Catalysts

Volatile solid CVD precursor to tantalum nitride (TaN) thin films. Also yields tantalum oxide (Ta2O5) thin films when O2, H2O, NO or H2O2 is present during the deposition process. Ta2O5 thins films show promise as gate dielectric materials in the manufacture of integrated circuits.

5 g in glass bottle

Features and Benefits

Quality Level	100,
assay	99.99%
form	solid
reaction suitability	core: tantalum, reagent type: catalyst
mp	100 °C (dec.) (lit.)
SMILES string	CN(C)[Ta](N(C)C)(N(C)C)(N(C)C)N(C)C
InChI	1S/5C2H6N.Ta/c51-3-2;/h51-2H3;/q5*-1;+5
InChI key	VSLPMIMVDUOYFW-UHFFFAOYSA-N

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H228 - H260 - H314
pcodes	P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Supp Hazards	EUH014
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3132 / PGI
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pentamethylcyclopentadienyliridium(III) chloride,dimer

Empirical Formula (Hill Notation):	C₂₀H₃₀Cl₄Ir₂
CAS Number:	12354-84-6
Molecular Weight:	796.70
MDL number:	MFCD00075435
PubChem Substance ID:	24861924
NACRES:	NA.22

Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.
Metal-Brnsted Acid Cooperative Catalysis for Asymmetric Reductive Amination,
Development of GSK's reagent guides – embedding sustainability into reagent selection,

100, 500 mg in glass bottle

Quality Level	100,
assay	96%
reaction suitability	core: iridium, reagent type: catalyst
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
SMILES string	Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4ClH.2Ir/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
Inchi Key	JDOHSXHCQARCAW-UHFFFAOYSA-J

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis,
Catalyst for:

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pentamethylcyclopentadienylrhodium(III) chloride dimer

Empirical Formula (Hill Notation):	C₂₀H₃₀Cl₄Rh₂
Linear Formula:	[Rh(C₅Me₅)Cl₂]₂
CAS Number:	12354-85-7
Molecular Weight:	618.08
MDL number:	MFCD00061552
PubChem Substance ID:	24860540

Oxidative olefination reactions
C-C bond cleavage of secondary alcohols
Ortho C-H olefination of phenol derivatives
Oxidative annulation of pyridines
Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
Amidation reactions
Reductive alkylation reactions

Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:

Oxidative olefination reactions
C-C bond cleavage of secondary alcohols
Ortho C-H olefination of phenol derivatives
Oxidative annulation of pyridines
Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
Amidation reactions
Reductive alkylation reactions

1 g in glass bottle
250 mg in glass bottle

Quality Level	100,
assay	97%
reaction suitability	core: rhodium, reagent type: catalyst reaction type: C-Mannosylation
SMILES string	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
Inchi Key	QNIVKTTWBMFSBR-UHFFFAOYSA-J

Entry points into pentamethylcyclopentadienyl chemistry of ruthenium.

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315
pcodes	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pentamethylcyclopentadienylruthenium(III) chloride polymer

Linear Formula:	[C₁₀H₁₅Cl₂Ru]_n
CAS Number:	96503-27-4
MDL number:	MFCD00070449
PubChem Substance ID:	329755285
NACRES:	NA.22

1 g in glass bottle

reaction suitability	core: ruthenium, reaction type: solution phase peptide synthesis, reagent type: catalyst
SMILES string	Cl[Ru]Cl.Cl[Ru]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4ClH.2Ru/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
Inchi Key	VDXZXHGAMPUNED-UHFFFAOYSA-J

Hydrosilylation Catalysts,
Reagent use as catalyst precursors for carbon-carbon or carbon-heteroatom bond forming reactions.
A versatile catalyst for hydrosilylation of alkynes providing α-vinylsilanes.

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) hexafluorophosphate

Empirical Formula (Hill Notation):	C₁₆H₂₄N₃PRuF₆
CAS Number:	99604-67-8
Molecular Weight:	504.42
MDL number:	MFCD08457650
PubChem Substance ID:	24884913
NACRES:	NA.22

250 mg in glass bottle

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
storage temp.	2-8°C
SMILES string	[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C
InChI	1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;31-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;31H3;;/q;;;;-1;+1
InChI key	IYEMDYLFXFMECZ-UHFFFAOYSA-N

Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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PEPPSI™-IPr catalyst

Empirical Formula (Hill Notation):	C₃₂H₄₀Cl₃N₃Pd
CAS Number:	905459-27-0
Molecular Weight:	679.46
MDL number:	MFCD08457656
PubChem Substance ID:	24884825
NACRES:	NA.22

Catalyst for Kumada-Tamao-Corriu (KTC) reaction (eq. 1)
Catalyst for Negishi coupling reaction (eq. 2)
Catalyst for Suzuki coupling reaction (eq. 3)
Catalyst for Buchwald-Hartwig amination reaction (eq. 4)

1, 5 g in glass bottle
250 g in poly bottle
1 kg in poly bottle

Product of Umicore
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyers use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com,
Patented, U.S. Pat. No. 7,250,510. Sold under an exclusive license from Total Synthesis Ltd.
PEPPSI is a trademark of Total Synthesis Ltd.

