Catalysts
- Сортировать:
- Вид таблицей
-
(S)-Ru(OAc)2(BINAP)
Empirical Formula (Hill Notation): C48H38O4P2Ru CAS Number: 261948-85-0 Molecular Weight: 841.83 MDL number: MFCD09753020 PubChem Substance ID: 329761570 NACRES: NA.22
Кат. номер 693189-500MG 693189-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
Catalyst for:- Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
- Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
- Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
- Asymmetric reduction of (nitro)(phenyl)propene
- Asymmetric synthesis of chiral d-lactones via hydrogenation
- Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene
Packaging100, 500 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C InChI 1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2 Inchi Key NMLZYEWNUCRSRJ-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Ru(OAc)2(DM-BINAP)
Empirical Formula (Hill Notation): C56H54O4P2Ru CAS Number: 374067-49-9 Molecular Weight: 954.04 MDL number: MFCD09753022 PubChem Substance ID: 329761579 NACRES: NA.22
Кат. номер 693286-50MG 693286-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C SMILES string CC(=O)O[Ru]OC(C)=O.Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8 InChI 1S/C52H48P2.2C2H4O2.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;2*1-2(3)4;/h9-32H,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2 InChI key IFUMNSKQNPECEY-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Ru(OAc)2(DM-SEGPHOS®)
Empirical Formula (Hill Notation): C50H50O8P2Ru CAS Number: 944450-50-4 Molecular Weight: 941.94 MDL number: MFCD09753025 PubChem Substance ID: 329761575 NACRES: NA.22
Кат. номер 693235-50MG 693235-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
(S)-Ru(OAc)2(DM-SEGPHOS®) can be used as a catalyst in:- The enantioselective asymmetric hydrogenation reaction.
- The asymmetric reductive amination reaction.
- The total synthesis of (-)-tubingensin B via Suzuki-Miyaura coupling and aryne cyclization reactions.
Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.ПараметрыQuality Level 100, storage temp. 2-8°C InChI 1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;2*1-2(3)4;/h9-24H,25-26H2,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2 InChI key ACKYBTAGKAINOG-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Ru(OAc)2(H8-BINAP)
Empirical Formula (Hill Notation): C48H46O4P2Ru CAS Number: 142962-95-6 Molecular Weight: 849.89 MDL number: MFCD09753023 PubChem Substance ID: 329761578
Кат. номер 693278-50MG 693278-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
Catalyst for:- Enantioselective asymmetric hydrogenation reactions
Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C InChI 1S/C44H40P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-12,19-26,29-32H,13-18,27-28H2;2*1H3,(H,3,4);/q;;;+2/p-2 Inchi Key HZRBASMTZGJUJU-UHFFFAOYSA-L
Safety Informationpictograms GHS07 signalword Warning hcodes H319 - H335 pcodes P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Ru(OAc)2(SEGPHOS®)
Empirical Formula (Hill Notation): C42H34O8P2Ru CAS Number: 373650-12-5 Molecular Weight: 829.73 MDL number: MFCD09753024 PubChem Substance ID: 329761576 NACRES: NA.22
Кат. номер 693243-50MG 693243-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
(S)-Ru(OAc)2(SEGPHOS®) can be used as a catalyst:- To prepare highly chemo, enantio, and diastereoselective primary -amino lactams by asymmetric reductive amination of racemic -keto lactams.
- To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
- For the conversion of levulinic acid to optically active -valerolactone via asymmetric hydrogenation reaction.
Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.ПараметрыQuality Level 100, storage temp. 2-8°C InChI 1S/C38H28O4P2.2C2H4O2.Ru/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;2*1-2(3)4;/h1-24H,25-26H2;2*1H3,(H,3,4);/q;;;+2/p-2 InChI key BHGLLIGZFQVMBJ-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Ru(OAc)2(T-BINAP)
Empirical Formula (Hill Notation): C52H46O4P2Ru CAS Number: 106681-15-6 Molecular Weight: 897.94 MDL number: MFCD09753021 PubChem Substance ID: 329761571 NACRES: NA.22
Кат. номер 693197-500MG 693197-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging100, 500 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C InChI 1S/C48H40P2.2C2H4O2.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;2*1-2(3)4;/h5-32H,1-4H3;2*1H3,(H,3,4);/q;;;+2/p-2 InChI key HXHQOYKBZFDKSM-UHFFFAOYSA-L
Safety Informationpictograms GHS07 signalword Warning hcodes H319 - H335 pcodes P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-RuCl[(p-cymene(BINAP)]Cl
Empirical Formula (Hill Notation): C54H46Cl2P2Ru Linear Formula: [C54H46ClP2Ru]+Cl- CAS Number: 130004-33-0 Molecular Weight: 928.87 MDL number: MFCD00134456 PubChem Substance ID: 329761547 NACRES: NA.22
Кат. номер 692972-500MG 692972-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging100, 500 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C SMILES string Cl[Ru]Cl.CC(C)c1ccc(C)cc1.c2ccc(cc2)P(c3ccccc3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9 InChI 1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 Inchi Key WNHLGYRPKARUHY-UHFFFAOYSA-L
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-RuCl[(p-cymene)(DM-BINAP)]Cl
Empirical Formula (Hill Notation): C62H62Cl2P2Ru Linear Formula: [C62H62ClP2Ru]+Cl- CAS Number: 1345887-44-6 Molecular Weight: 1041.08 PubChem Substance ID: 329761561 NACRES: NA.22
Кат. номер 693103-50MG 693103-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C SMILES string [Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.Cc2cc(C)cc(c2)P(c3cc(C)cc(C)c3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8cc(C)cc(C)c8)c9cc(C)cc(C)c9 InChI 1S/C52H48P2.C10H14.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-8(2)10-6-4-9(3)5-7-10;;;/h9-32H,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 InChI key CBZXDZCPCDMKJU-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-RuCl[(p-cymene)(DM-SEGPHOS®)]Cl
