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48

Bis(ethylcyclopentadienyl)tungsten(IV) dichloride 522430-1G

Empirical Formula (Hill Notation):	C₁₄H₁₈Cl₂W
CAS Number:	83136-76-9
Molecular Weight:	441.04
MDL number:	MFCD02093752
PubChem Substance ID:	24874273

Параметры

assay	97%
reaction suitability	core: tungsten, reagent type: catalyst
mp	156-160 °C (lit.)
SMILES string	CC[C]=12C3C4=C5C=1[W]23456789(Cl)(Cl)C%10C6=C7[C]8(CC)=C9%10
InChI	1S/2C7H9.2ClH.W/c21-2-7-5-3-4-6-7;;;/h23-6H,2H2,1H3;2*1H;/q;;;;+2/p-2
InChI key	JDKUBQXWTUJJBD-UHFFFAOYSA-L

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	3

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Bis(isopropylcyclopentadienyl)manganese 710490-1G

Empirical Formula (Hill Notation):	C₁₆H₂₂Mn
CAS Number:	85594-02-1
Molecular Weight:	269.28
MDL number:	MFCD01862453
PubChem Substance ID:	329762927
NACRES:	NA.22

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: manganese, reagent type: catalyst
density	1.090 g/cm³ at 25 °C
SMILES string	[Mn].CC(C)[C]1[CH][CH][CH][CH]1.CC(C)[C]2[CH][CH][CH][CH]2
InChI	1S/2C8H11.Mn/c21-7(2)8-5-3-4-6-8;/h23-7H,1-2H3;
Inchi Key	CRDYYRDPRXAYHD-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	230.0 °F - closed cup
Flash Point C	> 110 °C - closed cup

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Bis(methylcyclopentadienyl)nickel(II)

Empirical Formula (Hill Notation):	C₁₂H₁₄Ni
Linear Formula:	Ni(C₅H₄CH₃)₂
CAS Number:	1293-95-4
Molecular Weight:	216.93
MDL number:	MFCD01863654
PubChem Substance ID:	24873505

Reactant for synthesis of:

Nickel sandwich complexes
N-heterocyclic carbene complexes
Functionally substituted monocyclopentadienyl compounds

Packaging

1, 5 g in glass bottle

Features and Benefits

Volatile OMCVD precursor for the controlled growth of nickel nanoparticles on silicon substrates. Possible uses for metallic nickel nanoparticles embedded on silicon include the manufacture of high-density storage media 9. Nickel oxide thin films are generated via OMCVD in the presence of O2 or H2O2.

Параметры

Quality Level	100,
assay	97%
form	liquid
reaction suitability	core: nickel, reagent type: catalyst
bp	85-90 °C/1 mmHg (lit.)
mp	34-36 °C (lit.)
storage temp.	2-8°C
SMILES string	[Ni].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2
InChI	1S/2C6H7.Ni/c21-6-4-2-3-5-6;/h22-5H,1H3;
Inchi Key	IHRNDXJDUYVDRB-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	150.8 °F - closed cup
Flash Point C	66 °C - closed cup

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Bis(pentamethylcyclopentadienyl)cobalt(III) hexafluorophosphate

Empirical Formula (Hill Notation):	C₂₀H₃₀CoF₆P
CAS Number:	79973-42-5
Molecular Weight:	474.35
MDL number:	MFCD00269818
PubChem Substance ID:	24872851
NACRES:	NA.22

Spontaneous assembly of titanium and gallium bis(dihydroxybenzamido)naphthalene supramolecular tetranuclear cluster complexes
Preparation of cobaltocenium nickel bisdithiolene complexes
Metathesis reaction with potassium biphenoxide
Nucleophilic addition and single-electron reduction reactions

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	98%
reaction suitability	core: cobalt, reagent type: catalyst
mp	305 °C (dec.) (lit.)
SMILES string	[Co+].F[P-](F)(F)(F)(F)F.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.Co.F6P/c21-6-7(2)9(4)10(5)8(6)3;;1-7(2,3,4,5)6/h21-5H3;;/q;;+1;-1
Inchi Key	ILKSSYYMFRGBHO-UHFFFAOYSA-N

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
pcodes	P280 - P305 + P351 + P338 - P310
Supp Hazards	EUH014
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3260 8 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(salicylideniminato-3-propyl)methylaminocobalt(II) 360155-5G

Empirical Formula (Hill Notation):	C₂₁H₂₅CoN₃O₂
Linear Formula:	CH₃N[(CH₂)₃N=CHC₆H₄-2-(O)]₂Co
CAS Number:	15391-24-9
Molecular Weight:	410.38
MDL number:	MFCD00134174
PubChem Substance ID:	24862151
NACRES:	NA.22

Application

Catalyst for:

Biomimetic coupled catalytic system
Cobalt-Schiff base complex catalyzed oxidation of para-substituted phenolics
Allylation, oxidation, and oxidative cleavages
Oxidative carbonylation of phenol

Packaging

5 g in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: cobalt, reagent type: catalyst
mp	290-292 °C (lit.)
SMILES string	CN1CCC\N=C\c2ccccc2O[Co]Oc3ccccc3\C=N\CCC1
InChI	1S/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,25-26H,6-7,12-15H2,1H3;/q;+2/p-2/b22-16+,23-17+;
InChI key	BJSFADUIUGJFKX-VLQAMQNLSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(tert-butylimino)bis(dimethylamino)tungsten(VI) 577936-5G

Empirical Formula (Hill Notation):	C₁₂H₃₀N₄W
Linear Formula:	((CH₃)₃CN)₂W(N(CH₃)₂)₂
CAS Number:	406462-43-9
Molecular Weight:	414.23
MDL number:	MFCD07369712
PubChem Substance ID:	24880900
NACRES:	NA.23