Quality Level	200,
assay	98%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Торговая марка	Umicore
mp	230 °C
SMILES string	Cl[Pd]Cl.Clc1cccnc1.CC(C)c2cccc(C(C)C)c2N3CN(C=C3)c4c(cccc4C(C)C)C(C)C
InChI	1S/C27H38N2.C5H4ClN.2ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;6-5-2-1-3-7-4-5;;;/h9-16,18-21H,17H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2
InChI key	BLDKGTGQENJFON-UHFFFAOYSA-L

Application Guide for Palladium Catalyzed Cross-Coupling Reactions,
Catalyst for C-C and C-N coupling reactions.

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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PEPPSI™-SIPr catalyst

Empirical Formula (Hill Notation):	C₃₂H₄₂Cl₃N₃Pd
CAS Number:	927706-57-8
Molecular Weight:	681.47
PubChem Substance ID:	24885231
NACRES:	NA.22

1, 5 g in glass bottle

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
Торговая марка	Umicore
mp	229-230 °C
SMILES string	Cl[Pd]Cl.Clc1cccnc1.CC(C)c2cccc(C(C)C)c2N3[CH]N(CC3)c4c(cccc4C(C)C)C(C)C
InChI	1S/C27H39N2.C5H4ClN.2ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;6-5-2-1-3-7-4-5;;;/h9-14,17-21H,15-16H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2
InChI key	BWASJRFNPJXAGT-UHFFFAOYSA-L

It is also used to prepare highly conducting and superconducting synthetic metals.

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Perrhenic acid solution

Empirical Formula (Hill Notation):	HO₄Re
Linear Formula:	HReO₄
CAS Number:	13768-11-1
Molecular Weight:	251.21
MDL number:	MFCD00011326
PubChem Substance ID:	24855847
NACRES:	NA.22

Perrhenic acid solution (HReO4) can be used in dehydrations of oximes, amides, and urea.
HReO4 can also catalyze azeotropic dehydration of syn- or anti-aldoximes to yield corresponding nitriles.
In combination with tertiary arsines, it gives a versatile catalytic system for epoxidation of alkenes with hydrogen peroxide.

5, 25 g in poly bottle

Quality Level	100,
reaction suitability	core: rhenium, reagent type: catalyst
concentration	75-80 wt. % in H₂O
density	2.16 g/mL at 25 °C
SMILES string	O[Re](=O)(=O)=O
InChI	1S/H2O.3O.Re/h1H2;;;;/q;;;;+1/p-1
InChI key	UGSFIVDHFJJCBJ-UHFFFAOYSA-M

This phenoxazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst 901112,) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with the Miyake, Research Group.

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
RIDADR	UN 3264 8 / PGII
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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901112-100MG

PhenN O-PC™ B0301 901112-100MG

Empirical Formula (Hill Notation): C₃₂H₂₂N₂

CAS Number: 1934269-97-2

Molecular Weight: 434.53

Application
This dihydrophenazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst 901111,) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with the Miyake, Research Group.
Packaging
100 mg in amber glass bottle
Other Notes
Strongly Reducing Visible Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals,
Organocatalyzed Atom Transfer Radical Polymerization Driven by Visible Light,
Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts,
Intramolecular Charge Transfer and Ion Pairing in N, N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization,
Legal Information
Patent application PCT/US2016/058245. Sold in collaboration with New Iridium Inc. For orders greater than 25g, please contact New Iridium at chern@newiridium.com or visit https://www.newiridium.com.
PhenN O-PC is a trademark of New Iridium Inc.
Phenox O-PC is a trademark of New Iridium LLC
Параметры

Quality Level 100,

assay 97%

form powder or crystals

reaction suitability reagent type: catalyst
reaction type: Photocatalysis

photocatalyst activation 460 nm

Safety Information

pictograms GHS07

signalword Warning

hcodes H302

pcodes P301 + P312 + P330

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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Phenox O-PC™ A0202

Empirical Formula (Hill Notation):	C₄₆H₃₁NO
CAS Number:	1987900-95-7
Molecular Weight:	613.74

Strongly Reducing Visible Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals,
Organocatalyzed Atom Transfer Radical Polymerization Driven by Visible Light,
Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts,
Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization,

Patent application PCT/US2016/058245. Sold in collaboration with New Iridium Inc. For orders greater than 25g, please contact New Iridium at chern@newiridium.com or visit https://www.newiridium.com.
Phenox O-PC is a trademark of New Iridium LLC

Quality Level	100,
assay	97%
form	powder or crystals
reaction suitability	reagent type: catalyst reaction type: Photocatalysis
mp	171 °C
photocatalyst activation	400 nm
SMILES string	C1(C=CC(C2=CC=C(C3=CC=CC=C3)C=C2)=C4)=C4OC(C=C(C5=CC=C(C6=CC=CC=C6)C=C5)C=C7)=C7N1C8=C(C=CC=C9)C9=CC=C8

Phenylphosphonic dichloride (PPDC) is an organophosphorus compound with flame-retardant properties.
It can be used:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Phenylphosphonic dichloride

Empirical Formula (Hill Notation):	C₆H₅Cl₂OP
Linear Formula:	C₆H₅POCl₂
CAS Number:	824-72-6
Molecular Weight:	194.98
Beilstein/REAXYS Number:	1072240
EC Number:	212-534-3
MDL number:	MFCD00002070
PubChem Substance ID:	24864291
NACRES:	NA.22

In the synthesis of PBPP (3,9-diphenyl-3,9-dioxa-2,4,8,10-tetraoxa-3,9-diphosphaspiro-5,5-undecane), another organo-phosphorus flame retardant.
As a reactant in the synthesis of perfluoroalkyl(phenyl)phosphinic acids from perfluoroalkyl Grignard reagents.
As a starting material for the synthesis of benzoxazine monomer containing phenylphosphine oxide which can be polymerized via ring-opening polymerization.
As a chlorinating agent for the conversion of thienopyrimidinedione into 4,6-dichlorothienopyrimidine.