Empirical Formula (Hill Notation): C56H58Cl2O4P2Ru Linear Formula: [C56H58ClO4P2Ru]+Cl– CAS Number: 944451-31-4 Molecular Weight: 1028.98 MDL number: MFCD09753018 PubChem Substance ID: 329761544 NACRES: NA.22
Кат. номер 692948-50MG 692948-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.Параметрыstorage temp. 2-8°C Quality Level 100, InChI 1S/C46H44O4P2.C10H14.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;1-8(2)10-6-4-9(3)5-7-10;;;/h9-24H,25-26H2,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 Inchi Key LLNJPFQWQJQPEH-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-RuCl[(p-cymene)(DTBM-SEGPHOS®)]Cl
Empirical Formula (Hill Notation): C84H114Cl2O8P2Ru Linear Formula: [C84H114ClO8P2Ru]+Cl− CAS Number: 944451-33-6 Molecular Weight: 1485.72 MDL number: MFCD09753019 PubChem Substance ID: 329761560
Кат. номер 693073-50MG 693073-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.Параметрыstorage temp. 2-8°C Quality Level 100, InChI 1S/C74H100O8P2.C10H14.2ClH.Ru/c1-67(2,3)47-33-43(34-48(61(47)75-25)68(4,5)6)83(44-35-49(69(7,8)9)62(76-26)50(36-44)70(10,11)12)57-31-29-55-65(81-41-79-55)59(57)60-58(32-30-56-66(60)82-42-80-56)84(45-37-51(71(13,14)15)63(77-27)52(38-45)72(16,17)18)46-39-53(73(19,20)21)64(78-28)54(40-46)74(22,23)24;1-8(2)10-6-4-9(3)5-7-10;;;/h29-40H,41-42H2,1-28H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 Inchi Key MYYXUILRYSITRR-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-RuCl[(p-cymene)(H8-BINAP)]Cl
Empirical Formula (Hill Notation): C54H54Cl2P2Ru Linear Formula: [C54H54ClP2Ru]+Cl- CAS Number: 944451-27-8 Molecular Weight: 936.93 PubChem Substance ID: 329761563 NACRES: NA.22
Кат. номер 693111-50MG 693111-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.Параметрыstorage temp. 2-8°C Quality Level 100, SMILES string [Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2CCc3c(C2)ccc(P(c4ccccc4)c5ccccc5)c3-c6c7CCCCc7ccc6P(c8ccccc8)c9ccccc9 InChI 1S/C44H40P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-12,19-26,29-32H,13-18,27-28H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 Inchi Key RDVYAXZMACLMGN-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-RuCl[(p-cymene)(T-BINAP)]Cl
Empirical Formula (Hill Notation): C58H54Cl2P2Ru Linear Formula: [C58H54ClP2Ru]+Cl− CAS Number: 228120-95-4 Molecular Weight: 984.97 PubChem Substance ID: 329761546 NACRES: NA.22
Кат. номер 692964-500MG 692964-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging100, 500 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C SMILES string [Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.Cc2ccc(cc2)P(c3ccc(C)cc3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8ccc(C)cc8)c9ccc(C)cc9 InChI 1S/C48H40P2.C10H14.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-8(2)10-6-4-9(3)5-7-10;;;/h5-32H,1-4H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 InChI key BHIUOOHVIWKUTN-UHFFFAOYSA-L
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-SDP 700746-50MG
Empirical Formula (Hill Notation): C41H34P2 CAS Number: 528521-86-0 Molecular Weight: 588.66 MDL number: MFCD08459344 PubChem Substance ID: 329762227 NACRES: NA.22 General description(S)-SDP is a chiral diphosphine reagent used in the asymmetric hydrogenation of ketones catalyzed by transition metal. It is also used in hydrosilylation or cyclization of 1,6-enynes.Application(S)-SDP can be used:- As a ligand in the ruthenium-catalyzed asymmetric hydrogenation of cyclic ketones to give cycloalkanols.
- To prepare ruthenium complexes, which are used in the asymmetric hydrogenation of different prochiral ketones.
Packaging50 mg in amber glass bottleПараметрыQuality Level 100, assay 95% optical activity []22/D 191°, c = 1 in chloroform mp 199-204 °C storage temp. 20°C SMILES string C1CC2(CCc3cccc(P(c4ccccc4)c5ccccc5)c23)c6c1cccc6P(c7ccccc7)c8ccccc8 InChI 1S/C41H34P2/c1-5-17-33(18-6-1)42(34-19-7-2-8-20-34)37-25-13-15-31-27-29-41(39(31)37)30-28-32-16-14-26-38(40(32)41)43(35-21-9-3-10-22-35)36-23-11-4-12-24-36/h1-26H,27-30H2 Inchi Key DKZNVWNOOLQCMJ-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-SEGPHOS®
Empirical Formula (Hill Notation): C38H28O4P2 CAS Number: 210169-54-3 Molecular Weight: 610.57 MDL number: MFCD09753005 PubChem Substance ID: 329761551 NACRES: NA.22
Кат. номер 693006-50MG 693006-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
Chiral biaryl bisphosphine catalytic ligand used for:- Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes
- Stereoselective preparation of homoallylic alcohols via Ir-catalyzed stereoselective transfer hydrogenative crotylation of an allylic acetate with alcohols or aldehydes
- Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives
- Diastereo- and enantioselective hydrogenation of -amino--keto ester hydrochlorides catalyzed by an iridium complex
- Preparation of dihydroisoquinolinones via nickel-catalyzed denitrogenative annulation of benzotriazinones with 1,3-dienes and alkenes
- Stereoselective preparation of indanol derivatives via Rh-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes
Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.ПараметрыQuality Level 100, assay 94% optical activity []20/D -11°, c = 0.5 in chloroform mp 231-235 °C InChI 1S/C38H28O4P2/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30/h1-24H,25-26H2 InChI key RZZDRSHFIVOQAF-UHFFFAOYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-SIPHOS-PE
Empirical Formula (Hill Notation): C33H32NO2P CAS Number: 500997-70-6 Molecular Weight: 505.59 MDL number: MFCD08459342 PubChem Substance ID: 329762229 NACRES: NA.22
Кат. номер 700762-50MG 700762-250MG Application(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:- Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
- Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones.
- Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.
Packaging50, 250 mg in amber glass bottleПараметрыQuality Level 100, assay 97% optical activity []22/D 65.0°, c = 1 in chloroform mp 120-125 °C storage temp. 20°C SMILES string C[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7 InChI 1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1 Inchi Key ZXLQLIDJAURBDD-HRPAVAKOSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P261 - P305 + P351 + P338 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-T-BINAP
Empirical Formula (Hill Notation): C48H40P2 CAS Number: 100165-88-6 Molecular Weight: 678.78 MDL number: MFCD01311709 PubChem Substance ID: 329761556 NACRES: NA.22
Кат. номер 693030-500MG 693030-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO3, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form -aminoamides. It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.Packaging100 mg in glass bottle
500 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.Параметрыoptical activity []20/D -156°, c = 0.5 in benzene Quality Level 100, mp 250-255 °C InChI 1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3 InChI key IOPQYDKQISFMJI-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-TCYP T511609-100MG
Empirical Formula (Hill Notation): C68H81O4P Molecular Weight: 993.34 Other NotesPlease note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.ПараметрыQuality Level 100, refractive index n/D SMILES string OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)C6CCCCC6)C7CCCCC7
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Tol-SDP 700835-50MG
Empirical Formula (Hill Notation): C45H42P2 CAS Number: 817176-80-0 Molecular Weight: 644.76 MDL number: MFCD08459345 PubChem Substance ID: 329762236 NACRES: NA.22 Параметрыoptical activity []22/D 206°, c = 1 in chloroform Quality Level 100, mp 154-161 °C storage temp. 20°C SMILES string Cc1ccc(cc1)P(c2ccc(C)cc2)c3cccc4CCC5(CCc6cccc(P(c7ccc(C)cc7)c8ccc(C)cc8)c56)c34 InChI 1S/C45H42P2/c1-31-11-19-37(20-12-31)46(38-21-13-32(2)14-22-38)41-9-5-7-35-27-29-45(43(35)41)30-28-36-8-6-10-42(44(36)45)47(39-23-15-33(3)16-24-39)40-25-17-34(4)18-26-40/h5-26H,27-30H2,1-4H3 InChI key VLIOMJFCGWZUON-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-VANOL
Empirical Formula (Hill Notation): C32H22O2 CAS Number: 147702-14-5 Molecular Weight: 438.52 MDL number: MFCD08459338 PubChem Substance ID: 24884836 NACRES: NA.22
Кат. номер 676098-250MG 676098-250G ApplicationVANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
(S)-VANOL is a vaulted biaryl ligand that may be used in the synthesis of coordinated complexes, such as (dppe)Pt(S-VANOL) [dppe= bis(diphenylphosphino)ethane] and (S,S-chiraphos)Pt(S-VANOL) [chiraphos= 2,3-bis(diphenylphosphino)butane].Packaging250 mg in amber glass bottleПараметрыQuality Level 100, assay 97% optical activity []20/D -314°, c = 1 in chloroform mp 199-203 °C SMILES string Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6 InChI 1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H InChI key NDTDVKKGYBULHF-UHFFFAOYSA-N
Safety Informationpictograms GHS05,GHS07 signalword Danger hcodes H315 - H318 - H335 - H413 pcodes P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-VAPOL
Empirical Formula (Hill Notation): C40H26O2 CAS Number: 147702-15-6 Molecular Weight: 538.63 EC Number: 200-838-9 MDL number: MFCD11617354 PubChem Substance ID: 24885273 NACRES: NA.22
Кат. номер 675334-100MG 675334-500MG 675334-250MG Packaging100 mg in clear glass bottle
500 mg in amber glass bottleApplicationVAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.ПараметрыQuality Level 100, assay 97% optical activity []20/D 128°, c = 1 in chloroform mp 185-191 °C SMILES string Oc1c(c(cc2ccc3ccccc3c12)-c4ccccc4)-c5c(O)c6c(ccc7ccccc67)cc5-c8ccccc8 InChI 1S/C40H26O2/c41-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)42/h1-24,41-42H InChI key UFYXKDMLGBKHIC-UHFFFAOYSA-N
Safety Informationpictograms GHS07,GHS08 signalword Warning hcodes H315 - H319 - H351 pcodes P201 - P302 + P352 - P305 + P351 + P338 - P308 + P313 RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-VAPOL hydrogenphosphate
Empirical Formula (Hill Notation): C40H25O4P CAS Number: 871130-17-5 Molecular Weight: 600.60 MDL number: MFCD09265084 PubChem Substance ID: 329760854 NACRES: NA.22
Кат. номер 688320-500MG 688320-100MG ApplicationCatalyst for:- Benzoyloxylation of (aryl)oxindoles with benzoyl peroxide
- Enantioselective synthesis of homoaldols and cyclic acetals via kinetic resoln of homoaldols
- Desymmetrization of mono- and bicyclic N-acyl meso-aziridines by ring opening
- Highly enantioselective addition of imides to imines to give aminals
- Friedel-Crafts reaction of pyrroles with benzylidenebenzamides
Packaging100 mg in clear glass bottle
500 mg in amber glass bottleПараметрыoptical activity []22/D +412°, c = 1 in chloroform Quality Level 100, mp >400 °C InChI 1S/C40H25O4P/c41-45(42)43-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)44-45/h1-24H,(H,41,42) Inchi Key YKIJNEDTUDPMNC-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-Xyl-SDP 700851-50MG