Параметры

Quality Level	200,
assay	97%, 99.99% trace metals basis
form	liquid
reaction suitability	core: tungsten, reagent type: catalyst
bp	81 °C/0.02 mmHg (lit.)
density	1.305 g/mL at 25 °C (lit.)
SMILES string	CN(C)[W](=NC(C)(C)C)(=NC(C)(C)C)N(C)C
InChI	1S/2C4H9N.2C2H6N.W/c21-4(2,3)5;21-3-2;/h21-3H3;21-2H3;/q;;2*-1;+2
Inchi Key	JVCWKXBYGCJHDF-UHFFFAOYSA-N

Safety Information

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H260 - H314
pcodes	P223 - P231 + P232 - P280 - P302 + P335 + P334 - P303 + P361 + P353 - P305 + P351 + P338
Personal Protective Equipment	Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter,
RIDADR	UN 3398 4.3 / PGI
WGK Germany	WGK 3
Flash Point F	185.0 °F - closed cup
Flash Point C	85 °C - closed cup

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Bis(tri-tert-butylphosphine)palladium(0)

Empirical Formula (Hill Notation):	C₂₄H₅₄P₂Pd
CAS Number:	53199-31-8
Molecular Weight:	511.05
MDL number:	MFCD03094580
PubChem Substance ID:	24884857
NACRES:	NA.22

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here,.

Application

Catalyst for greener Heck reaction in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors,

Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)
Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
Catalyst for Negishi coupling reaction (eq. 3)
Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)

Packaging

250 mg in glass insert
1 g in glass bottle

Параметры

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry,.
mp	258-272 °C
storage temp.	20°C
SMILES string	[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI	1S/2C12H27P.Pd/c21-10(2,3)13(11(4,5)6)12(7,8)9;/h21-9H3;
Inchi Key	MXQOYLRVSVOCQT-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(tri-tert-butylphosphine)platinum(0)

Empirical Formula (Hill Notation):	C₂₄H₅₄P₂Pt
Linear Formula:	[((CH₃)₃C)₃P]₂Pt
CAS Number:	60648-70-6
Molecular Weight:	599.71
MDL number:	MFCD04974248
PubChem Substance ID:	329760505
NACRES:	NA.22

Reactant for synthesis of:

Trimetallic ReBiPt complexes
Rhodium-germanium carbonyl complexes

Catalyst for the synthesis of:

Amidobipyridyl inhibitors of protein kinase D
5-Fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling

Catalyst for phenyl and methyl group transfer from tin to iridium

Activator of metal hydride complexes

Packaging

1 g in glass bottle
250 mg in glass bottle

Параметры

Quality Level	100,
reaction suitability	core: platinum, reagent type: catalyst
mp	260-269 °C
storage temp.	2-8°C
SMILES string	[Pt].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI	1S/2C12H27P.Pt/c21-10(2,3)13(11(4,5)6)12(7,8)9;/h21-9H3;
Inchi Key	RJQWVEJVXWLMRE-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(tricyclohexylphosphine)palladium(0)

Empirical Formula (Hill Notation):	C₃₆H₆₆P₂Pd
CAS Number:	33309-88-5
Molecular Weight:	667.28
MDL number:	MFCD01073796
PubChem Substance ID:	329765126
NACRES:	NA.22

Bis(tricyclohexylphosphine)palladium(0) [Pd(PCy3)2] is a general palladium precatalyst that can be used to catalyze various reactions such as thioesterification of alkynes, alumination of unactivated arenes, direct arylation polycondensation and intramolecular alkane arylation adjacent to amides and sulfonamides.

Packaging

1 g in glass bottle
250 mg in glass bottle

Параметры

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
mp	87-92 °C
storage temp.	2-8°C
SMILES string	[Pd].C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6
InChI	1S/2C18H33P.Pd/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h216-18H,1-15H2;
Inchi Key	JGBZTJWQMWZVNX-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(triphenylphosphine)nickel(II) dichloride

Empirical Formula (Hill Notation):	C₃₆H₃₀Cl₂NiP₂
Linear Formula:	[(C₆H₅)₃P]₂NiCl₂
CAS Number:	14264-16-5
Molecular Weight:	654.17
EC Number:	238-154-8
MDL number:	MFCD00009592
PubChem Substance ID:	24854218
NACRES:	NA.22

Catalyst in the coupling reaction of aryl mesylates and allylic carbonates with lithium organoborates.

Packaging

10, 50 g in glass bottle

Параметры

grade	synthesis grade
Quality Level	100,
reaction suitability	core: nickel, reagent type: catalyst
mp	250 °C (dec.) (lit.)
SMILES string	Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI	1S/2C18H15P.2ClH.Ni/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h21-15H;2*1H;/q;;;;+2/p-2
InChI key	ZBRJXVVKPBZPAN-UHFFFAOYSA-L

Safety Information

pictograms	GHS07,GHS08
signalword	Danger
hcodes	H317 - H350 - H412
pcodes	P201 - P273 - P280 - P302 + P352 - P308 + P313
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(triphenylphosphine)palladium(II) diacetate

Empirical Formula (Hill Notation):	C₄₀H₃₆O₄P₂Pd
Linear Formula:	[(C₆H₅)₃P]₂Pd(CH₃COO)₂
CAS Number:	14588-08-0
Molecular Weight:	749.08
EC Number:	238-628-4
MDL number:	MFCD00010013
PubChem Substance ID:	24853498
NACRES:	NA.22

Quality Level	100,
assay	98%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	136 °C (dec.) (lit.)
SMILES string	CC(=O)O[Pd]OC(C)=O.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI	1S/2C18H15P.2C2H4O2.Pd/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;21-2(3)4;/h21-15H;21H3,(H,3,4);/q;;;;+2/p-2
Inchi Key	UVBXZOISXNZBLY-UHFFFAOYSA-L

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(triphenylphosphine)palladium(II) dichloride

Empirical Formula (Hill Notation):	C₃₆H₃₀Cl₂P₂Pd
Linear Formula:	[(C₆H₅)₃P]₂PdCl₂
CAS Number:	13965-03-2
Molecular Weight:	701.90
Beilstein/REAXYS Number:	4935975
EC Number:	237-744-2
MDL number:	MFCD00009593
PubChem Substance ID:	24865821
NACRES:	NA.22

Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.