100, 500 mL in glass bottle

grade	technical grade
Quality Level	100,
assay	90%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index	n20/D 1.559 (lit.)
bp	258 °C (lit.)
mp	3 °C (lit.)
density	1.375 g/mL at 25 °C (lit.)
functional group	phosphine
SMILES string	ClP(Cl)(=O)c1ccccc1
InChI	1S/C6H5Cl2OP/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
Inchi Key	IBDMRHDXAQZJAP-UHFFFAOYSA-N

Red phosphorus is the most common allotrope of phosphorus. It exists in an amorphous form and found to be more stable than white phosphorus. It is used in organic synthesis and chemical warfare including igniters, incendiaries, screening smoke ammunition and smoke signal. Red phosphorus is also used as a flame retardant in many thermoplastics and thermosetting plastics.

pictograms	GHS05,GHS07
signalword	Danger
hcodes	H302 - H314 - H335
pcodes	P261 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
Target Organs	Respiratory system
Supp Hazards	EUH014
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3265 8 / PGII
WGK Germany	WGK 3
Flash Point F	399.2 °F
Flash Point C	204 °C

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Phosphorus, red

Empirical Formula (Hill Notation):	P
CAS Number:	7723-14-0
Molecular Weight:	30.97
EC Number:	231-768-7
MDL number:	MFCD00133771
PubChem Substance ID:	57646724
NACRES:	NA.22

Red phosphorus can be used as a:

Photocatalyst for the formation of H2 from water.
Catalyst in the synthesis of tris(2-pyridyl)phosphine by reacting with 2-bromopyridine in the presence of a base.
Flame retardant along with aluminum oxide in recycled poly(ethylene terephthalate).
Anode material in combination with carbon composites for sodium-ion batteries.

vapor density	0.02 (vs air)
Quality Level	100,
vapor pressure	0.03 mmHg ( 21 °C), 1 mmHg ( 76.6 °C)
assay	≥97.0%
autoignition temp.	500 °F
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reagent type: ligand
resistivity	10 μΩ-cm, 20°C
mp	416 °C (subl.) (lit.)
density	2.34 g/mL at 25 °C (lit.)
cation traces	Fe: ≤2000 mg/kg
functional group	phosphine
storage temp.	2-8°C
SMILES string	[P]
InChI	1S/P
InChI key	OAICVXFJPJFONN-UHFFFAOYSA-N

pictograms	GHS02
signalword	Warning
hcodes	H228 - H412
pcodes	P210 - P240 - P241 - P273 - P280 - P370 + P378
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN1338 - class 4.1 - PG 3 - Phosphorus, amorphous
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Phthalocyanine green CDS000384-1G

Empirical Formula (Hill Notation):	C₃₂Cl₁₆CuN₈
CAS Number:	14832-14-5
Molecular Weight:	1127.19
EC Number:	215-524-7
MDL number:	MFCD00053950
PubChem Substance ID:	329777727

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

reaction suitability	core: copper, reagent type: catalyst
SMILES string	Clc1c(Cl)c(Cl)c2c3nc(nc4n5[Cu]n6c(n3)c7c(Cl)c(Cl)c(Cl)c(Cl)c7c6nc8nc(nc5c9c(Cl)c(Cl)c(Cl)c(Cl)c49)c%10c(Cl)c(Cl)c(Cl)c(Cl)c8%10)c2c1Cl
InChI	1S/C32Cl16N8.Cu/c33-9-1-2(10(34)18(42)17(9)41)26-49-25(1)53-27-3-4(12(36)20(44)19(43)11(3)35)29(50-27)55-31-7-8(16(40)24(48)23(47)15(7)39)32(52-31)56-30-6-5(28(51-30)54-26)13(37)21(45)22(46)14(6)38;/q-2;+2
InChI key	ABFKYPFPQRDCGM-UHFFFAOYSA-N

Platinum nanopowder has a high catalytic activity and is used widely in catalysis, batteries, fuel cells, capacitors and sensors. They are used in the synthesis of counter electrode in dyes sensitized solar cells. Since it is difficult to directly use platinum nanoparticle as the electrode, they are usually surface supported on graphene or multi-walled carbon nanotubes.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum 771937-250MG

Empirical Formula (Hill Notation):	Pt
CAS Number:	7440-06-4
Molecular Weight:	195.08
EC Number:	231-116-1
MDL number:	MFCD00011179
PubChem Substance ID:	329767526
NACRES:	NA.23

General description

Nanoscale platinum powders possess improved reaction rates compared to bulk powders owing to their high surface area. Platinum nanopowders have found use in applications including in fuel cells and oxidation catalysts.

High catalytic functionality, high conductivity and chemical stability in an acid-base environment.