Empirical Formula (Hill Notation): C49H50P2 CAS Number: 528521-89-3 Molecular Weight: 700.87 MDL number: MFCD08459343 PubChem Substance ID: 329762238 NACRES: NA.22 ПараметрыQuality Level 100, optical activity []22/D 62.0°, c = 1 in chloroform mp >300 °C storage temp. 20°C SMILES string Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cccc4CCC5(CCc6cccc(P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8)c56)c34 InChI 1S/C49H50P2/c1-31-19-32(2)24-41(23-31)50(42-25-33(3)20-34(4)26-42)45-13-9-11-39-15-17-49(47(39)45)18-16-40-12-10-14-46(48(40)49)51(43-27-35(5)21-36(6)28-43)44-29-37(7)22-38(8)30-44/h9-14,19-30H,15-18H2,1-8H3 InChI key AZSBNBQMIMQOPG-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-[(RuCl(BINAP))2(-Cl)3][NH2Me2]
Empirical Formula (Hill Notation): C90H72Cl5NP4Ru2 Linear Formula: (CH3)2NH2+[C88H64Cl5P4Ru2]− CAS Number: 199541-17-8 Molecular Weight: 1670.84 MDL number: MFCD09753033 PubChem Substance ID: 329761565
Кат. номер 693138-500MG 693138-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging100, 500 mg in glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.ПараметрыQuality Level 100, storage temp. 2-8°C SMILES string Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.c3ccc(cc3)P(c4ccccc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccccc9)c%10ccccc%10.c%11ccc(cc%11)P(c%12ccccc%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17ccccc%17)c%18ccccc%18 InChI 1S/2C44H32P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1 InChI key FRRCROPKBKLCMQ-UHFFFAOYSA-M
Safety Informationpictograms GHS02 signalword Warning hcodes H228 pcodes P210 Personal Protective Equipment Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-[(RuCl(H8-BINAP))2(-Cl)3][NH2Me2]
Empirical Formula (Hill Notation): C90H88Cl5NP4Ru2 Linear Formula: (CH3)2NH2+[C88H80Cl5P4Ru2]- CAS Number: 944451-12-1 Molecular Weight: 1686.97 MDL number: MFCD09753036 PubChem Substance ID: 329761584 NACRES: NA.22
Кат. номер 693324-50MG 693324-100MG Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.Параметрыstorage temp. 2-8°C Quality Level 100, InChI 1S/2C44H40P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-12,19-26,29-32H,13-18,27-28H2;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1 InChI key BQQWMTMUAYPPMV-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-[(RuCl(SEGPHOS®))2(-Cl)3][NH2Me2]
Empirical Formula (Hill Notation): C78H64Cl5NO8P4Ru2 Linear Formula: (CH3)2NH2+[C76H56Cl5O8P4Ru2]− CAS Number: 488809-34-3 Molecular Weight: 1646.64 MDL number: MFCD09753037 PubChem Substance ID: 329761568 NACRES: NA.22
Кат. номер 693162-50MG 693162-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging50, 100 mg in amber glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. JP Registration No. 3148136, 3549390
SEGPHOS is a registered trademark of Takasago Intl. Corp.Параметрыstorage temp. 2-8°C Quality Level 100, InChI 1S/2C38H28O4P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-3-2;;;;;;;/h2*1-24H,25-26H2;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1 InChI key RENFEASRVBXAEN-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)-[(RuCl(T-BINAP))2(-Cl)3[NH2Me2]
Empirical Formula (Hill Notation): C98H88Cl5NP4Ru2 Linear Formula: (CH3)2NH2+[C96H80Cl5P4Ru2]- CAS Number: 309735-86-2 Molecular Weight: 1783.05 MDL number: MFCD09753034 PubChem Substance ID: 329761566 NACRES: NA.22
Кат. номер 693146-500MG 693146-100MG ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,Packaging100, 500 mg in glass bottleLegal InformationSold in collaboration with Takasago for research purposes only.Параметрыstorage temp. 2-8°C Quality Level 100, InChI 1S/2C48H40P2.C2H7N.2ClH.3Cl.2Ru/c2*1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-3-2;;;;;;;/h2*5-32H,1-4H3;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1 InChI key QGBBTZBFEYSGDQ-UHFFFAOYSA-M
Safety Informationpictograms GHS02 signalword Warning hcodes H228 pcodes P210 Personal Protective Equipment Eyeshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline 717398-100MG
Empirical Formula (Hill Notation): C28H28FeNOP CAS Number: 163169-29-7 Molecular Weight: 481.35 MDL number: MFCD15144869 PubChem Substance ID: 329763485 NACRES: NA.22 Application(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.Packaging100 mg in clear glass bottleLegal InformationSold under license from Kanata Chemical Technologies Inc. for research purposes only.ПараметрыQuality Level 100, assay 97% optical activity []20/D 366°, c = 0.1 in chloroform mp 158-162 °C SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5 InChI 1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1 Inchi Key FELCHLOAEMNOQM-GHVWMZMZSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a]dinaphthalen-4-yl)-(1-phenylethyl)amine
Empirical Formula (Hill Notation): C28H25NO2P CAS Number: 422509-53-3 Molecular Weight: 438.48 MDL number: MFCD04117689 PubChem Substance ID: 24884731 NACRES: NA.22
Кат. номер 665347-500MG 665347-100MG ApplicationDSM MonoPhos Family of Highly Efficient Privileged Ligands,Packaging100 mg in clear glass bottle
500 mg in glass bottleLegal InformationSold under license from DSM for research purposes only.ПараметрыQuality Level 100, assay 96% mp 213-220 °C SMILES string C[C@@H](NP1Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45)c6ccccc6 InChI 1S/C28H22NO2P/c1-19(20-9-3-2-4-10-20)29-32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-19,29H,1H3/t19-/m1/s1 Inchi Key OXUOPBPAVLQNGC-LJQANCHMSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,R)-Noscapine