Application

Bis(triphenylphosphine)palladium(II) dichloride was employed in the following studies:

As model catalyst for the evaluation of functionalized silicas for the adsorptive recovery of homogeneous catalysts, via its interaction with metal centre.
As catalyst in the synthesis of diphenylacetylene.
One-pot synthesis of furoquinolines, via Pd-catalyzed Sonogashira coupling followed by Cu(I) catalyzed ring closure.
Catalyst for Sonogashira coupling of aryl alkynes to 2-bromothiazole and 2-bromothiophene.

Application Guide for Palladium Catalyzed Cross-Coupling Reactions,

Packaging

250 mg in glass bottle
1, 5, 25, 250 g in glass bottle

Параметры

Quality Level	200,
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
SMILES string	Cl[Pd]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI	1S/2C18H15P.2ClH.Pd/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h21-15H;2*1H;/q;;;;+2/p-2
InChI key	YNHIGQDRGKUECZ-UHFFFAOYSA-L

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H317 - H413
pcodes	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride

Empirical Formula (Hill Notation):	C₃₈H₃₀Cl₂O₂P₂Ru
Linear Formula:	[(C₆H₅)₃P]₂Ru(CO)₂Cl₂
CAS Number:	14564-35-3
Molecular Weight:	752.57
EC Number:	238-605-9
MDL number:	MFCD00009594
PubChem Substance ID:	57647345

Quality Level	100,
assay	≥98.0% (CH)
reaction suitability	core: ruthenium, reagent type: catalyst
SMILES string	Cl[Ru](Cl)(C#[O])(C#[O])([PH](c1ccccc1)(c2ccccc2)c3ccccc3)[PH](c4ccccc4)(c5ccccc5)c6ccccc6
InChI	1S/2C18H15P.2CO.2ClH.Ru/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;21-2;;;/h21-15H;;;21H;/q;;;;;;+2/p-2
InChI key	PXURRFCLQDNZOY-UHFFFAOYSA-L

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth

Empirical Formula (Hill Notation):	Bi
CAS Number:	7440-69-9
Molecular Weight:	208.98
EC Number:	231-177-4
MDL number:	MFCD00134033
PubChem Substance ID:	57653676
NACRES:	NA.22

Bismuth granules are used in the preparation of bismuth nanoparticles by solution dispersion method. It is a precursor to synthesize bismuth-silicate glasses.

Packaging

100 g in poly bottle

Параметры

vapor pressure	<0.1 mmHg ( 20 °C)
Quality Level	100,
assay	≥99.99% trace metals basis
form	granular
reaction suitability	core: bismuth, reagent type: catalyst
resistivity	129 μΩ-cm, 20°C
bp	1560 °C (lit.)
mp	271 °C (lit.), 272 °C
density	9.8 g/mL at 25 °C (lit.)
SMILES string	[Bi]
InChI	1S/Bi
InChI key	JCXGWMGPZLAOME-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	nwg
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth aluminate hydrate 510289-500G

Empirical Formula (Hill Notation):	Al₆Bi₂O₁₂ · xH₂O
Linear Formula:	Bi₂(Al₂O₄)₃ · xH₂O
CAS Number:	308796-32-9
Molecular Weight:	771.84 (anhydrous basis)
EC Number:	235-552-3
MDL number:	MFCD00672141
PubChem Substance ID:	24873490
NACRES:	NA.22

Параметры

Quality Level	100,
assay	≥99.9%
reaction suitability	core: bismuth, reagent type: catalyst
SMILES string	[Bi+3].[O-][Al]=O.[O-][Al]=O.[O-][Al]=O
InChI	1S/3Al.Bi.6O/q;;;+3;;;;3*-1
InChI key	ZWSUTHPTOGDVHM-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth neodecanoate

Empirical Formula (Hill Notation):	C₃₀H₅₇BiO₆
Linear Formula:	Bi(OCOC(CH₃)₂(CH₂)₅CH₃)₃
CAS Number:	34364-26-6
Molecular Weight:	722.75
EC Number:	251-964-6
MDL number:	MFCD00070469
PubChem Substance ID:	24878296
NACRES:	NA.22

Quality Level	200,
form	liquid
reaction suitability	core: bismuth, reagent type: catalyst
refractive index	n20/D 1.479 (lit.)
bp	300 °C (lit.)
density	1.145 g/mL at 25 °C (lit.)
SMILES string	CCCCCCC(C)(C)C(=O)O[Bi](OC(=O)C(C)(C)CCCCCC)OC(=O)C(C)(C)CCCCCC
InChI	1S/3C10H20O2.Bi/c31-4-5-6-7-8-10(2,3)9(11)12;/h34-8H2,1-3H3,(H,11,12);/q;;;+3/p-3
Inchi Key	TUQRJVHQQXIPMN-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth tungsten oxide 709239-10G

Linear Formula:	Bi₂(WO₄)₃
CAS Number:	13595-87-4
EC Number:	237-033-7
MDL number:	MFCD00046190
PubChem Substance ID:	329762859

Параметры

assay	99.5% trace metals basis
form	powder
reaction suitability	reagent type: catalyst core: bismuth, reagent type: catalyst core: tungsten
particle size	200 mesh
mp	>300 °C
SMILES string	[Bi+3].[Bi+3].[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O
InChI	1S/2Bi.12O.3W/q2+3;;;;;;;6-1;;;
InChI key	DWNBMQNJXHTBPG-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) acetate

Empirical Formula (Hill Notation):	C₆H₉BiO₆
Linear Formula:	(CH₃CO₂)₃Bi
CAS Number:	22306-37-2
Molecular Weight:	386.11
MDL number:	MFCD00015629
PubChem Substance ID:	24865027
NACRES:	NA.22

Bismuth(III) acetate is employed as a starting material in the synthesis of bismuth(III) sulfide (Bi2S3) which can be used in solution-processable bulk heterojunction solar cells.
It is used in the preparation of gold-bismuth sulfide (Au–Bi2S3) heteronanostructures and bismuth titanate nanorods as photocatalysts.
It is also used in the synthesis of triarylbismuth compounds.