250 mg in glass bottle

Features and Benefits

Quality Level	100,
assay	99.9% (metals basis)
form	nanopowder
reaction suitability	reagent type: catalyst core: platinum
resistivity	10.6 µ-cm, 20°C
particle size	200 nm (SEM)
bp	3827 °C (lit.)
mp	1772 °C (lit.)
density	21.45 g/cm³ (lit.)
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

Platinum black can be used as a catalyst to facilitate the electrochemical reactions in proton exchange membrane (PEM) fuel cells. These fuel cells are promising candidates as a clean and energy efficient power source.
Platinum black (black, powder, ≤20 μm) can be electroplated on implantable microelectrode arrays (MEAs) to improve the impedence of the device. It can also be used as a microelectrode for the formation of a microfluidic electrochemical sensor for glucose sensing applications. It can be used as a photocathode for the production of hydrogen.

pictograms	GHS02
signalword	Danger
hcodes	H228
pcodes	P210 - P240 - P241 - P280 - P370 + P378
RIDADR	UN 3089 4.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum black

Empirical Formula (Hill Notation):	Pt
CAS Number:	7440-06-4
Molecular Weight:	195.08
EC Number:	231-116-1
MDL number:	MFCD00011179
PubChem Substance ID:	24852362
NACRES:	NA.22

250 mg in glass bottle
1, 5 g in glass bottle

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here,.

Quality Level	200,
assay	99.95% trace metals basis
form	powder
reaction suitability	core: platinum, reagent type: catalyst
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
particle size	20 µm
surface area	~25 m²/g
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum cobalt on carbon 738565-1G

Empirical Formula (Hill Notation):	CoPt₃
Molecular Weight:	644.17
PubChem Substance ID:	329765288

form	powder
Quality Level	100,
reaction suitability	reagent type: catalyst core: platinum
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	30 wt. % Pt₃Co loading
particle size	<5 nm (Pt)
InChI	1S/Co.3Pt
Inchi Key	GUBSQCSIIDQXLB-UHFFFAOYSA-N

Platinum on alumina (Pt/Al2O3) (5 wt. % loading, powder) can be used as a catalyst for a variety of applications, such as:

pictograms	GHS02,GHS08
signalword	Danger
hcodes	H228 - H317 - H334
pcodes	P210 - P240 - P241 - P261 - P280 - P302 + P352
RIDADR	UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 3

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Platinum on alumina

MDL number:	MFCD00011179
PubChem Substance ID:	24852367
NACRES:	NA.22

in the hydrodechlorination of chlorobenzenes
oxidation, reduction, and decomposition
in methanol steam reforming
hydrocarbon combustion

10, 50 g in poly bottle

form	powder
Quality Level	100,
reaction suitability	core: platinum, reagent type: catalyst
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	5 wt. % loading
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

Catalyst used for the hydrogenation of alkenes, alkynes, nitro groups, ketones, aromatics; used for hydrogenolysis of cyclopropanes; catalyzes oxidation of alcohols.
Platinum on carbon (Pt/C) can be used as a catalyst for a variety of applications, such as:

pictograms	GHS02
signalword	Danger
hcodes	H228
pcodes	P210 - P240 - P241 - P280 - P370 + P378
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum on carbon

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179
PubChem Substance ID:	24852365
NACRES:	NA.22

hydrosilylation reaction for the production of molecules with silicon-carbon bonds
direct alcohol fuel cells (DAFCs)
an electrocatalyst in hydrogen evolution reaction (HER)
formation of nanocatalyst for polymer electrolyte fuel cells

1, 10, 50 g in glass bottle

Quality Level	200,
reaction suitability	core: platinum, reagent type: catalyst
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	10 wt. % loading
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum on carbon 907812-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P2086 10% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

oxidation of alcohols and sugars
selective hydrogenation of aryl nitroalkanes in the presence of halogens
hydrogenation of aldehydes and ketones

Note: Unit weight is of net dry catalyst.

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~50% water
extent of labeling	10 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 907898-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P8078 1% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of aromatic nitro groups in the presence of halogens and other functional groups

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~60% water
extent of labeling	1 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

WGK 2

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Platinum on carbon 908010-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P8077 5% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

oxidation of alcohols and sugars

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~50% water
extent of labeling	5 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 908150-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P2060 5% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of imines
hydrogenation of aliphatic nitro groups

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~50% water
extent of labeling	5 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 908088-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P2065 3% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of aromatic nitro groups to hydroxylamines
hydrogenation of aldehydes and ketones

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~60% water
extent of labeling	3 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 908037-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P2061 5% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of imines
hydrogenation of aromatic nitro groups
hydrogenation of alkenes and alkynes
hydrogenation of nitriles
hydrogenation of hydrazones
hydrogenation of aldehydes and ketones

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~50% water
extent of labeling	5 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 908053-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P2058 5% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of aromatic nitro groups
hydrogenation of hydrazones
hydrogenation of aromatic carbonyls to alcohols
hydrogenation of nitriles

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

form	powder
contains	~60% water
extent of labeling	5 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 908169-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P2057 3% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of aromatic nitro groups

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

form	powder
contains	~60% water
extent of labeling	3 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

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Platinum on carbon 907820-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P8075 1% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of aromatic nitro groups in halonitroaromatics

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

contains	~50% water
extent of labeling	1 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