Empirical Formula (Hill Notation): C22H23NO7 CAS Number: 128-62-1 Molecular Weight: 413.42 EC Number: 204-899-2 MDL number: MFCD00069316 PubChem Substance ID: 24862408 NACRES: NA.22
Кат. номер 363960-5G 363960-25G General description(S,R)-Noscapine is a phthalideisoquinoline alkaloid found in opium. It is an antimicrotubule agent that also shows potent antitumor activity.ApplicationNoscapine may be used as a source to synthesize its bromo-derivatives, which has higher tubulin binding activity when compared to noscapine. Its 3,4,5-trimethoxybenzyl analog is a potential antitumor agent.Packaging5 g in glass bottleOther NotesTandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 363960.pdf , Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.,ПараметрыQuality Level 100, assay 97% optical activity []20/D 200°, c = 1 in chloroform mp 174-176 °C (lit.) SMILES string COc1ccc2C(OC(=O)c2c1OC)C3N(C)CCc4cc5OCOc5c(OC)c34 InChI 1S/C22H23NO7/c1-23-8-7-11-9-14-20(29-10-28-14)21(27-4)15(11)17(23)18-12-5-6-13(25-2)19(26-3)16(12)22(24)30-18/h5-6,9,17-18H,7-8,10H2,1-4H3/t17-,18+/m1/s1 InChI key AKNNEGZIBPJZJG-MSOLQXFVSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 - H336 pcodes P301 + P312 + P330 Target Organs Central nervous system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Empirical Formula (Hill Notation): C36H30NO2P CAS Number: 497883-22-4 Molecular Weight: 539.60 MDL number: MFCD08561138 PubChem Substance ID: 24884733 NACRES: NA.22
Кат. номер 665363-500MG 665363-100MG 665363-2G ApplicationDSM MonoPhos Family of Highly Efficient Privileged Ligands,
Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors. Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation.Packaging2 g in glass bottle
100, 500 mg in glass insertFeatures and BenefitsAdvantages of the MonoPhos® ligands:- Superior enantiocontrol in numerous transformations
- High activities at low catalyst loadings
- Hydrogenations under low-pressure conditions
Legal InformationSold under license from DSM for research purposes only.
MonoPhos is a registered trademark of DSM IP Assets B.V.ПараметрыQuality Level 100, assay 95% (HPLC) mp 102-103 °C SMILES string C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56)c7ccccc7 InChI 1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m1/s1 InChI key LKZPDRCMCSBQFN-CLJLJLNGSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-()-1,2-Di(1-naphthyl)-1,2-ethanediol 482846-250MG
Empirical Formula (Hill Notation): C22H18O2 Linear Formula: [C10H7CH(OH)-]2 CAS Number: 229184-99-0 Molecular Weight: 314.38 MDL number: MFCD01863520 PubChem Substance ID: 24871848 NACRES: NA.22 Application(S, S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol can be used as:- A ligand in the asymmetric sulfoxidation of dihydrothienopyrimidine.
- A reactant for the preparation of (2S,2S)-[(1S,2S)-1,2-bis(naphthalen-1-yl)ethane-1,2-diyl] bis[2-(dimethylamino)propanoate], a chiral bisester ligand via condensation reaction with N,N-dimethylamino acid using aldol-Tishchenko condensation catalyst.
- A reactant to synthesize diol-SnCl4 chiral Bronsted acid complex, which is employed as a catalyst in the allylboration of aldehydes.
Packaging250 mg in amber glass bottleПараметрыQuality Level 100, assay 98% optical activity []23/D 25°, c = 1 in chloroform mp 149-151 °C (lit.) SMILES string O[C@H]([C@@H](O)c1cccc2ccccc12)c3cccc4ccccc34 InChI 1S/C22H18O2/c23-21(19-13-5-9-15-7-1-3-11-17(15)19)22(24)20-14-6-10-16-8-2-4-12-18(16)20/h1-14,21-24H/t21-,22-/m0/s1 InChI key MNRCSHSTIWDUPJ-VXKWHMMOSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-()-2-Amino-1,2-diphenylethanol 671223-500MG
Empirical Formula (Hill Notation): C14H15NO Linear Formula: C6H5CH(NH2)CH(C6H5)OH CAS Number: 23190-17-2 Molecular Weight: 213.28 Beilstein/REAXYS Number: 2806217 MDL number: MFCD03093886 PubChem Substance ID: 329760412 NACRES: NA.22 ПараметрыQuality Level 100, assay 99.5% (HPLC) optical activity []/D -124±3°, c = 0.87 in ethanol optical purity enantiomeric excess: 99.0% (HPLC) mp 116-119 °C storage temp. 2-8°C SMILES string N[C@H]([C@@H](O)c1ccccc1)c2ccccc2 InChI 1S/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14-/m0/s1 InChI key GEJJWYZZKKKSEV-KBPBESRZSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-()-Hydrobenzoin
Empirical Formula (Hill Notation): C14H14O2 Linear Formula: C6H5CH(OH)CH(OH)C6H5 CAS Number: 2325-10-2 Molecular Weight: 214.26 Beilstein/REAXYS Number: 2330888 MDL number: MFCD00064255 PubChem Substance ID: 24855513 NACRES: NA.22
Кат. номер 256269-100MG 256269-500MG 256269-25G 256269-5G 256269-1G General descriptionChiral reagent.Application(S,S)-(-)-Hydrobenzoin may also be used to prepare (1S,2S,1S)- and (1S,2S,1R)-2-(cyclohex-2-enyloxy)-1,2-diphenylethanol, which are intermediates to prepare enantiopure cyclohexitols. The (S,S)-(-)-hydrobenzoin/Ca complex may be used to catalyze the direct asymmetric aldol reaction of acetophenone and pivalaldehyde to form (R)-3-hydroxy-4,4-dimethyl-1-phenylpentan-1-one.