Packaging

10, 50 g in poly bottle

Параметры

Quality Level	100,
assay	99.99% trace metals basis
reaction suitability	core: bismuth, reagent type: catalyst
impurities	5% Bi₂O₃
SMILES string	CC(=O)O[Bi](OC(C)=O)OC(C)=O
InChI	1S/3C2H4O2.Bi/c31-2(3)4;/h31H3,(H,3,4);/q;;;+3/p-3
InChI key	WKLWZEWIYUTZNJ-UHFFFAOYSA-K

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) citrate

Empirical Formula (Hill Notation):	C₆H₅BiO₇
Linear Formula:	[O₂CCH₂C(OH)(CO₂)CH₂CO₂]Bi
CAS Number:	813-93-4
Molecular Weight:	398.08
EC Number:	212-390-1
MDL number:	MFCD00050817
PubChem Substance ID:	24871714
NACRES:	NA.22

Bismuth(III) citrate has been used as a sorbent in spin columns to develop a novel stationary phase for the selective and efficient isolation of phenolic compounds from natural sources via solid phase extraction (SPE) method. It can be used to synthesize bismuth subcarbonate ((BiO)2CO3) nanotubes that are reported to show antibacterial property against Helicobacter pylori.

Packaging

100, 500 g in poly bottle

Параметры

Quality Level	100,
assay	99.99% trace metals basis
reaction suitability	core: bismuth, reagent type: catalyst
particle size	−325 mesh
mp	300 °C (dec.) (lit.)
density	0.94 g/mL at 25 °C (lit.)
SMILES string	OC12CC(=O)O[Bi](OC(=O)C1)OC2=O
InChI	1S/C6H8O7.Bi/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);/q;+3/p-3
InChI key	ANERHPOLUMFRDC-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) gallate basic hydrate

Empirical Formula (Hill Notation):	C₇H₅BiO₆ · xH₂O
CAS Number:	99-26-3
Molecular Weight:	394.09 (anhydrous basis)
EC Number:	202-742-2
MDL number:	MFCD20441998
PubChem Substance ID:	57647308
NACRES:	NA.22

Pharmacological activity, specifically NO and PGE2 production by macrophages
Treatment of Helicobacter pylori infections

Packaging

100 g in poly bottle

Параметры

Quality Level	100,
assay	≥98.0% (calc. on dry substance, KT)
reaction suitability	core: bismuth, reagent type: catalyst
impurities	~10% water
SMILES string	O.O[Bi]1Oc2cc(cc(O)c2O1)C(O)=O
InChI	1S/C7H6O5.Bi.2H2O/c8-4-1-3(7(11)12)2-5(9)6(4)10;;;/h1-2,8-10H,(H,11,12);;2*1H2/q;+3;;/p-3
InChI key	VJXPXOVBMBKEHX-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) iodide

Empirical Formula (Hill Notation):	BiI₃
CAS Number:	7787-64-6
Molecular Weight:	589.69
EC Number:	232-127-4
MDL number:	MFCD00010894
PubChem Substance ID:	24860889
NACRES:	NA.22

Bismuth(III) iodide or Bismuth triiodide are nontoxic and hence they are used as environmentally friendly catalysts. It can be used as a catalyst in the:

Chemoselective deprotection of acetals and ketals in water.
Synthesis of polysubstituted guanidines by guanylation reaction of thioureas with amines.
Sulfenylation of carbonyl compounds.

Packaging

25, 100 g in glass bottle

Параметры

Quality Level	100,
assay	99%
reaction suitability	core: bismuth, reagent type: catalyst
mp	408 °C (lit.)
density	5.78 g/mL at 25 °C (lit.)
SMILES string	I[Bi](I)I
InChI	1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChI key	KOECRLKKXSXCPB-UHFFFAOYSA-K

Safety Information

pictograms	GHS05
signalword	Danger
hcodes	H314
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 3260 8 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) nitrate pentahydrate

Empirical Formula (Hill Notation):	BiN₃O₉ · 5H₂O
Linear Formula:	Bi(NO₃)₃ · 5H₂O
CAS Number:	10035-06-0
Molecular Weight:	485.07
EC Number:	233-791-8
PubChem Substance ID:	24854938
NACRES:	NA.22

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.

Packaging

100, 500 g in poly bottle

Параметры

grade	reagent grade
Quality Level	100,
assay	98%
reaction suitability	core: bismuth, reagent type: catalyst
bp	75-80 °C (lit.)
mp	30 °C (lit.)
SMILES string	O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
InChI	1S/CH4.Bi.3NO3/c;;32-1(3)4/h1H4;;;;/q;+3;3-1
Inchi Key	DPLOIMSBRDLLRI-UHFFFAOYSA-N

Safety Information

pictograms	GHS03,GHS05
signalword	Danger
hcodes	H272 - H318
pcodes	P210 - P220 - P280 - P305 + P351 + P338 - P370 + P378 - P501
Personal Protective Equipment	Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges,
RIDADR	UN 1477 5.1 / PGII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) phosphate 483311-25G

Empirical Formula (Hill Notation):	BiO₄P
CAS Number:	10049-01-1
Molecular Weight:	303.95
EC Number:	233-161-2
MDL number:	MFCD00049721
PubChem Substance ID:	24871882
NACRES:	NA.22