WGK 2

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Platinum on carbon 907952-10G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179

Evonik Noblyst® P8071 2% Pt is a platinum on carbon catalyst. It has been shown to be effective in the following reactions:

hydrogenation of aromatic nitro groups in the presence of halogens and other functional groups

Manufactured by Evonik Degussa GmbH.
Noblyst is a registered trademark of Evonik Degussa GmbH

form	powder
contains	~60% water
extent of labeling	2 wt. % loading (dry basis)
weight	Unit weight excludes weight of water
matrix	activated carbon support
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

WGK 2

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Platinum on graphitized carbon 738557-1G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179
PubChem Substance ID:	329765287
NACRES:	NA.23

Platinum on graphitized carbon (40% Pt/Vulcan XC72) is a high surface area material that is used as an electrocatalyst for the development of electrolytic fuel cells and direct methanol fuel cells. It can also be used in the formation of a non-enzymatic sensor for the oxidation of glucose.

form	powder
Quality Level	100,
reaction suitability	reagent type: catalyst core: platinum
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	40 wt. % loading
particle size	<5 nm (Pt)
SMILES string	[Pt]
InChI	1S/Pt
InChI key	BASFCYQUMIYNBI-UHFFFAOYSA-N

pictograms	GHS02
signalword	Danger
hcodes	H228
pcodes	P210 - P240 - P241 - P280 - P370 + P378
RIDADR	UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 3

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Platinum on graphitized carbon 738581-1G

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179
PubChem Substance ID:	329765290
NACRES:	NA.23

General description

Platinum on graphitized carbon (10% Pt/Vulcan XC72) is a high surface area material that is used as an electrocatalyst for the development of electrolytic fuel cells and direct methanol fuel cells. It can also be used in the formation of a non-enzymatic sensor for the oxidation of glucose.

1 g in glass bottle

form	powder
Quality Level	100,
reaction suitability	reagent type: catalyst core: platinum
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	10 wt. % loading
particle size	<5 nm (Pt)
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex is a platinum complex, commonly known as a Karstedt′s catalyst. It is generally employed as a catalyst in hydrosilylation reactions.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution

Empirical Formula (Hill Notation):	C₈H₁₈OPtSi₂
Linear Formula:	O[Si(CH₃)₂CH=CH₂]₂Pt
CAS Number:	68478-92-2
Molecular Weight:	381.48
MDL number:	MFCD00151662
PubChem Substance ID:	24871623
NACRES:	NA.22

Hydrosilylation Catalysts,
A powerful hydrosilylation catalyst for preparation of trans--silanes.

5, 25, 250 g in glass bottle

vapor pressure	7 mmHg ( 21 °C)
Quality Level	200,
composition	Pt, ~2%
reaction suitability	core: platinum, reagent type: catalyst
concentration	in xylene
bp	138 °C
mp	12-13 °C
density	0.855 g/mL at 25 °C
SMILES string	[Pt].C[Si](C)(O[Si](C)(C)C=C)C=C
InChI	1S/C8H18OSi2.Pt/c1-7-10(3,4)9-11(5,6)8-2;/h7-8H,1-2H2,3-6H3;
InChI key	RCNRJBWHLARWRP-UHFFFAOYSA-N

pictograms	GHS02,GHS07,GHS08
signalword	Danger
hcodes	H226 - H304 - H312 + H332 - H315 - H319 - H335 - H373 - H412
pcodes	P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P331
Target Organs	Respiratory system
RIDADR	UN1307 - class 3 - PG 3 - Xylenes
WGK Germany	WGK 3
Flash Point F	77.0 °F
Flash Point C	25 °C

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Platinum(0)-2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane complex solution

Empirical Formula (Hill Notation):	C₁₂H₂₄O₄PtSi₄
CAS Number:	68585-32-0
Molecular Weight:	539.74
EC Number:	271-555-6
MDL number:	MFCD00166503
PubChem Substance ID:	24871627
NACRES:	NA.22

Quality Level	100,
reaction suitability	core: platinum, reagent type: catalyst
concentration	0.104 M in methylvinylcyclosiloxanes
bp	207 °C
density	1.017 g/mL at 25 °C
SMILES string	[Pt].C[Si]1(O[Si](C)(O[Si](C)(O[Si](C)(O1)C=C)C=C)C=C)C=C
InChI	1S/C12H24O4Si4.Pt/c1-9-17(5)13-18(6,10-2)15-20(8,12-4)16-19(7,11-3)14-17;/h9-12H,1-4H2,5-8H3;
Inchi Key	PIZSEPSUZMIOQF-UHFFFAOYSA-N

Platinum (II) chloride is a catalyst used for a variety of C-C bond, C-O bond, and C-N bond formation.
Platinum (II) chloride can be used to catalyze the cyclization of 1(indole2yl)2,3allenols to form polysubstituted carbazoles. It is also used in studies involving metalation of aromatic compounds.

Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	233.6 °F - closed cup
Flash Point C	112 °C - closed cup

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Platinum(II) chloride

Empirical Formula (Hill Notation):	Cl₂Pt
Linear Formula:	PtCl₂
CAS Number:	10025-65-7
Molecular Weight:	265.98
MDL number:	MFCD00011181
eCl@ss:	38191303
PubChem Substance ID:	24852376
NACRES:	NA.22

250 mg in glass bottle
1, 5 g in glass bottle

Quality Level	100,
assay	98%
reaction suitability	core: platinum, reagent type: catalyst
mp	581 °C (dec.) (lit.)
density	6.05 g/mL at 25 °C
SMILES string	Cl[Pt]Cl
InChI	1S/2ClH.Pt/h2*1H;/q;;+2/p-2
InChI key	CLSUSRZJUQMOHH-UHFFFAOYSA-L

pictograms	GHS05,GHS08
signalword	Danger
hcodes	H314 - H317 - H334
pcodes	P260 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3260 8 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum(II) chloride 482315-1G

Empirical Formula (Hill Notation):	Cl₂Pt
Linear Formula:	PtCl₂
CAS Number:	10025-65-7
Molecular Weight:	265.98
MDL number:	MFCD00011181
PubChem Substance ID:	24871820
NACRES:	NA.23

Quality Level	100,
assay	99.99% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: platinum
impurities	150.0 ppm Trace Metal Analysis
mp	581 °C (dec.) (lit.)
density	5.87 g/mL at 25 °C
SMILES string	Cl[Pt]Cl
InChI	1S/2ClH.Pt/h2*1H;/q;;+2/p-2
Inchi Key	CLSUSRZJUQMOHH-UHFFFAOYSA-L

Platinum(IV) oxide has been used for the reduction of citernyl bromide to form (S)-3,7-dimethyloctylbromide.
Catalyst for hydrogenation of various functional groups with minimal hydrogenolysis problems; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.
Catalyst for:

pictograms	GHS05,GHS08
signalword	Danger
hcodes	H314 - H317 - H334
pcodes	P260 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3260 8 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum(IV) oxide

Empirical Formula (Hill Notation):	O₂Pt
Linear Formula:	PtO₂
CAS Number:	1314-15-4
Molecular Weight:	227.08
EC Number:	215-223-0
MDL number:	MFCD00011184
PubChem Substance ID:	24852371
NACRES:	NA.22

Hydrohydrazination reactions
Oxidation of sugars
Low-temperature oxidation of carbon monoxide
Oxygen reduction reaction
Hydrogenation reactions
Hydrogenolysis of the cyclopropyl group into an isopropyl group
Hydroxycyclopropanation reactions

250 mg in glass bottle
1, 5, 50 g in glass bottle

composition	Pt, 81-83%
Quality Level	200,
reaction suitability	core: platinum, reagent type: catalyst
greener alternative product characteristics	Designing Safer Chemicals Catalysis Learn more about the Principles of Green Chemistry,.
surface area	60 m²/g
mp	450 °C (lit.)
greener alternative category	Aligned,
SMILES string	O=[Pt]=O
InChI	1S/2O.Pt
Inchi Key	YKIOKAURTKXMSB-UHFFFAOYSA-N

pictograms	GHS03,GHS07
signalword	Danger
hcodes	H272 - H319
pcodes	P210 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 1479 5.1 / PGII
WGK Germany	WGK 2

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Platinum(IV) oxide hydrate

Empirical Formula (Hill Notation):	O₂Pt · xH₂O
Linear Formula:	PtO₂ · xH₂O
CAS Number:	52785-06-5
Molecular Weight:	227.08 (anhydrous basis)
EC Number:	215-223-0
MDL number:	MFCD00011184
PubChem Substance ID:	24874152
NACRES:	NA.22

1, 5 g in glass bottle

Catalyst for hydrogenation and hydrogenolysis of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.

Quality Level	100,
assay	≥99.9%
composition	Pt, 77-81%
reaction suitability	core: platinum, reagent type: catalyst
mp	450 °C (lit.)
SMILES string	O=[Pt]=O
InChI	1S/2O.Pt
Inchi Key	YKIOKAURTKXMSB-UHFFFAOYSA-N

pictograms	GHS03,GHS07
signalword	Danger
hcodes	H272 - H319
pcodes	P210 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 1479 5.1 / PGII
WGK Germany	WGK 2

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Platinum, nanoparticle dispersion 773875-25ML

Empirical Formula (Hill Notation):	Pt
Molecular Weight:	195.08
MDL number:	MFCD00011179
PubChem Substance ID:	329767643
NACRES:	NA.23

Platinum nanoparticles are used in several important catalytic applications including fuel cells and photocatalysts. Platinum nanocrystal arrays have also been studied as nonvolatile memory systems.

25 mL in Sure/Seal™

Quality Level	100,
assay	99.99% trace metals basis
form	dispersion, nanoparticle
reaction suitability	reagent type: catalyst core: platinum
concentration	1,000 ppm in H₂O
particle size	3 nm
density	0.997 g/mL at 25 °C
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

1, 10, 50 g in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	No data available
Flash Point C	No data available

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Platinum, sulfided, on carbon

MDL number:	MFCD00011179
PubChem Substance ID:	24852368
NACRES:	NA.22

form	dry
Quality Level	100,
reaction suitability	core: platinum, reagent type: catalyst
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	5 wt. % loading
matrix	carbon, reduced support
SMILES string	[Pt]
InChI	1S/Pt
Inchi Key	BASFCYQUMIYNBI-UHFFFAOYSA-N

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Platinum-ruthenium alloy on graphitized carbon 738573-1G