C2 symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.Packaging5, 25 g in glass bottleOther NotesTandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 256269.pdf , Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.,Параметрыassay 99% optical activity []24/D 94°, c = 2.5 in ethanol optical purity ee: 99% (GLC) mp 148-150 °C (lit.) SMILES string O[C@H]([C@@H](O)c1ccccc1)c2ccccc2 InChI 1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14-/m0/s1 InChI key IHPDTPWNFBQHEB-KBPBESRZSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-(+)-2,6-Bis[2-(hydroxydiphenylmethyl)-1-pyrrolidinyl-methyl]-4-methylphenol
Empirical Formula (Hill Notation): C43H46N2O3 Molecular Weight: 638.84 MDL number: MFCD08276890 PubChem Substance ID: 24884980 NACRES: NA.22
Кат. номер 668370-5G 668370-1G Packaging1, 5 g in glass bottleApplicationA useful catalyst in asymmetric aldol, Henry, and Mannich-type reactions.ПараметрыQuality Level 400, assay 95% optical activity []/D +50°, c = 1 in chloroform impurities 6% dichloromethane and/or diethylether mp 93-102 °C SMILES string Cc1cc(CN2CCC[C@H]2C(O)(c3ccccc3)c4ccccc4)c(O)c(CN5CCC[C@H]5C(O)(c6ccccc6)c7ccccc7)c1 InChI 1S/C43H46N2O3/c1-32-28-33(30-44-26-14-24-39(44)42(47,35-16-6-2-7-17-35)36-18-8-3-9-19-36)41(46)34(29-32)31-45-27-15-25-40(45)43(48,37-20-10-4-11-21-37)38-22-12-5-13-23-38/h2-13,16-23,28-29,39-40,46-48H,14-15,24-27,30-31H2,1H3/t39-,40-/m0/s1 InChI key NEOVWBNAXIBNRT-ZAQUEYBZSA-N
Safety Informationpictograms GHS07,GHS08 signalword Warning hcodes H302 + H312 - H315 - H319 - H351 pcodes P202 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313 Supp Hazards EUH019 RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Empirical Formula (Hill Notation): C36H54N2O2 Linear Formula: [[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10 CAS Number: 135616-36-3 Molecular Weight: 546.83 Beilstein/REAXYS Number: 5464823 MDL number: MFCD00191801 PubChem Substance ID: 24865245 NACRES: NA.22
Кат. номер 404438-1G 404438-5G Application(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsens catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.Packaging1, 5 g in glass bottleLegal InformationLicensed through Research Corporation TechnologiesПараметрыQuality Level 100, assay 98% optical activity []20/D +315 to 15°, c = 1 in methylene chloride mp 203-206 °C (lit.) SMILES string CC(C)(C)c1cc(\C=N\[C@H]2CCCC[C@@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C InChI 1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m0/s1 Inchi Key FYNXDGNCEBQLGC-GTHUDTLPSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
Empirical Formula (Hill Notation): C36H52CoN2O2 Linear Formula: [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co CAS Number: 188264-84-8 Molecular Weight: 603.74 MDL number: MFCD01631278 PubChem Substance ID: 24871025 NACRES: NA.22
Кат. номер 474606-25G 474606-5G 474606-1G Application(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) may be used as a catalyst for the Jacobsens hydrolytic kinetic resolution of racemic epoxides, which is a key step during the multi-step synthesis of (+)-patulolide C, macrosphelides(I and G), (-)-(3S,6R)-3,6-dihydroxy-10-methylundecanoic acid, dodoneine, epidodoneine and protein kinase C epsilon (PKCe) inhibitors.
Catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.Packaging1, 5, 25 g in glass bottleLegal InformationSold under license from Sterling Pharma Solutions Limited.ПараметрыQuality Level 200, mp >350 °C (lit.) SMILES string CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C InChI 1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m0./s1 Inchi Key ZFWPDJKMASHRPT-IKKUFEJKSA-L
Safety InformationPersonal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Empirical Formula (Hill Notation): C36H52ClMnN2O2 Linear Formula: [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl CAS Number: 135620-04-1 Molecular Weight: 635.20 MDL number: MFCD02101663 PubChem Substance ID: 24865247 NACRES: NA.22
Кат. номер 404454-5G 404454-25G 404454-1G General description(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.ApplicationReactant involved in:- Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity
- Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)
- Synthesis of derivatvies for studies of conformational models of enantioselective reactions
Catalyst involved in:- Asymmetric epoxidation of olefins
- Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols†
- Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene
Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsens catalyst has also been used in the asymmetric -hydroxylation of silyl enol ethers. Catalyst for the enantioselective epoxidation of a variety of olefins.Packaging1, 5, 25 g in glass bottleLegal InformationManufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.ПараметрыQuality Level 200, mp 330-332 °C (lit.) SMILES string CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C InChI 1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1 Inchi Key LJVAWOSDJSQANR-RUIQGICGSA-K
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-(+)-N,N-Dimethyl-1,2-cyclohexanediamine 669660-1G
Empirical Formula (Hill Notation): C8H18N2 CAS Number: 87583-89-9 Molecular Weight: 142.24 Beilstein/REAXYS Number: 4304824 MDL number: MFCD00671528 PubChem Substance ID: 329760345 NACRES: NA.22 Application(S,S)-(+)-N,N-Dimethyl-1,2-cyclohexanediamine can be used:- To synthesize derivatives of -diazophosphonic acid, which are employed in O-H and N-H insertion reactions.