Application

Used for:

Coprecipitation of polonium
Approach to bismuth modifying procedure for voltammetric thick film carbon containing electrodes
Investigations of the association between plutonium radiation exposure and leukemia mortality
Membrane electrodes selective for hydrogen phosphate ions

Catalyst for:

Ammoxidation of propylene
Decomposition of CCl2F2

Packaging

25 g in poly bottle

Параметры

Quality Level	100,
assay	99.99%
reaction suitability	core: bismuth, reagent type: catalyst
mp	>350 °C (lit.)
density	6.32 g/mL at 25 °C (lit.)
SMILES string	[Bi+3].[O-]P([O-])([O-])=O
InChI	1S/Bi.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3
Inchi Key	SFOQXWSZZPWNCL-UHFFFAOYSA-K

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) subsalicylate

Empirical Formula (Hill Notation):	C₇H₅BiO₄
Linear Formula:	HOC₆H₄COOBiO
CAS Number:	14882-18-9
Molecular Weight:	362.09
EC Number:	238-953-1
MDL number:	MFCD00085368
PubChem Substance ID:	24871718

Bismuth(III) subsalicylate (BSS) is mainly used in bismuth-based medicines for treating gastrointestinal disorders and diarrhea.

Packaging

100, 500 g in poly bottle

Параметры

Quality Level	100,
assay	99.9% trace metals basis
reaction suitability	core: bismuth, reagent type: catalyst
mp	>350 °C (lit.)
SMILES string	O[Bi]1OC(=O)c2ccccc2O1
InChI	1S/C7H6O3.Bi.H2O/c8-6-4-2-1-3-5(6)7(9)10;;/h1-4,8H,(H,9,10);;1H2/q;+3;/p-3
InChI key	ZREIPSZUJIFJNP-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bismuth(III) trifluoromethanesulfonate

Empirical Formula (Hill Notation):	C₃BiF₉O₉S₃
Linear Formula:	Bi(OSO₂CF₃)₃
CAS Number:	88189-03-1
Molecular Weight:	656.19
MDL number:	MFCD02093669
PubChem Substance ID:	24882545
NACRES:	NA.22

Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.
Bismuth(III) trifluoromethanesulfonate may be used as a catalyst in the following processes:

deprotection of acetals
cleavage of 2-tert-butoxy derivatives of thiophenes and furans
allylation of acetals to form homoallyl ethers

It may also be used as a substitute to corrosive triflic acid in Friedel-Crafts (FC) acylation and sulfonylation of arenes.

Packaging

5, 25 g in glass bottle
Bismuth(III) trifluoromethanesulfonate is an eco-friendly Lewis acid that can be prepared by reacting triflic acid with bismuth(III) trifluoroacetate.

Параметры

Quality Level	100,
reaction suitability	core: bismuth, reagent type: catalyst
mp	>300 °C (lit.)
SMILES string	[Bi+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI	1S/3CHF3O3S.Bi/c32-1(3,4)8(5,6)7;/h3(H,5,6,7);/q;;;+3/p-3
InChI key	NYENCOMLZDQKNH-UHFFFAOYSA-K

Safety Information

Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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BisPhePhos XD gold(I) chloride L511846-100MG

Empirical Formula (Hill Notation):	C₄₂H₅₃AuClO₄P
CAS Number:	1616612-78-2
Molecular Weight:	885.26
MDL number:	MFCD27952561
PubChem Substance ID:	329817540

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Параметры

Quality Level	100,
reaction suitability	core: gold, reagent type: catalyst
SMILES string	CC(C)OC(C=CC=C1OC(C)C)=C1C2=CC(P(C3CCCCC3)C4=CC(C5=C(OC(C)C)C=CC=C5OC(C)C)=CC=C4)=CC=C2.[Au]Cl
InChI	1S/C42H53O4P.Au.ClH/c1-28(2)43-37-22-14-23-38(44-29(3)4)41(37)32-16-12-20-35(26-32)47(34-18-10-9-11-19-34)36-21-13-17-33(27-36)42-39(45-30(5)6)24-15-25-40(42)46-31(7)8;;/h12-17,20-31,34H,9-11,18-19H2,1-8H3;;1H/q;+1;/p-1
InChI key	FSMSZCNOYZSTBC-UHFFFAOYSA-M

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride

Empirical Formula (Hill Notation):	C₁₆H₂₀ClN₃Ni
CAS Number:	1033772-47-2
Molecular Weight:	348.50
MDL number:	MFCD17015253
PubChem Substance ID:	329764408
NACRES:	NA.22

Alkyl-alkyl Kumada coupling of secondary alkyl halides
Direct alkylation of heterocyclic C-H bonds
Sonogashira coupling of nonactivated alkyl halides
Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles

Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation

Packaging

100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

Параметры

assay	97% (AT)
reaction suitability	core: nickel, reagent type: catalyst
SMILES string	CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
InChI	1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
Inchi Key	IRLHVNUEEKJBEL-UHFFFAOYSA-M

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis[(tetrabutylammonium iodide)copper(I) iodide]

Empirical Formula (Hill Notation):	C₃₂H₇₂Cu₂I₄N₂
Molecular Weight:	1119.64
MDL number:	MFCD22200557
PubChem Substance ID:	329766980
NACRES:	NA.22

Quality Level	100,
assay	95%
reaction suitability	core: copper, reagent type: catalyst
mp	90-97 °C
SMILES string	[I-].[I-].[Cu]I.[Cu]I.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
InChI	1S/2C16H36N.2Cu.4HI/c21-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;/h25-16H2,1-4H3;;;41H/q4+1;;;;/p-4
Inchi Key	AVVGGLORWAVEFH-UHFFFAOYSA-J