Linear Formula:	Pt/Ru
MDL number:	MFCD00798552
PubChem Substance ID:	329765289
NACRES:	NA.23

Platinum-ruthenium alloy on graphitized carbon (30% Pt-Ru/Vulcan) can be used as an electrocatalyst for the fabrication of direct methanol fuel cells (DMFC) and proton exchange membrane (PEM) based fuel cells.

form	powder
Quality Level	100,
reaction suitability	reagent type: catalyst core: platinum
greener alternative product characteristics	Design for Energy Efficiency Learn more about the Principles of Green Chemistry,.
extent of labeling	20 wt. % Pt loading, 10 wt. % Ru loading
particle size	<5 nm (Pt)
SMILES string	[Ru].[Pt]
InChI	1S/Pt.Ru
InChI key	CFQCIHVMOFOCGH-UHFFFAOYSA-N

pictograms	GHS02
signalword	Danger
hcodes	H228
pcodes	P210 - P240 - P241 - P280 - P370 + P378
RIDADR	UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Potassium 5-bromo-1H-indole-1-carbodithioate

Empirical Formula (Hill Notation): C₉H₅BrKNS₂

Molecular Weight: 310.28

Кат. номер

907502-100MG

907502-250MG

Application
Potassium 5-bromo-1H-indole-1-carbodithioate is an organic photocatalyst shown to activate alkyl electrophiles via an SN2 pathway.
Other Notes
Photochemical generation of radicals from alkyl electrophiles using a nucleophilic organic catalyst,
Параметры

assay 95%

form powder or crystals

reaction suitability reaction type: Photocatalysis, reagent type: catalyst

mp 179-185 °C

storage temp. 2-8°C

Safety Information

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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Potassium diphenylphosphide solution

Empirical Formula (Hill Notation):	C₁₂H₁₀KP
Linear Formula:	(C₆H₅)₂PK
CAS Number:	15475-27-1
Molecular Weight:	224.28
Beilstein/REAXYS Number:	4164304
MDL number:	MFCD00134530
PubChem Substance ID:	24863767
NACRES:	NA.22

Quality Level	100,
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
concentration	0.5 M in THF
density	0.929 g/mL at 25 °C
functional group	phosphine
SMILES string	[K]P(c1ccccc1)c2ccccc2
InChI	1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
InChI key	FCLYZQXPJKJTDR-UHFFFAOYSA-N

Potassium hexachloroplatinate(IV) can be used as a reactant to synthesize compounds such as chloropentaammineplatinum(IV), platinum triselenide, trans-dichloro(ethylenediamine-N,N-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N-di-3-propanoato)platinum(IV) complexes.

pictograms	GHS02,GHS05,GHS07,GHS08
signalword	Danger
hcodes	H225 - H302 - H314 - H335 - H351
pcodes	P201 - P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Target Organs	Respiratory system
Supp Hazards	EUH018 - EUH019
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point F	-4.0 °F - closed cup
Flash Point C	-20 °C - closed cup

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Potassium hexachloroplatinate(IV)

Empirical Formula (Hill Notation):	Cl₆K₂Pt
Linear Formula:	K₂PtCl₆
CAS Number:	16921-30-5
Molecular Weight:	485.99
EC Number:	240-979-3
MDL number:	MFCD00011389
PubChem Substance ID:	24874176
NACRES:	NA.22

1, 5 g in glass bottle

Quality Level	100,
assay	≥99.9% trace metals basis
composition	Pt, 38-41%
reaction suitability	core: platinum, reagent type: catalyst
mp	250 °C (dec.) (lit.)
SMILES string	[K+].[K+].Cl[Pt--](Cl)(Cl)(Cl)(Cl)Cl
InChI	1S/6ClH.2K.Pt/h61H;;;/q;;;;;;2+1;+4/p-6
Inchi Key	DPAIVKJGTXERIM-UHFFFAOYSA-H

pictograms	GHS05,GHS06,GHS08,GHS09
signalword	Danger
hcodes	H290 - H301 - H318 - H334 - H372 - H410
pcodes	P234 - P273 - P280 - P301 + P310 - P304 + P340 + P312 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN3290 - class 6.1 - PG 2 - acidic - Toxic solid, corrosive, inorganic, n.o.s., HI: all
WGK Germany	WGK 1
Flash Point F	does not flash
Flash Point C	does not flash

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Potassium hexacyanochromate(III) 473448-1G

Empirical Formula (Hill Notation):	C₆CrK₃N₆
Linear Formula:	K₃Cr(CN)₆
CAS Number:	13601-11-1
Molecular Weight:	325.40
EC Number:	237-079-8
MDL number:	MFCD00049670
PubChem Substance ID:	24870905
NACRES:	NA.23

Quality Level	100,
assay	99.99% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: chromium
impurities	150.0 ppm Trace Metal Analysis
mp	>350 °C (lit.)
SMILES string	[K+].[K+].[K+].N#C[Cr-3](C#N)(C#N)(C#N)(C#N)C#N
InChI	1S/6CN.Cr.3K/c61-2;;;;/q;;;;;;-3;3+1
Inchi Key	VOCDJOPDZZSPRQ-UHFFFAOYSA-N

Supp Hazards	EUH032
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Potassium tetraphenylborate

Empirical Formula (Hill Notation):	C₂₄H₂₀BK
Linear Formula:	(C₆H₅)₄BK
CAS Number:	3244-41-5
Molecular Weight:	358.32
MDL number:	MFCD03093877
PubChem Substance ID:	24870357

Quality Level	100,
assay	97%
reaction suitability	core: boron, reagent type: catalyst
mp	>300 °C (lit.)
SMILES string	[K+].c1ccc(cc1)[B-](c2ccccc2)(c3ccccc3)c4ccccc4
InChI	1S/C24H20B.K/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
InChI key	MAMCUZQNCMYPCY-UHFFFAOYSA-N

Potassium titanium oxide oxalate dihydrate can be used as a precursor to synthesize titanium dioxide (TiO2) nanoparticles.