- As a starting material for the synthesis of -chloro--alkylphosphonic acids.
- To prepare C2 symmetrical diamine enantiomers of C60 with chirospectrosopic properties.
Packaging1 g in glass bottleПараметрыQuality Level 300, assay 97.0% (GC) optical activity []/D +145±5°, c = 4.47 in chloroform mp 39-44 °C storage temp. 2-8°C SMILES string CN[C@H]1CCCC[C@@H]1NC InChI 1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m0/s1 InChI key JRHPOFJADXHYBR-YUMQZZPRSA-N
Safety Informationpictograms GHS05,GHS07 signalword Danger hcodes H302 - H314 pcodes P260 - P280 - P301 + P312 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN 3259PSN2 8 / PGII WGK Germany WGK 3 Flash Point F 165.2 °F - closed cup Flash Point C 74 °C - closed cup Узнать цену -
(S,S)-1-Naphthyl-DIPAMP
Empirical Formula (Hill Notation): C34H28P2 Molecular Weight: 498.53 MDL number: MFCD12198318 PubChem Substance ID: 329761952
Кат. номер 697788-100MG 697788-500MG ПараметрыQuality Level 100, assay 95% optical activity []22/D 19.0, c = 1 in chloroform mp 140-144 °C SMILES string C(CP(c1ccccc1)c2cccc3ccccc23)P(c4ccccc4)c5cccc6ccccc56 InChI 1S/C34H28P2/c1-3-17-29(18-4-1)35(33-23-11-15-27-13-7-9-21-31(27)33)25-26-36(30-19-5-2-6-20-30)34-24-12-16-28-14-8-10-22-32(28)34/h1-24H,25-26H2/t35-,36-/m0/s1 InChI key AJLHFWYWUUCAAX-ZPGRZCPFSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany 3 Узнать цену -
(S,S)-2,2-Bipyrrolidine D-tartrate trihydrate
Empirical Formula (Hill Notation): C8H16N2 · C4H6O6 · 3H2O CAS Number: 136937-03-6 Molecular Weight: 344.36 Beilstein/REAXYS Number: 5387052 MDL number: MFCD11656042 PubChem Substance ID: 329761189
Кат. номер 688746-5G 688746-1G ПараметрыQuality Level 100, assay 98.5% (sum of enantiomers, GC), 99% optical purity ee: 99.5% (GC) mp 117-118 °C (dec.) (lit.) SMILES string O.O.O.O[C@@H]([C@H](O)C(O)=O)C(O)=O.C1CNC(C1)C2CCCN2 InChI 1S/C8H16N2.C4H6O6.3H2O/c1-3-7(9-5-1)8-4-2-6-10-8;5-1(3(7)8)2(6)4(9)10;;;/h7-10H,1-6H2;1-2,5-6H,(H,7,8)(H,9,10);3*1H2/t7-,8-;1-,2-;;;/m00.../s1 Inchi Key XWLGYXKNZXAYBR-KVNOGXSSSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 pcodes P302 + P352 - P305 + P351 + P338 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 694215-100MG
Empirical Formula (Hill Notation): C18H28N2P2 CAS Number: 1107608-80-9 Molecular Weight: 334.38 MDL number: MFCD10567042 PubChem Substance ID: 329761244 NACRES: NA.22 Packaging100 mg in glass bottleLegal InformationQuinoxP is a registered trademark of Nippon Chemical Industry Co., Ltd.Параметрыoptical activity []22/D +55°, c = 1 in chloroform Quality Level 100, mp 100-105 °C SMILES string CP(c1nc2ccccc2nc1P(C)C(C)(C)C)C(C)(C)C InChI 1S/C18H28N2P2/c1-17(2,3)21(7)15-16(22(8)18(4,5)6)20-14-12-10-9-11-13(14)19-15/h9-12H,1-8H3/t21-,22-/m1/s1 Inchi Key DRZBLHZZDMCPGX-FGZHOGPDSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 - H315 - H319 - H335 - H413 pcodes P273 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-DACH-naphthyl Trost Ligand
Empirical Formula (Hill Notation): C52H44N2O2P2 CAS Number: 205495-66-5 Molecular Weight: 790.87 MDL number: MFCD02684552 PubChem Substance ID: 329761527 NACRES: NA.22
Кат. номер 692786-250MG 692786-1G ApplicationTrost Ligands for Asymmetric Allylic Alkylation,
Asymmetric allylic alkylation ligand.Packaging1 g in glass bottle
250 mg in amber glass bottleLegal InformationSold in collaboration with Dr. Reddy′s Laboratories for research purposes only.ПараметрыQuality Level 100, assay 95% optical activity []20/D -66.0°, c = 1 in methanol mp 232-237 °C SMILES string O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9 InChI 1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1 Inchi Key VXFKMKXTPXVEMU-ZYBCLOSLSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-DACH-phenyl Trost ligand
Empirical Formula (Hill Notation): C44H40N2O2P2 CAS Number: 169689-05-8 Molecular Weight: 690.75 MDL number: MFCD01631274 PubChem Substance ID: 329761528
Кат. номер 692794-250MG 692794-1G ApplicationTrost Ligands for Asymmetric Allylic Alkylation,
Asymmetric allylic alkylation ligand.Packaging1 g in glass bottle
250 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.Legal InformationSold in collaboration with Dr. Reddy′s Laboratories for research purposes only.ПараметрыQuality Level 100, assay 95% optical activity []20/D -134°, c = 1 in methanol mp 136-142 °C SMILES string O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7 InChI 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1 Inchi Key AXMSEDAJMGFTLR-ZAQUEYBZSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-DIPAMP
Empirical Formula (Hill Notation): C28H28O2P2 Linear Formula: [CH3OC6H4P(C6H5)CH2]2 CAS Number: 97858-62-3 Molecular Weight: 458.47 MDL number: MFCD05863547 PubChem Substance ID: 329761950
Кат. номер 697753-500MG 697753-100MG ПараметрыQuality Level 100, assay 95% optical activity []22/D +82, c = 1 in chloroform mp 101-105 °C (lit.) SMILES string COc1ccccc1P(CCP(c2ccccc2)c3ccccc3OC)c4ccccc4 InChI 1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m0/s1 Inchi Key QKZWXPLBVCKXNQ-ACHIHNKUSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Empirical Formula (Hill Notation): C36H52AlClN2O2 CAS Number: 307926-51-8 Molecular Weight: 607.24 MDL number: MFCD02684548 PubChem Substance ID: 24877851 NACRES: NA.22
Кат. номер 531979-1G 531979-5G Application(S,S)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:- In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
- In the cyanation of ,-unsaturated imides to yield saturated imides.