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis[1,2-bis(diphenylphosphine oxide)benzene] sodium phenoxide 708836-1G

Empirical Formula (Hill Notation):	C₆₆H₅₃NaO₅P₄
Molecular Weight:	1073.01
MDL number:	MFCD16621406
PubChem Substance ID:	329762828

Параметры

assay	95%
reaction suitability	core: sodium, reaction type: C-C Bond Formation, reagent type: catalyst
SMILES string	[Na+].[O-]c1ccccc1.O=P(c2ccccc2)(c3ccccc3)c4ccccc4P(=O)(c5ccccc5)c6ccccc6.O=P(c7ccccc7)(c8ccccc8)c9ccccc9P(=O)(c%10ccccc%10)c%11ccccc%11
InChI	1S/2C30H24O2P2.C6H6O.Na/c231-33(25-15-5-1-6-16-25,26-17-7-2-8-18-26)29-23-13-14-24-30(29)34(32,27-19-9-3-10-20-27)28-21-11-4-12-22-28;7-6-4-2-1-3-5-6;/h21-24H;1-5,7H;/q;;;+1/p-1
InChI key	NYNZJRNHSJIINX-UHFFFAOYSA-M

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302-H312-H315-H319-H332-H335
pcodes	P261-P280-P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	2

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Bis[rhodium(,,,-tetramethyl-1,3-benzenedipropionic acid)]

Empirical Formula (Hill Notation):	C₃₂H₄₀O₈Rh₂
CAS Number:	819050-89-0
Molecular Weight:	758.47
MDL number:	MFCD08457636
PubChem Substance ID:	24884595

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination,
Catalyst for an efficient intermolecular amination of tertiary, benzylic C-H bonds.

Packaging

100, 500 mg in glass bottle

Параметры

Quality Level	100,
assay	96%
reaction suitability	core: rhodium, reagent type: catalyst reaction type: C-H Activation
mp	>300 °C
SMILES string	[Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O
InChI	1S/2C16H22O4.2Rh/c21-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h25-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;
Inchi Key	OBMUTUNJWNQIAJ-UHFFFAOYSA-N

Safety Information

Personal Protective Equipment	Eyeshields,, Gloves,, type N95 (US),
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bis[tris(2-methylphenyl)phosphine]palladium 711071-500MG

Empirical Formula (Hill Notation):	C₄₂H₄₂P₂Pd
CAS Number:	69861-71-8
Molecular Weight:	715.15
MDL number:	MFCD12911908
PubChem Substance ID:	329763029
NACRES:	NA.22

Application

Catalyst for:

Palladium-catalyzed cross-coupling reactions and aminations
Kumada coupling
Arylation
Heck coupling

Packaging

500 mg in glass bottle

Параметры

Quality Level	100,
assay	97%
reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp	220-225 °C
storage temp.	20°C
SMILES string	[Pd].Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C
InChI	1S/2C21H21P.Pd/c21-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;/h24-15H,1-3H3;
Inchi Key	CUBIJGNGGJBNOC-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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900920-100MG

Bis[[diisopropylphosphino]methyl]-4-methyl-pyridine bis(pivaloyloxy)cobalt 900920-100MG

Empirical Formula (Hill Notation): C₃₀H₅₅CoNO₄P₂

CAS Number: 2071741-36-9

Molecular Weight: 614.64

Application
Bis[[diisopropylphosphino]methyl]-4-methyl-pyridine bis(pivaloyloxy)cobalt also known as JennyCat is developed in the laboratory of Paul Chirik is an effective cobalt precatalyst for the borylation of aromatic compounds, including diverse heteroarenes, pyridine derivatives, and fluoroarenes.
Other Notes
C(sp2)-H Borylation of fluorinated arenes using an air-stable cobalt precatalyst: electronically enhanced site selectivity enables synthetic opportunities,
Параметры

Quality Level 100,

assay 95%

form powder

reaction suitability core: cobalt, reagent type: catalyst

mp >300 °C

SMILES string CC1=CC(CP(C(C)C)C(C)C)=NC(CP(C(C)C)C(C)C)=C1.O=C(C(C)(C)C)O[Co]OC(C(C)(C)C)=O

Safety Information

RIDADR NONH for all modes of transport

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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Boron

Empirical Formula (Hill Notation):	B
CAS Number:	7440-42-8
Molecular Weight:	10.81
EC Number:	231-151-2
MDL number:	MFCD00134034
PubChem Substance ID:	57647503
NACRES:	NA.22

Boron (amorphous powder) has been used as a boron source to synthesize hexagonal boron nitride (h-BN), boron doped diamond (BDD) and europium-doped BN nanotubes.

Packaging

50, 250 g in poly bottle

Параметры

Quality Level	200,
assay	≥95% (boron)
form	amorphous powder
reaction suitability	core: boron, reagent type: catalyst
resistivity	1.5E12 μΩ-cm, 20 °C
particle size	≤1 μm
density	2.34 g/mL at 25 °C (lit.)
SMILES string	[B]
InChI	1S/B
InChI key	ZOXJGFHDIHLPTG-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 - H412
pcodes	P264 - P270 - P273 - P301 + P312 - P501
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	nwg
Flash Point F	Not applicable
Flash Point C	Not applicable

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Boxed reaction: Buchwald-Hartwig in Lipshutz Surfactant 747599-1KT

This kit contains the reagents, catalyst, and solvent required to perform a Buchwald-Hartwig reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol, for details.

Packaging

1 kit in ampule

Параметры

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
greener alternative product characteristics	Waste Prevention Designing Safer Chemicals Design for Energy Efficiency Catalysis Learn more about the Principles of Green Chemistry,.

Safety Information

pictograms	GHS02,GHS05
signalword	Danger
hcodes	H228 - H260 - H314
pcodes	P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Supp Hazards	EUH014
RIDADR	UN 3131 8(4.3) / PGI
WGK Germany	WGK 3

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Boxed reaction: Heck Reaction in Lipshutz Surfactant 747904-1KT

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here,.

