C 68 °C - closed cup Узнать цену -
(S)-1-[(1-Methyl-2-pyrrolidinyl)methyl]piperidine 446351-1ML
Empirical Formula (Hill Notation): C11H22N2 CAS Number: 84466-85-3 Molecular Weight: 182.31 Beilstein/REAXYS Number: 4242955 MDL number: MFCD18642280 PubChem Substance ID: 24868270 NACRES: NA.22 Packaging1 mL in glass bottleApplicationUseful chiral ligand for catalytic asymmetric aldol reactions. Mukaiyama, T.Параметрыassay 97% optical activity []20/D 69°, c = 0.5 in ethanol refractive index n20/D 1.478 (lit.) bp 121-123 °C/22 mmHg (lit.) density 0.909 g/mL at 25 °C (lit.) SMILES string CN1CCC[C@H]1CN2CCCCC2 InChI 1S/C11H22N2/c1-12-7-5-6-11(12)10-13-8-3-2-4-9-13/h11H,2-10H2,1H3/t11-/m0/s1 Inchi Key VCVPSRADUBPOKJ-NSHDSACASA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 pcodes P305 + P351 + P338 Personal Protective Equipment Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
(S)-1-[(R)--Methylbenzyl)aziridine-2-carboxamide
Empirical Formula (Hill Notation): C11H14N2O CAS Number: 75985-51-2 Molecular Weight: 190.24 MDL number: MFCD04039900 PubChem Substance ID: 24880572
Кат. номер 570524-1G 570524-5G Параметрыassay 98% optical activity []20/D 43°, c = 1 in methanol optical purity ee: 98% (GLC) mp 102-105 °C (lit.) SMILES string C[C@@H](N1C[C@H]1C(N)=O)c2ccccc2 InChI 1S/C11H14N2O/c1-8(9-5-3-2-4-6-9)13-7-10(13)11(12)14/h2-6,8,10H,7H2,1H3,(H2,12,14)/t8-,10+,13?/m1/s1 Inchi Key PUPRTGJZBLTWDQ-KMDCHFIWSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315-H319-H335 pcodes P261-P305 + P351 + P338 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany 3 Узнать цену -
(S)-1-[(RP)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine
Empirical Formula (Hill Notation): C34H44FeP2 CAS Number: 849924-77-2 Molecular Weight: 570.51 MDL number: MFCD08561173 PubChem Substance ID: 24889144
Кат. номер 88756-100G 88756-250G 88756-50G 88756-1G 88756-500MG 88756-5G 88756-100MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыassay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(C(C)(C)C)C(C)(C)C)P(c3ccccc3C)c4ccccc4C InChI 1S/C29H39P2.C5H5.Fe/c1-21-15-10-12-18-25(21)30(26-19-13-11-16-22(26)2)23(3)24-17-14-20-27(24)31(28(4,5)6)29(7,8)9;1-2-4-5-3-1;/h10-20,23H,1-9H3;1-5H;/t23-;;/m0../s1 Inchi Key DSZYQALCGVODLB-IFUPQEAVSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany 3 Узнать цену -
(S)-1-[(RP)-2-(Di-tert-butylphosphino)ferrocenyl]ethyldiphenylphosphine
Empirical Formula (Hill Notation): C32H40FeP2 CAS Number: 223121-01-5 Molecular Weight: 542.45 MDL number: MFCD08561171 PubChem Substance ID: 24889142 NACRES: NA.22
Кат. номер 88754-5G 88754-1G 88754-500MG 88754-100MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(C(C)(C)C)C(C)(C)C)P(c3ccccc3)c4ccccc4 InChI 1S/C27H35P2.C5H5.Fe/c1-21(24-19-14-20-25(24)29(26(2,3)4)27(5,6)7)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m0../s1 Inchi Key MJOXBJGLXGTJRJ-FGJQBABTSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-[(RP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Empirical Formula (Hill Notation): C32H52FeP2 CAS Number: 1246841-00-8 Molecular Weight: 554.55 MDL number: MFCD08561155 PubChem Substance ID: 24889122 NACRES: NA.22
Кат. номер 88734-100MG 88734-1G 88734-500MG 88734-5G General descriptionsold in collaboration with Solvias AGPackaging1 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C InChI 1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m0../s1 Inchi Key FFFWTQLOUUWUJJ-FGJQBABTSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-[(RP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
Empirical Formula (Hill Notation): C36H56FeP2 CAS Number: 246231-77-6 Molecular Weight: 606.62 MDL number: MFCD00800279 PubChem Substance ID: 24888990 NACRES: NA.22