Packaging1 g in glass bottleLegal InformationSold under license from Sterling Pharma Solutions Limited.ПараметрыQuality Level 100, mp >350 °C (lit.) SMILES string CC(C)(C)c1cc2\C=N\[C@H]3CCCC[C@@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C InChI 1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1 Inchi Key KGVBCKDZFMLRMA-RUIQGICGSA-K
Safety Informationpictograms GHS07 signalword Warning hcodes H302 + H312 + H332 pcodes P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Empirical Formula (Hill Notation): C36H30NO2P CAS Number: 380230-02-4 Molecular Weight: 539.60 MDL number: MFCD04117688 PubChem Substance ID: 24884726 NACRES: NA.22
Кат. номер 665290-500MG 665290-100MG 665290-2G ApplicationThe product may be used as a ligand in:- Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
- Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
- Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.
Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors. Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation.
DSM MonoPhos Family of Highly Efficient Privileged Ligands,Packaging2 g in glass bottle
100, 500 mg in glass insertFeatures and BenefitsAdvantages of the MonoPhos® ligands:- Superior enantiocontrol in numerous transformations
- High activities at low catalyst loadings
- Hydrogenations under low-pressure conditions
Legal InformationSold under license from DSM for research purposes only.
MonoPhos is a registered trademark of DSM IP Assets B.V.ПараметрыQuality Level 100, assay 97% mp 88-89 °C SMILES string C[C@H](N([C@@H](C)c1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56)c7ccccc7 InChI 1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m0/s1 InChI key LKZPDRCMCSBQFN-UIOOFZCWSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
(S,S,S)-DiazaPhos-PPE
Empirical Formula (Hill Notation): C46H39N4O4P CAS Number: 615538-63-1 Molecular Weight: 742.80 PubChem Substance ID: 329760955
Кат. номер 685240-100MG 685240-500MG ApplicationDiazaphospholane Ligands for Catalytic Asymmetric Transformations,
Diazaphospholane ligands display excellent levels of conversion and selectivity in Rh-catalyzed asymmetric hydroformylation reactions.Packaging100 mg in clear glass bottle
500 mg in amber glass bottleLegal InformationProduct is sold for R&D purpose only and use by end user in the manufacture of products of commerce is not permitted. Product is sold in association with DowpharmaSM a business unit of The Dow Chemical Company. U.S. Pat. 7,071,357B.Параметрыoptical activity []20/D -27°, c = 1 in chloroform mp 134-159 °C SMILES string C[C@H](NC(=O)c1ccccc1[C@H]2N3N([C@H](P2c4ccccc4)c5ccccc5C(=O)N[C@@H](C)c6ccccc6)C(=O)c7ccccc7C3=O)c8ccccc8 InChI 1S/C46H39N4O4P/c1-30(32-18-6-3-7-19-32)47-41(51)35-24-12-16-28-39(35)45-49-43(53)37-26-14-15-27-38(37)44(54)50(49)46(55(45)34-22-10-5-11-23-34)40-29-17-13-25-36(40)42(52)48-31(2)33-20-8-4-9-21-33/h3-31,45-46H,1-2H3,(H,47,51)(H,48,52)/t30-,31-,45-,46?,55?/m0/s1 Inchi Key XLHCPIVFAWUOET-OQGDIVOVSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany 3 Узнать цену -
(S,S,S)-SPIRAP 905305-50MG
Empirical Formula (Hill Notation): C43H38O2P2 Molecular Weight: 648.71 Application(S,S,S)-SPIRAP is a chiral C2-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation.Other NotesDesign, Synthesis, and Application of Chiral C2-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis,Параметрыassay 95% form powder or crystals reaction suitability reaction type: Asymmetric synthesis mp 226-228 °C SMILES string CC[C@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2
Safety InformationWGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену
Получите коммерческое предложение в течение 1 часа
Менеджер подготовит коммерческое предложение и позвонит, если понадобится уточнить детали вашего заказа
Анна Гловацкая
Менеджер по работе с клиентами
С 2010 года мы поставляем оборудование с заводов Европы. Берем на себя все — от подбора оборудования до внедрения на предприятии
Все сотрудники имеют высшее образование, закончили ведущие химические вузы страны, такие как РХТУ им Менделеева.
У большинства компаний срок ожидания составляет 10-12 недель.
Оборудование хранится на сухом отапливаемом складе, где поддерживается ровная температура.
Работаем с PonyExpress и Деловыми линиями. Вы также можете выбрать свою транспортную компанию или забрать товар со склада в Москве.
В случае любых неполадок за свой счет выполним ремонт в сервисном центре или на заводе-изготовителе. Или бесплатно заменим прибор на новый.
Производим пуско-наладку оборудования, валидацию, обучение сотрудников. Если нужно, привлекаем инженеров с заводов- изготовителей.