Application

This kit contains the reagents, catalyst, and solvent required to perform a Heck reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol, for details.

Параметры

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
greener alternative product characteristics	Waste Prevention Designing Safer Chemicals Design for Energy Efficiency Catalysis Learn more about the Principles of Green Chemistry,.
storage temp.	20°C

Safety Information

pictograms	GHS02,GHS05,GHS07
signalword	Danger
hcodes	H225 - H302 + H312 + H332 - H314
pcodes	P210 - P280 - P305 + P351 + P338 - P310
RIDADR	UN 3316 9
Flash Point F	5.0 °F - closed cup
Flash Point C	-15 °C - closed cup

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Boxed reaction: Sonogashira Reaction in Lipshutz Surfactant 747912-1KT

This kit contains the reagents, catalyst, and solvent required to perform a Sonogashira reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol, for details.

Параметры

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
greener alternative product characteristics	Waste Prevention Designing Safer Chemicals Design for Energy Efficiency Catalysis Learn more about the Principles of Green Chemistry,.
storage temp.	20°C

Safety Information

pictograms	GHS02,GHS05,GHS06
signalword	Danger
hcodes	H225 - H301 + H311 + H331 - H314 - H413
pcodes	P210 - P261 - P280 - P301 + P310 - P305 + P351 + P338 - P310
RIDADR	UN 3316 9
Flash Point F	5.0 °F
Flash Point C	-15 °C

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Boxed reaction: Suzuki coupling in Lipshutz Surfactant 747602-1KT

NACRES:

NA.22

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis and energy efficiency. Find details here,.

Application

This kit contains the reagents, catalyst, and solvent required to perform a Suzuki-Miyaura reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol, for details.

Параметры

reaction suitability	core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level	100,
greener alternative product characteristics	Waste Prevention Designing Safer Chemicals Design for Energy Efficiency Catalysis Learn more about the Principles of Green Chemistry,.
storage temp.	20°C

Safety Information

pictograms	GHS02,GHS05,GHS07
signalword	Danger
hcodes	H225 - H302 + H312 + H332 - H314
pcodes	P210 - P280 - P305 + P351 + P338 - P310
RIDADR	UN 3316 9
Flash Point F	5.0 °F - closed cup
Flash Point C	-15 °C - closed cup

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Bromoferrocene

Empirical Formula (Hill Notation):	C₁₀H₉BrFe
CAS Number:	1273-73-0
Molecular Weight:	264.93
MDL number:	MFCD03093913
PubChem Substance ID:	329764141
NACRES:	NA.22

reaction suitability	core: iron, reagent type: catalyst
Quality Level	100,
mp	26-32 °C
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.Br[C]2[CH][CH][CH][CH]2
InChI	1S/C5H4Br.C5H5.Fe/c6-5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H;1-5H;
Inchi Key	RFYQCXFGACWJED-UHFFFAOYSA-N

Safety Information

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bromopentacarbonylrhenium(I)

Empirical Formula (Hill Notation):	C₅BrO₅Re
Linear Formula:	Re(CO)₅Br
CAS Number:	14220-21-4
Molecular Weight:	406.16
EC Number:	238-084-8
MDL number:	MFCD00013295
PubChem Substance ID:	24859676
NACRES:	NA.22

Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes.
Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands.
Starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
assay	98%
reaction suitability	core: rhenium, reagent type: catalyst
SMILES string	Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI	1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
Inchi Key	NWJBOTGGBYFKEJ-UHFFFAOYSA-M

Safety Information

pictograms	GHS06
signalword	Danger
hcodes	H301 + H311 + H331 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN 3288 6.1 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer

Empirical Formula (Hill Notation):	C₁₄H₁₆Br₂O₈Re₂
Linear Formula:	[ReBr(CO)₃(C₄H₈O)]₂
CAS Number:	54082-95-0
Molecular Weight:	844.49
MDL number:	MFCD11656181
PubChem Substance ID:	329760985
NACRES:	NA.22

100 mg in clear glass bottle
500 mg in amber glass bottle

Application

Catalyst for insertation of acetylenes into 1,3-dicarbonyl′s and for isobenzofuran synthesis.

Параметры

reaction suitability	core: rhenium, reagent type: catalyst
Quality Level	100,
SMILES string	Br[Re].Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1CCOC1.C2CCOC2
InChI	1S/2C4H8O.6CO.2BrH.2Re/c21-2-4-5-3-1;61-2;;;;/h21-4H2;;;;;;;21H;;/q;;;;;;;;;;2*+1/p-2
Inchi Key	GARJHXMUDDMPBU-UHFFFAOYSA-L

Safety Information

pictograms	GHS06
signalword	Danger
hcodes	H301 + H311 + H331
pcodes	P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311
Personal Protective Equipment	Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN 3288 6.1 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Cacodylic acid

Empirical Formula (Hill Notation):	C₂H₇AsO₂
Linear Formula:	(CH₃)₂As(O)OH
CAS Number:	75-60-5
Molecular Weight:	138.00
Beilstein/REAXYS Number:	1736965
EC Number:	200-883-4
MDL number:	MFCD00002095
PubChem Substance ID:	57647876
NACRES:	NA.22

10, 50 g in glass bottle

Application

Used as herbicides.