Кат. номер 88722-5G 88722-1G 88722-500MG 88722-100MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)C6CCCCC6 InChI 1S/C31H51P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h14,23-29H,2-13,15-22H2,1H3;1-5H;/t25-;;/m0../s1 InChI key LVJMXQBMWBNENE-WLOLSGMKSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Empirical Formula (Hill Notation): C32H40FeP2 CAS Number: 277306-29-3 Molecular Weight: 542.45 MDL number: MFCD01074443 PubChem Substance ID: 24888988 NACRES: NA.22
Кат. номер 88720-500MG 88720-100MG 88720-1G 88720-50G 88720-250G 88720-100G 88720-5G General descriptionsold in collaboration with Solvias AGPackaging1 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97% optical activity []20/D +410±15°, c = 0.5 in chloroform optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C(C)(C)C)C(C)(C)C InChI 1S/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m0../s1 InChI key STAGMXYQPGLLTD-FGJQBABTSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine
Empirical Formula (Hill Notation): C36H44FeP2 · C2H5OH CAS Number: 162291-02-3 Molecular Weight: 640.60 MDL number: MFCD00800285 PubChem Substance ID: 24888986 NACRES: NA.22
Кат. номер 88718-250G 88718-5G 88718-100MG 88718-1G 88718-100G 88718-50G 88718-500MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыdescription ethanol adduct Quality Level 100, assay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C5CCCCC5)C6CCCCC6 InChI 1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m0../s1 InChI key HGTBZFMPHBAUCQ-WLOLSGMKSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-{(RP)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine
Empirical Formula (Hill Notation): C42H56FeO2P2 CAS Number: 849923-88-2 Molecular Weight: 710.69 MDL number: MFCD08561152 PubChem Substance ID: 24889118
Кат. номер 88730-100MG 88730-1G 88730-5G 88730-500MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыassay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.COc2c(C)cc(cc2C)P([C]3[CH][CH][CH][C]3[C@H](C)P(C4CCCCC4)C5CCCCC5)c6cc(C)c(OC)c(C)c6 InChI 1S/C37H51O2P2.C5H5.Fe/c1-25-21-32(22-26(2)36(25)38-6)41(33-23-27(3)37(39-7)28(4)24-33)35-20-14-19-34(35)29(5)40(30-15-10-8-11-16-30)31-17-12-9-13-18-31;1-2-4-5-3-1;/h14,19-24,29-31H,8-13,15-18H2,1-7H3;1-5H;/t29-;;/m0../s1 Inchi Key QYTRSAIHSZHSTP-UJXPALLWSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany 3 Узнать цену -
(S)-1-{(RP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine
Empirical Formula (Hill Notation): C34H38F6FeP2 CAS Number: 849924-37-4 Molecular Weight: 678.45 MDL number: MFCD04038736 PubChem Substance ID: 24889124
Кат. номер 88736-1G 88736-500MG 88736-100MG 88736-5G General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыassay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccc(cc3)C(F)(F)F)c4ccc(cc4)C(F)(F)F)P(C(C)(C)C)C(C)(C)C InChI 1S/C29H33F6P2.C5H5.Fe/c1-19(37(26(2,3)4)27(5,6)7)24-9-8-10-25(24)36(22-15-11-20(12-16-22)28(30,31)32)23-17-13-21(14-18-23)29(33,34)35;1-2-4-5-3-1;/h8-19H,1-7H3;1-5H;/t19-;;/m1../s1 InChI key ZYPSDHCBNMCWCZ-JQDLGSOUSA-N
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(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine
Empirical Formula (Hill Notation): C46H32F12FeP2 CAS Number: 849925-17-3 Molecular Weight: 930.52 MDL number: MFCD04117710 PubChem Substance ID: 24884221 NACRES: NA.22
Кат. номер 65672-1G 65672-500MG 65672-100MG 65672-50G 65672-250G 65672-100G 65672-5G General descriptionsold in collaboration with Solvias AGApplication(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine can be used:- To prepare sulfide-capped triruthenium hydrido clusters containing Walphos ligands, which are employed as catalysts for asymmetric hydrogenation of tiglic acid (trans-2-methyl-2-butenoic acid).
- As a ligand in the reductive allylic alkylation of unsaturated carbonyl compounds using Pd catalyst.
Packaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97% optical purity ee: 99% SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F InChI 1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m1../s1 Inchi Key LKNKYBWIZNAXBY-KHZPMNTOSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethyldicyclohexylphosphine
Empirical Formula (Hill Notation): C42H48FeP2 CAS Number: 849925-19-5 Molecular Weight: 670.62 MDL number: MFCD04117711 PubChem Substance ID: 24884229
Кат. номер 65676-5G 65676-1G 65676-500MG 65676-100MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыassay 97% optical purity ee: >99% storage temp. 2-8°C SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(C6CCCCC6)C7CCCCC7 InChI 1S/C37H43P2.C5H5.Fe/c1-29(38(30-17-6-2-7-18-30)31-19-8-3-9-20-31)34-26-16-27-35(34)36-25-14-15-28-37(36)39(32-21-10-4-11-22-32)33-23-12-5-13-24-33;1-2-4-5-3-1;/h4-5,10-16,21-31H,2-3,6-9,17-20H2,1H3;1-5H;/t29-;;/m1../s1 Inchi Key OBVCATYDMKRFLP-SYXKTQFYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany 3 Узнать цену -
(S)-1-{(SP)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine
Empirical Formula (Hill Notation): C52H44F12FeO2P2 CAS Number: 849925-20-8 Molecular Weight: 1046.68 MDL number: MFCD08561125 PubChem Substance ID: 24884232
Кат. номер 65678-5G 65678-1G 65678-500MG 65678-100MG General descriptionsold in collaboration with Solvias AGPackaging1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97% optical purity ee: 99% storage temp. 2-8°C SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.COc2c(C)cc(cc2C)P(c3cc(C)c(OC)c(C)c3)c4ccccc4[C]5[CH][CH][CH][C]5[C@H](C)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F InChI 1S/C47H39F12O2P2.C5H5.Fe/c1-25-15-34(16-26(2)42(25)60-6)63(35-17-27(3)43(61-7)28(4)18-35)41-14-9-8-11-40(41)39-13-10-12-38(39)29(5)62(36-21-30(44(48,49)50)19-31(22-36)45(51,52)53)37-23-32(46(54,55)56)20-33(24-37)47(57,58)59;1-2-4-5-3-1;/h8-24,29H,1-7H3;1-5H;/t29-;;/m0../s1 InChI key LYSMTOMQQHQCKG-UJXPALLWSA-N
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(S)-2,5-Dihydro-3,6-dimethoxy-2-isopropylpyrazine
Empirical Formula (Hill Notation): C9H16N2O2 CAS Number: 78342-42-4 Molecular Weight: 184.24 Beilstein/REAXYS Number: 3650245 MDL number: MFCD00066229 PubChem Substance ID: 329755637 NACRES: NA.22
Кат. номер 37289-1ML 37289-VAR ПараметрыQuality Level 100, assay 97.0% (GC) optical activity []20/D +102.0±5°, c = 1% in ethanol density 1.028 g/mL at 20 °C (lit.) SMILES string COC1=N[C@@H](C(C)C)C(OC)=NC1 InChI 1S/C9H16N2O2/c1-6(2)8-9(13-4)10-5-7(11-8)12-3/h6,8H,5H2,1-4H3/t8-/m0/s1 Inchi Key FCFWEOGTZZPCTO-QMMMGPOBSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-(1-Diphenylphosphino-2-methylpropan-2-yl)-4-isopropyl-4,5-dihydrooxazole 729264-100MG
Empirical Formula (Hill Notation): C22H28NOP Molecular Weight: 353.44 MDL number: MFCD16876061 PubChem Substance ID: 329764464 NACRES: NA.22 ПараметрыQuality Level 100, assay 97% optical activity []22/D 25.0°, c = 0.5 in chloroform refractive index n20/D 1.575 density 1.057 g/mL at 25 °C SMILES string CC(C)[C@H]1COC(=N1)C(C)(C)CP(c2ccccc2)c3ccccc3 InChI 1S/C22H28NOP/c1-17(2)20-15-24-21(23-20)22(3,4)16-25(18-11-7-5-8-12-18)19-13-9-6-10-14-19/h5-14,17,20H,15-16H2,1-4H3/t20-/m1/s1 InChI key FYXTWZZTVCGWFU-HXUWFJFHSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 230.0 °F Flash Point C 110 °C Узнать цену -
(S)-2-(2,3-Bis(dicyclohexylamino)cyclopropenimine)-3-phenylpropan-1-ol hydrochloride
Empirical Formula (Hill Notation): C36H55N3O · HCl CAS Number: 1366421-67-1 Molecular Weight: 582.30
Кат. номер 900811-500MG 900811-1G General descriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.ApplicationChiral cyclopropenimines are a highly effective new class of enantioselective Brnsted base catalysts - the so-called “superbases” for enantioselective organocatalysis. Due to the prevalence of chemical reactions involving proton transfer as a key mechanistic event, Brnsted bases have become indispensable tools for the practice of organic synthetic chemistry, capable of catalyzing proton transfer reactions enantioselectively for the production of optically enriched products. Catalyst is stored as co-salt for stability. Conversion of the HCl salt to free catalyst requires a simple wash with aqueous base. This is one of a suite of Brnsted catalysts reported by Tristan Lambert, and coworkers available through Sigma-Aldrich.Other NotesEnantioselective Bronsted Base Catalysis with Chiral Cyclopropenimines,
Cyclopropenimine-Catalyzed Enantioselective Mannich Reactions of tert-Butyl Glycinates with N-Boc-Imines,
Transition State Analysis of Enantioselective Bronsted Base Catalysis by Chiral Cyclopropenimines,
Structure-activity relationship studies of cyclopropenimines as enantioselective Bronsted base catalysts,
Asymmetric Bronsted Base-Catalyzed and -Directed [3+2] Cycloaddition of 2-Acyl Cycloheptatrienes with Azomethine Ylides,ПараметрыQuality Level 100, assay 95% form powder or solid reaction suitability reagent type: catalyst
reaction type: Asymmetric synthesisgreener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry,.greener alternative category Aligned,
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-(2-Bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole 720151-1G
Empirical Formula (Hill Notation): C14H18BrNO Molecular Weight: 296.20 MDL number: MFCD16621469 PubChem Substance ID: 329763705 NACRES: NA.22 Application(S)-2-(2-Bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole can be used as a key intermediate for the preparation of (S)-5,5-(dimethyl)-i-Pr-PHOX, a chiral ligand employed in the palladium-catalyzed asymmetric transformations.Packaging1 g in glass bottleПараметрыQuality Level 100, assay 96% optical activity []22/D 41.0°, c = 0.5 in chloroform refractive index n20/D 1.541 density 1.247 g/mL at 25 °C SMILES string CC1(C)[C@H](C(C)C)N=C(C2=CC=CC=C2Br)O1 InChI 1S/C14H18BrNO/c1-9(2)12-14(3,4)17-13(16-12)10-7-5-6-8-11(10)15/h5-9,12H,1-4H3/t12-/m0/s1 Inchi Key SJKCCGPXYWNYGX-LBPRGKRZSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany nwg Flash Point F 230.0 °F - closed cup Flash Point C > 110 °C - closed cup Узнать цену -
(S)-2-(3-Chloro-2,2-dimethyl-propionylamino)-3-methylbutanol 725315-1G
Empirical Formula (Hill Notation): C10H20ClNO2 Molecular Weight: 221.72 MDL number: MFCD16876062 PubChem Substance ID: 329764146 NACRES: NA.22 ПараметрыQuality Level 100, assay 97% mp 73-79 °C SMILES string CC(C)[C@@H](CO)NC(=O)C(C)(C)CCl InChI 1S/C10H20ClNO2/c1-7(2)8(5-13)12-9(14)10(3,4)6-11/h7-8,13H,5-6H2,1-4H3,(H,12,14)/t8-/m1/s1 InChI key NBXJRNNARUAEFQ-MRVPVSSYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 230.0 °F Flash Point C > 110 °C Узнать цену -
(S)-2-(Aminomethyl)-1-Boc-pyrrolidine
Empirical Formula (Hill Notation): C10H20N2O2 CAS Number: 119020-01-8 Molecular Weight: 200.28 Beilstein/REAXYS Number: 8905233 MDL number: MFCD03419257 PubChem Substance ID: 329760455 NACRES: NA.22
Кат. номер 672084-500MG 672084-100MG Application(S)-2-(Aminomethyl)-1-Boc-pyrrolidine can be used as a building block to synthesize:- Imidazo[1,2-b]pyridazine derivatives as potent IKK inhibitors.
- 1,2-dicarba-closo-dodecaborane (o-carborane) and 1,7-dicarba-closo-dodecaborane (m-carborane) derivatives as potential D2 receptor antagonists.
- Pyrrolidine based Merrifield resin as a chiral organocatalyst for the asymmetric Michael addition reaction of ketones with nitrostyrenes.
Packaging100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыassay 96.5% (GC), 96.5-103.5% (NT), 97% optical purity enantiomeric excess: 97.5% (GC) storage temp. 2-8°C SMILES string CC(C)(C)OC(=O)N1CCC[C@H]1CN InChI 1S/C10H20N2O2/c1-10(2,3)14-9(13)12-6-4-5-8(12)7-11/h8H,4-7,11H2,1-3H3/t8-/m0/s1 InChI key SOGXYCNKQQJEED-QMMMGPOBSA-N
Safety Informationpictograms GHS05,GHS07 signalword Danger hcodes H302 - H314 pcodes P260 - P280 - P301 + P312 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN 3259PSN1 8 / PGIII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-(Boc-amino)-1-propanol
Empirical Formula (Hill Notation): C8H17NO3 Linear Formula: CH3CH[NHCO2C(CH3)3]CH2OH CAS Number: 79069-13-9 Molecular Weight: 175.23 Beilstein/REAXYS Number: 3648840 MDL number: MFCD00043121 PubChem Substance ID: 24870610 NACRES: NA.22
Кат. номер 469513-5G 469513-1G ПараметрыQuality Level 100, assay 98% optical activity []20/D 11°, c = 1 in chloroform optical purity ee: 98% (GLC) mp 59-62 °C (lit.) SMILES string C[C@@H](CO)NC(=O)OC(C)(C)C InChI 1S/C8H17NO3/c1-6(5-10)9-7(11)12-8(2,3)4/h6,10H,5H2,1-4H3,(H,9,11)/t6-/m0/s1 InChI key PDAFIZPRSXHMCO-LURJTMIESA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-(Methoxydiphenylmethyl)pyrrolidine
Empirical Formula (Hill Notation): C18H21NO CAS Number: 118971-03-2 Molecular Weight: 267.37 MDL number: MFCD09750440 PubChem Substance ID: 24885069 NACRES: NA.22
Кат. номер 670197-100MG 670197-500MG Application(S)-2-(Methoxydiphenylmethyl)pyrrolidine is a diphenylprolinol methyl ether, which can be used as a catalyst to synthesize:- Enantioselective ketones via intermolecular asymmetric Michael addition of aldehydes to nonactivated enones.
- Stereoselective chiral bipyrazolidin-3-one derivatives by dipolar cycloaddition reaction of azomethine imines with , -unsaturated aldehydes.
- Enantioenriched spiro nitrogen heterocycles via asymmetric nucleophilic epoxidation of -ylideneoxindole esters.
- Optically active secondary alcohols by asymmetric addition of Et2Zn to various aldehydes.
Packaging100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Параметрыassay 95% (HPLC) optical purity ee: 99.5% (HPLC) storage temp. 2-8°C SMILES string COC([C@@H]1CCCN1)(c2ccccc2)c3ccccc3 InChI 1S/C18H21NO/c1-20-18(17-13-8-14-19-17,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17,19H,8,13-14H2,1H3/t17-/m0/s1 Inchi Key CGUGCZSRPDCLBT-KRWDZBQOSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-(N,N-Dibenzylamino)-3-methylbutanol 538167-5G
Empirical Formula (Hill Notation): C19H25NO CAS Number: 111060-54-9 Molecular Weight: 283.41 MDL number: MFCD05664217 PubChem Substance ID: 24878307 NACRES: NA.22 ПараметрыQuality Level 100, assay 90% impurities (4% EtOAc first lot) refractive index n20/D 1.5459 density 1.0088 g/mL at 25 °C SMILES string CC(C)[C@@H](CO)N(Cc1ccccc1)Cc2ccccc2 InChI 1S/C19H25NO/c1-16(2)19(15-21)20(13-17-9-5-3-6-10-17)14-18-11-7-4-8-12-18/h3-12,16,19,21H,13-15H2,1-2H3/t19-/m1/s1 InChI key ZWLAXLXECFRUPM-LJQANCHMSA-N
Safety Informationpictograms GHS02,GHS07 signalword Warning hcodes H226 - H315 - H319 - H335 pcodes P210 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 1993C 3 / PGIII WGK Germany WGK 3 Flash Point F 140.0 °F Flash Point C 60 °C Узнать цену -
(S)-2-(Trifluoromethyl)piperidine 755001-250MG
Empirical Formula (Hill Notation): C6H10F3N CAS Number: 154727-51-2 Molecular Weight: 153.15 MDL number: MFCD11226597 PubChem Substance ID: 329766472 NACRES: NA.22 Application(S)-2-(Trifluoromethyl)piperidine can be used as a reactant for the synthesis of (1R,2R)-2-((S)-2-(trifluoromethyl)piperidin-1-yl)-1,2-dihydronaphthalen-1-ol by ring-opening reaction of oxabenzonorbornadiene in the presence of iridium catalyst.Packaging250 mg in glass bottleПараметрыQuality Level 100, assay 97% optical activity []22/D -14.4°, c = 0.5% in methanol refractive index n20/D 1.391 density 1.161 g/mL at 25 °C SMILES string FC(F)(F)[C@@H]1CCCCN1 InChI 1S/C6H10F3N/c7-6(8,9)5-3-1-2-4-10-5/h5,10H,1-4H2/t5-/m0/s1 InChI key NAXDEFXCCITWEU-YFKPBYRVSA-N
Safety Informationpictograms GHS02,GHS07,GHS09 signalword Warning hcodes H226 - H302 - H315 - H319 - H335 - H400 pcodes P210 - P273 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR UN 1993C 3 / PGIII WGK Germany WGK 3 Flash Point F 79.0 °F - closed cup Flash Point C 26.1 °C - closed cup Узнать цену -
(S)-2-Oxiranylanisole
Empirical Formula (Hill Notation): C9H10O2 CAS Number: 71031-03-3 Molecular Weight: 150.17 MDL number: MFCD06659026 PubChem Substance ID: 329747984 NACRES: NA.22
Кат. номер 4855-VAR-F 4855-5G-F 4855-1G-F General descriptionThe epoxide hydrolase isolated from Bacillus megaterium ECU1001 can preferentially hydrolyze the (R)-enantiomer of racemic phenyl glycidyl ether to yield optically pure (S)-phenyl glycidyl ether.ПараметрыQuality Level 100, assay 97.0% (sum of enantiomers, GC) SMILES string C1O[C@@H]1COc2ccccc2 InChI 1S/C9H10O2/c1-2-4-8(5-3-1)10-6-9-7-11-9/h1-5,9H,6-7H2/t9-/m1/s1 Inchi Key FQYUMYWMJTYZTK-SECBINFHSA-N
Safety Informationpictograms GHS05,GHS07,GHS08 signalword Danger hcodes H312 + H332 - H315 - H317 - H318 - H335 - H350 pcodes P201 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 + P310 - P308 + P313 Target Organs Respiratory system Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, WGK Germany WGK 3 Flash Point F 159.8 °F Flash Point C 71 °C Узнать цену -
(S)-2-Phenyl-1-propanol
Empirical Formula (Hill Notation): C9H12O Linear Formula: CH3CH(C6H5)CH2OH CAS Number: 37778-99-7 Molecular Weight: 136.19 Beilstein/REAXYS Number: 2500176 MDL number: MFCD00145249 PubChem Substance ID: 329768196 NACRES: NA.22
Кат. номер 78929-5G 78929-VAR 78929-1G Параметрыgrade purum assay 98.0% (sum of enantiomers, GC) optical activity []20/D 15.0±1°, c = 1% in toluene refractive index n20/D 1.526 (lit.), n20/D 1.527 bp 214 °C (lit.) density 1 g/mL at 25 °C (lit.) SMILES string C[C@H](CO)c1ccccc1 InChI 1S/C9H12O/c1-8(7-10)9-5-3-2-4-6-9/h2-6,8,10H,7H2,1H3/t8-/m1/s1 Inchi Key RNDNSYIPLPAXAZ-MRVPVSSYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 226.4 °F - closed cup Flash Point C 108 °C - closed cup Узнать цену -
(S)-2-Piperidineethanol hydrochloride 670170-250MG
Empirical Formula (Hill Notation): C7H15NO · HCl CAS Number: 786684-21-7 Molecular Weight: 165.66 MDL number: MFCD09265049 PubChem Substance ID: 24885067 NACRES: NA.22 ПараметрыQuality Level 100, assay 98.0% (GC) optical purity enantiomeric ratio: 99.0:1.0 (GC) SMILES string Cl.OCC[C@@H]1CCCCN1 InChI 1S/C7H15NO.ClH/c9-6-4-7-3-1-2-5-8-7;/h7-9H,1-6H2;1H/t7-;/m0./s1 Inchi Key LJOCPKDUBFJADK-FJXQXJEOSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 - H315 - H319 - H335 pcodes P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-Vinyloxirane 19377-1G-F
Empirical Formula (Hill Notation): C4H6O CAS Number: 62249-80-3 Molecular Weight: 70.09 Beilstein/REAXYS Number: 5238466 MDL number: MFCD04040042 PubChem Substance ID: 57647791 NACRES: NA.22 ПараметрыQuality Level 100, grade technical assay 90% (sum of enantiomers, GC) optical activity []20/D +20.0±1°, c = 1% in pentane(lit.) refractive index n20/D 1.417 bp 66 °C (lit.) density 0.870 g/mL at 20 °C (lit.) storage temp. 2-8°C SMILES string C=C[C@H]1CO1 InChI 1S/C4H6O/c1-2-4-3-5-4/h2,4H,1,3H2/t4-/m0/s1 Inchi Key GXBYFVGCMPJVJX-BYPYZUCNSA-N
Safety Informationpictograms GHS02 signalword Danger hcodes H225 pcodes P210 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 1993BF 3 / PGII WGK Germany WGK 3 Flash Point F -58.0 °F - closed cup Flash Point C -50 °C - closed cup Узнать цену -
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine 716715-250MG
Empirical Formula (Hill Notation): C17H20NP CAS Number: 60261-46-3 Molecular Weight: 269.32 MDL number: MFCD16621443 PubChem Substance ID: 329763423 NACRES: NA.22 ApplicationCatalytic ligand in:- Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans
- Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal
Packaging250 mg in amber glass bottleLegal InformationSold under license from Kanata Chemical Technologies Inc. for research purposes only.Параметрыoptical activity []22/D 24.0°, c = 0.5 in ethanol Quality Level 100, refractive index n20/D 1.614 density 1.043 g/mL at 25 °C SMILES string C1CN[C@@H](C1)CP(c2ccccc2)c3ccccc3 InChI 1S/C17H20NP/c1-3-9-16(10-4-1)19(14-15-8-7-13-18-15)17-11-5-2-6-12-17/h1-6,9-12,15,18H,7-8,13-14H2/t15-/m0/s1 Inchi Key IWRBGJKCDORZHK-HNNXBMFYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 230.0 °F - closed cup Flash Point C > 110 °C - closed cup Узнать цену -
(S)-2-[2-[Bis(2-tolyl)phosphino]phenyl]-4-tert-butyl-2-oxazoline
Empirical Formula (Hill Notation): C27H30NOP CAS Number: 218460-00-5 Molecular Weight: 415.51 PubChem Substance ID: 329761173 NACRES: NA.22
Кат. номер 688533-500MG 688533-100MG ПараметрыQuality Level 100, assay 97% optical activity []22/D 69.0, c = 1 in chloroform mp 134-138 °C storage temp. 20°C SMILES string Cc1ccccc1P(c2ccccc2C)c3ccccc3C4=N[C@H](CO4)C(C)(C)C InChI 1S/C27H30NOP/c1-19-12-6-9-15-22(19)30(23-16-10-7-13-20(23)2)24-17-11-8-14-21(24)26-28-25(18-29-26)27(3,4)5/h6-17,25H,18H2,1-5H3/t25-/m1/s1 Inchi Key PWDWTBOBIGNWSX-RUZDIDTESA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide
Empirical Formula (Hill Notation): C23H25F6N3OS CAS Number: 959979-30-7 Molecular Weight: 505.52 MDL number: MFCD10567031 PubChem Substance ID: 329761582 NACRES: NA.22
Кат. номер 693316-500MG 693316-100MG General description(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide is a chiral thiourea organocatalyst developed by the Jacobsens group for asymmetric organic synthesis.Packaging100 mg in clear glass bottle
500 mg in amber glass bottleApplicationVersatile catalyst for reactions including the Mannich reaction.ПараметрыQuality Level 100, assay 97% optical activity []20/D -57.0°, c = 1 in chloroform mp 147-152 °C SMILES string CN(Cc1ccccc1)C(=O)[C@@H](NC(=S)Nc2cc(cc(c2)C(F)(F)F)C(F)(F)F)C(C)(C)C InChI 1S/C23H25F6N3OS/c1-21(2,3)18(19(33)32(4)13-14-8-6-5-7-9-14)31-20(34)30-17-11-15(22(24,25)26)10-16(12-17)23(27,28)29/h5-12,18H,13H2,1-4H3,(H2,30,31,34)/t18-/m1/s1 Inchi Key LTFFYVVCUVYZPE-GOSISDBHSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 + H312 - H315 - H319 - H335 - H413 pcodes P273 - P280 - P301 + P312 + P330 - P302 + P352 + P312 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-3,3-Bis(2,4,6-triisopropylphenyl)-1,1-bi-2-naphthol
Empirical Formula (Hill Notation): C50H58O2 CAS Number: 908338-44-3 Molecular Weight: 690.99 MDL number: MFCD11045378 PubChem Substance ID: 329761305 NACRES: NA.22
Кат. номер 690007-500MG 690007-100MG Application(S)-3,3-Bis(2,4,6-triisopropylphenyl)-1,1-bi-2-naphthol can be used as a reactant to prepare BINOL-based chiral N-triflyl thiophosphoramides as chiral Bronsted acid catalysts for the asymmetric synthesis of -substituted cycloalkanones via enantioselective hydrolysis of alicyclic silyl enol ethers.Packaging100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 95% (HPLC) optical purity ee: 99.0 SMILES string CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2cc3ccccc3c(c2O)-c4c(O)c(cc5ccccc45)-c6c(cc(cc6C(C)C)C(C)C)C(C)C InChI 1S/C50H58O2/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47(49(43)51)48-38-20-16-14-18-34(38)22-44(50(48)52)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12/h13-32,51-52H,1-12H3 InChI key BCAHCEFAVPAFSH-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-3,3-Bis(2,4,6-triisopropylphenyl)-1,1-binaphthyl-2,2-diyl hydrogenphosphate
Empirical Formula (Hill Notation): C50H57O4P CAS Number: 874948-63-7 Molecular Weight: 752.96 MDL number: MFCD10567009 PubChem Substance ID: 329761289 NACRES: NA.22
Кат. номер 689785-500MG 689785-100MG General descriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.ApplicationVersatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.
Metal-Brnsted Acid Cooperative Catalysis for Asymmetric Reductive Amination,Packaging100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.ПараметрыQuality Level 100, assay 97.0% (qNMR) greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry,.SMILES string CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2cc3ccccc3c-4c2OP(O)(=O)Oc5c(cc6ccccc6c-45)-c7c(cc(cc7C(C)C)C(C)C)C(C)C InChI 1S/C50H57O4P/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(50(48)54-55(51,52)53-49(43)47)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12/h13-32H,1-12H3,(H,51,52) InChI key AGQAQYPGJDBIQR-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-3,3-Bis(4-trifluoromethylphenyl)-1,1-binaphthyl-2,2-disulfonimide
Empirical Formula (Hill Notation): C34H19F6NO4S2 Molecular Weight: 683.64 MDL number: MFCD28016338 PubChem Substance ID: 329768244 NACRES: NA.22
Кат. номер 790850-500MG 790850-100MG ApplicationChiral Bronsted acid used in allylation of imines.
A Powerful Chiral Counteranion Motif for Asymmetric Catalysis,Packaging100 mg in clear glass bottle
500 mg in amber glass bottleПараметрыreaction suitability reaction type: Aldol Reaction, reaction type: Allylation, reaction type: Carbonyl/Imine Addition, reaction type: Friedel-Crafts Alkylation Quality Level 100, mp 340-360 °C SMILES string O=S(C1=C(C2=C(C=CC=C3)C3=CC(C4=CC=C(C(F)(F)F)C=C4)=C2S5(=O)=O)C6=C(C=CC=C6)C=C1C7=CC=C(C(F)(F)F)C=C7)(N5)=O InChI 1S/C34H19F6NO4S2/c35-33(36,37)23-13-9-19(10-14-23)27-17-21-5-1-3-7-25(21)29-30-26-8-4-2-6-22(26)18-28(20-11-15-24(16-12-20)34(38,39)40)32(30)47(44,45)41-46(42,43)31(27)29/h1-18,41H InChI key FQLCMGCITBTGMR-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-3,3-Bis(triphenylsilyl)-1,1-binaphthyl-2,2-diyl hydrogenphosphate 680184-100MG
Empirical Formula (Hill Notation): C56H41O4PSi2 CAS Number: 929097-92-7 Molecular Weight: 865.07 MDL number: MFCD09265079 PubChem Substance ID: 24885544 NACRES: NA.22 Application(S)-3,3-Bis(triphenylsilyl)-1,1-binaphthyl-2,2-diyl hydrogenphosphate can be used as a catalyst:- In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.
- In the exo-selective cyclization of mupirocin methyl ester.
- In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.
Packaging100 mg in clear glass bottleПараметрыQuality Level 100, assay 96% optical activity []22/D +210°, c = 1 in chloroform mp 188-193 °C SMILES string OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11 InChI 1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58) Inchi Key BDQOCXQVIFQJRK-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-3,3-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1-binaphthyl-2,2-disulfonimide
Empirical Formula (Hill Notation): C36H17F12NO4S2 CAS Number: 1242421-77-7 Molecular Weight: 819.64 MDL number: MFCD28009151 PubChem Substance ID: 329768238 NACRES: NA.22
Кат. номер 790761-500MG 790761-100MG ApplicationChiral Bronsted acid demonstrated in Mukaiyama aldol reactions and Friedel-Crafts alkylation of indoles with sulfonyl imines.
A Powerful Chiral Counteranion Motif for Asymmetric Catalysis,
Chiral Sulfonimide as a Brnsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines,
Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination,Packaging100 mg in clear glass bottle
500 mg in amber glass bottleПараметрыQuality Level 100, assay 95% reaction suitability reaction type: Aldol Reaction, reaction type: Allylation, reaction type: Carbonyl/Imine Addition, reaction type: Friedel-Crafts Alkylation mp 325-330 °C SMILES string O=S(C1=C(C2=C(C=CC=C3)C3=CC(C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)=C2S5(=O)=O)C6=C(C=CC=C6)C=C1C7=CC(C(F)(F)F)=CC(C(F)(F)F)=C7)(N5)=O InChI 1S/C36H17F12NO4S2/c37-33(38,39)21-9-19(10-22(15-21)34(40,41)42)27-13-17-5-1-3-7-25(17)29-30-26-8-4-2-6-18(26)14-28(32(30)55(52,53)49-54(50,51)31(27)29)20-11-23(35(43,44)45)16-24(12-20)36(46,47)48/h1-16,49H InChI key DFXCMPXSCANWFA-UHFFFAOYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену
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