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Potassium titanium oxide oxalate dihydrate

Empirical Formula (Hill Notation):	C₄K₂O₉Ti · 2H₂O
CAS Number:	14402-67-6
Molecular Weight:	354.13
EC Number:	238-475-3
MDL number:	MFCD00150592
PubChem Substance ID:	57647127
NACRES:	NA.22

1, 6×1 kg in poly bottle

Quality Level	100,
reaction suitability	core: titanium, reagent type: catalyst
SMILES string	O.O.[K+].[K+].[O-]C(=O)C(=O)O[Ti](=O)OC(=O)C([O-])=O
InChI	1S/2C2H2O4.2K.2H2O.O.Ti/c23-1(4)2(5)6;;;;;;/h2(H,3,4)(H,5,6);;;21H2;;/q;;2+1;;;;+2/p-4
InChI key	PGGRHIGITIPOBF-UHFFFAOYSA-J

Potassium trichloro(ethylene)platinate(II) hydrate is a transition-metal alkene complex commonly known as Zeise′s salt. It was first reported in the year 1930 and considered as a prototype for the classic Dewar-Chatt-Duncanson model.

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Potassium trichloro(ethylene)platinate(II) hydrate

Empirical Formula (Hill Notation):	C₂H₄Cl₃KPt · xH₂O
Linear Formula:	K[(H₂C=CH₂)PtCl₃] · xH₂O
CAS Number:	123334-22-5
Molecular Weight:	368.59 (anhydrous basis)
EC Number:	234-577-7
MDL number:	MFCD00150524
PubChem Substance ID:	24854720

500 mg in glass bottle

Quality Level	100,
composition	Degree of hydration, ≤1
reaction suitability	core: platinum, reagent type: catalyst
mp	220 °C (dec.) (lit.)
density	2.88 g/mL at 25 °C (lit.)
storage temp.	2-8°C
SMILES string	O.[K+].C=C.Cl[Pt-](Cl)Cl
InChI	1S/C2H4.3ClH.K.H2O.Pt/c1-2;;;;;;/h1-2H2;3*1H;;1H2;/q;;;;+1;;+2/p-3
Inchi Key	DCEGWIMEFFONKJ-UHFFFAOYSA-K

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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PPh3 Pd G2

Empirical Formula (Hill Notation):	C₃₀H₂₅ClNPPd
CAS Number:	847616-84-6
Molecular Weight:	572.37
MDL number:	MFCD20527202
PubChem Substance ID:	329766308
NACRES:	NA.22

Quality Level	100,
feature	generation 2
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	218-220 °C
SMILES string	Nc1ccccc1-c2ccccc2[Pd]Cl.c3ccc(cc3)P(c4ccccc4)c5ccccc5
InChI	1S/C18H15P.C12H10N.ClH.Pd/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h1-15H;1-6,8-9H,13H2;1H;/q;;;+1/p-1
Inchi Key	RNURSGDBDHOTOE-UHFFFAOYSA-M

Reactant involved in studies of:

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Protoporphyrin IX cobalt chloride

Empirical Formula (Hill Notation):	C₃₄H₃₂ClCoN₄O₄
Linear Formula:	C₃₄H₃₂CoN₄O₄Cl
CAS Number:	102601-60-5
Molecular Weight:	655.03
MDL number:	MFCD00216774
PubChem Substance ID:	329774912
NACRES:	NA.22

Enzyme models of hCBS heme group function
Electrocatalytic reduction of oxygen at electropolymerized films of porphyrins
Electrochemical redox behavior
Nitrogen(II) oxide coordination by metal porphyrins

100 mg in glass bottle

reaction suitability	core: cobalt, reagent type: catalyst
Quality Level	100,
storage temp.	2-8°C
SMILES string	Cc1c(CCC(O)=O)c2cc3c(CCC(O)=O)c(C)c4cc5nc(cc6c(C=C)c(C)c(cc1n2)n6[Co](Cl)n34)c(C)c5C=C
InChI	1S/C34H34N4O4.ClH.Co/c1-7-21-17(3)25-13-26-19(5)23(9-11-33(39)40)31(37-26)16-32-24(10-12-34(41)42)20(6)28(38-32)15-30-22(8-2)18(4)27(36-30)14-29(21)35-25;;/h7-8,13-16H,1-2,9-12H2,3-6H3,(H4,35,36,37,38,39,40,41,42);1H;/q;;+3/p-3/b25-13-,26-13-,27-14-,28-15-,29-14-,30-15-,31-16-,32-16-;;
Inchi Key	WWNXKQFLDNSNDN-HXFTUNQESA-K