Параметры

Quality Level	100,
assay	≥99.0%
reaction suitability	core: arsenic, reagent type: catalyst
SMILES string	C[As](C)(O)=O
InChI	1S/C2H7AsO2/c1-3(2,4)5/h1-2H3,(H,4,5)
Inchi Key	OGGXGZAMXPVRFZ-UHFFFAOYSA-N

Safety Information

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H301 + H331 - H350 - H410
pcodes	P201 - P273 - P301 + P310 + P330 - P304 + P340 + P311
RIDADR	UN 1572 6.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Cadmium

Empirical Formula (Hill Notation):	Cd
CAS Number:	7440-43-9
Molecular Weight:	112.41
Beilstein/REAXYS Number:	8137359
EC Number:	231-152-8
MDL number:	MFCD00010914
PubChem Substance ID:	24856069
NACRES:	NA.22

Quality Level	100,
assay	99.5% trace metals basis
form	powder
reaction suitability	core: cadmium, reagent type: catalyst
resistivity	7.27 μΩ-cm, 22°C
particle size	−100 mesh
bp	765 °C (lit.)
mp	320.9 °C (lit.)
density	8.65 g/mL at 25 °C (lit.)
SMILES string	[Cd]
InChI	1S/Cd
InChI key	BDOSMKKIYDKNTQ-UHFFFAOYSA-N

Safety Information

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H301 - H330 - H341 - H350 - H361fd - H372 - H410
pcodes	P201 - P202 - P260 - P264 - P273 - P304 + P340 + P310
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves,, type P2 (EN 143) respirator cartridges,
RIDADR	UN3288 - class 6.1 - PG 2 - EHS - RQ - Toxic solid, inorganic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Cadmium acetylacetonate 517585-50G

Empirical Formula (Hill Notation):	C₁₀H₁₄CdO₄
Linear Formula:	Cd(C₅H₇O₂)₂
CAS Number:	14689-45-3
Molecular Weight:	310.63
EC Number:	238-730-9
MDL number:	MFCD00040412
PubChem Substance ID:	24873958
NACRES:	NA.23

General description

Atomic number of base material: 48 Cadmium

Packaging

50 g in glass bottle

Параметры

Quality Level	100,
assay	≥99.9% trace metals basis
form	powder
reaction suitability	core: cadmium, reagent type: catalyst
mp	209-214 °C (lit.)
SMILES string	CC(=O)\C=C(\C)O[Cd]O\C(C)=C/C(C)=O
InChI	1S/2C5H8O2.Cd/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
Inchi Key	JXULEGTWCQDLTM-FDGPNNRMSA-L

Safety Information

pictograms	GHS07,GHS08,GHS09
signalword	Warning
hcodes	H302 + H312 + H332 - H351 - H361d - H373 - H410
pcodes	P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
RIDADR	UN 2570 6.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Calcium chromate CDS001277-1G

Empirical Formula (Hill Notation):	CaCrO₄
CAS Number:	13765-19-0
Molecular Weight:	156.07
EC Number:	237-366-8
MDL number:	MFCD00049403
PubChem Substance ID:	329778489

Other Notes

Параметры

reaction suitability	core: chromium, reagent type: catalyst
storage temp.	20°C
SMILES string	[Ca++].[O-][Cr]([O-])(=O)=O
InChI	1S/Ca.Cr.4O/q+2;;;;2*-1
InChI key	RFAFBXGYHBOUMV-UHFFFAOYSA-N

Safety Information

pictograms	GHS07,GHS08,GHS09
signalword	Danger
hcodes	H302 - H350 - H410
pcodes	P201 - P273 - P301 + P312 + P330 - P308 + P313
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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CARAC

Empirical Formula (Hill Notation):	C₇H₇O₄Rh
Linear Formula:	Rh(CO)₂(C₅H₇O₂)
CAS Number:	14874-82-9
Molecular Weight:	258.03
EC Number:	238-947-9
MDL number:	MFCD00009884
PubChem Substance ID:	329760803
NACRES:	NA.22

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis,

Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds

Packaging

2 g in glass bottle
500 mg in glass bottle

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com,

Параметры

Quality Level	100,
assay	98%
form	solid
reaction suitability	core: rhodium, reagent type: catalyst
mp	154-156 °C (lit.)
SMILES string	[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
InChI	1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
Inchi Key	BZCAWKOPWNIDOC-FGSKAQBVSA-M

Safety Information

pictograms	GHS02,GHS07
signalword	Warning
hcodes	H228 - H317 - H319
pcodes	P210 - P280 - P302 + P352 - P305 + P351 + P338
Supp Hazards	EUH044
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	UN 3467 6.1 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

Empirical Formula (Hill Notation):	C₅₅H₄₆ClOP₃Ru
Linear Formula:	[(C₆H₅)₃P]₃Ru(CO)(Cl)H
CAS Number:	16971-33-8
Molecular Weight:	952.40
EC Number:	241-051-0
MDL number:	MFCD00049804
PubChem Substance ID:	24860276

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst
mp	204-206 °C (dec.) (lit.)
SMILES string	Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.CO.ClH.Ru/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h31-15H;;1H;/q;;;;;+1/p-1
InChI key	MVJRXTSUBHUUPN-UHFFFAOYSA-M

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332 - H315 - H319 - H335
pcodes	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Empirical Formula (Hill Notation):	C₅₅H₄₇OP₃Rh
Linear Formula:	[(C₆H₅)₃P]₃Ru(CO)H₂
CAS Number:	25360-32-1
Molecular Weight:	919.79
PubChem Substance ID:	24860277
NACRES:	NA.22

Catalyst for conversion of 1,4-alkynediols into pyrroles
Catalyst for oxidation of primary alcohols to methyl esters
Catalyst for rearrangement of oximes to amides
Catalyst for C-C coupling via directed C-H activation
Catalyst for enyne cyclization

Packaging

1 g in glass bottle

Параметры

Quality Level	100,
reaction suitability	core: ruthenium, reagent type: catalyst reaction type: C-H Activation
mp	161-163 °C (lit.)
SMILES string	[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.CO.Ru.2H/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h31-15H;;;;
InChI key	MLIYPCQSOXNTLJ-UHFFFAOYSA-N

Safety Information

pictograms	GHS07
signalword	Warning
hcodes	H302 + H312 + H332
pcodes	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable