Buchwald Catalysts & Ligands
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Triethylphosphine
Empirical Formula (Hill Notation): C6H15P Linear Formula: (C2H5)3P CAS Number: 554-70-1 Molecular Weight: 118.16 Beilstein/REAXYS Number: 969170 EC Number: 209-068-8 MDL number: MFCD00009256 PubChem Substance ID: 24854512 NACRES: NA.22
Кат. номер 245275-25G 245275-5G ApplicationTriethylphosphine is generally used as a ligand in the organometallic chemistry. It can be used in:- Synthesis of the tetrahedrally coordinated L3Fe-Nx complex with a terminal nitride group.
- Synthesis of (PEt3)2Ni(2-C14H10), a source of the reactive Ni(PEt3)2 moiety.
- Synthesis of dinuclear rhodium complexes with triethyllphosphane bridges.
Packaging25 g in Sure/Seal™
5 g in glass bottleOther NotesThis container should be opened only by a technically qualified person.ПараметрыQuality Level 100, assay 99% reaction suitability reagent type: ligand
reaction type: Arylationsrefractive index n20/D 1.456 (lit.) bp 127-128 °C (lit.) density 0.802 g/mL at 20 °C (lit.) functional group phosphine SMILES string CCP(CC)CC InChI 1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3 InChI key RXJKFRMDXUJTEX-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05 signalword Danger hcodes H250 - H314 pcodes P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P370 + P378 Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 2845 4.2 WGK Germany WGK 3 Узнать цену -
Triethylphosphine oxide
Empirical Formula (Hill Notation): C6H15OP Linear Formula: (C2H5)3PO CAS Number: 597-50-2 Molecular Weight: 134.16 MDL number: MFCD00013914 PubChem Substance ID: 24880030 NACRES: NA.22
Кат. номер 562394-1G 562394-5G ПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 48-52 °C (lit.) functional group phosphine SMILES string CCP(=O)(CC)CC InChI 1S/C6H15OP/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3 InChI key ZSSWXNPRLJLCDU-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Triethylphosphine solution 346179-50ML
Empirical Formula (Hill Notation): C6H15P Linear Formula: (C2H5)3P CAS Number: 554-70-1 Molecular Weight: 118.16 Beilstein/REAXYS Number: 969170 MDL number: MFCD00009256 PubChem Substance ID: 24861378 NACRES: NA.22 ApplicationCatalyst for:- Regioselective formation of alcohols from hydrocarbonylation of alkenes
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates
- Silaboration of enynes
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles
- Thermal decomposition of platinum and palladium naphthalenediyl
- Asymmetrical Morita-Baylis-Hillman reaction
Packaging50 mL in Sure/Seal™ПараметрыQuality Level 100, reaction suitability reagent type: ligand
reaction type: Arylationsconcentration 1.0 M in THF density 0.869 g/mL at 25 °C functional group phosphine SMILES string CCP(CC)CC InChI 1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3 Inchi Key RXJKFRMDXUJTEX-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07,GHS08 signalword Danger hcodes H225 - H250 - H302 - H314 - H335 - H336 - H351 pcodes P201 - P210 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P370 + P378 Supp Hazards EUH018 - EUH019 Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 1993BF 3 / PGII WGK Germany WGK 3 Flash Point F -4.0 °F - closed cup Flash Point C -20 °C - closed cup Узнать цену -
Triethylphosphine solution 901439-25ML
Empirical Formula (Hill Notation): C6H15P Linear Formula: (C2H5)3P CAS Number: 554-70-1 Molecular Weight: 118.16 Beilstein/REAXYS Number: 969170 MDL number: MFCD00009256 ApplicationCatalyst for:- Regioselective formation of alcohols from hydrocarbonylation of alkenes
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates
- Silaboration of enynes
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles
- Thermal decomposition of platinum and palladium naphthalenediyl
- Asymmetrical Morita-Baylis-Hillman reaction
Offered as the toluene solution for more convenient handling, triethylphosphine is a valuable ligand for- Regioselective formation of alcohols from hydrocarbonylation of alkenes.
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates.
- Silaboration of enynes.
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles.
- Thermal decomposition of platinum and palladium naphthalenediyl.
- Asymmetrical Morita-Baylis-Hillman reaction.
Параметрыform liquid Quality Level 100, reaction suitability reagent type: ligand
reaction type: Arylationsconcentration 1.0 M in toluene density 0.857 g/mL functional group phosphine SMILES string CCP(CC)CC InChI 1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3 Inchi Key RXJKFRMDXUJTEX-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07,GHS08 signalword Danger hcodes H225 - H250 - H304 - H314 - H336 - H361d - H373 - H412 pcodes P210 - P280 - P301 + P310 + P331 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P370 + P378 Target Organs Central nervous system RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F 44.6 °F Flash Point C 7 °C Узнать цену -
Triethylphosphine solution 901440-25ML
Empirical Formula (Hill Notation): C6H15P Linear Formula: (C2H5)3P CAS Number: 554-70-1 Molecular Weight: 118.16 Beilstein/REAXYS Number: 969170 MDL number: MFCD00009256 ApplicationOffered as the 2-methyltetrahydrofuran solution for more convenient handling, triethylphosphine is a valuable ligand for:- Regioselective formation of alcohols from hydrocarbonylation of alkenes.
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates.
- Silaboration of enynes.
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles.
- Thermal decomposition of platinum and palladium naphthalenediyl.
- Asymmetrical Morita-Baylis-Hillman reaction.
Catalyst for:- Regioselective formation of alcohols from hydrocarbonylation of alkenes
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates
- Silaboration of enynes
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles
- Thermal decomposition of platinum and palladium naphthalenediyl
- Asymmetrical Morita-Baylis-Hillman reaction
Параметрыform liquid Quality Level 100, reaction suitability reagent type: ligand
reaction type: Arylationsconcentration 1.0 M in 2-methyltetrahydrofuran density 0.843 g/mL functional group phosphine SMILES string CCP(CC)CC InChI 1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3 Inchi Key RXJKFRMDXUJTEX-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07 signalword Danger hcodes H225 - H250 - H302 - H314 pcodes P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P370 + P378 Supp Hazards EUH019 RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F 8.6 °F Flash Point C -13 °C Узнать цену -
Triisopropylphosphine
Empirical Formula (Hill Notation): C9H21P Linear Formula: [(CH3)2CH]3P CAS Number: 6476-36-4 Molecular Weight: 160.24 Beilstein/REAXYS Number: 906732 EC Number: 229-333-1 MDL number: MFCD00015029 PubChem Substance ID: 24863218
Кат. номер 377309-250MG 377309-1G Параметрыgrade technical grade reaction suitability reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligandrefractive index n20/D 1.466 (lit.) bp 81 °C/22 mmHg (lit.) density 0.839 g/mL at 25 °C (lit.) functional group phosphine SMILES string CC(C)P(C(C)C)C(C)C InChI 1S/C9H21P/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3 Inchi Key IGNTWNVBGLNYDV-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05 signalword Danger hcodes H250 - H314 pcodes P222 - P231 - P280 - P305 + P351 + P338 - P310 - P422 Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F 221.0 °F - closed cup Flash Point C 105 °C - closed cup Узнать цену -
Triisopropylphosphonium tetrafluoroborate 698466-500MG
Empirical Formula (Hill Notation): C9H22BF4P CAS Number: 121099-07-8 Molecular Weight: 248.05 PubChem Substance ID: 329761257 NACRES: NA.22 ApplicationReactant for:- Synthesis of triisopropylphosphine complexes of ruthenium(II)
- Imine hydrogenation
- Dihydride and alkene-6-arene complexes
Packaging500 mg in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand functional group phosphine SMILES string F[B-](F)(F)F.CC(C)[PH+](C(C)C)C(C)C InChI 1S/C9H21P.BF4/c1-7(2)10(8(3)4)9(5)6;2-1(3,4)5/h7-9H,1-6H3;/q;-1/p+1 Inchi Key KGBIZABAOCDZNU-UHFFFAOYSA-O
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Trimethylphosphine 323322-25G
Empirical Formula (Hill Notation): C3H9P Linear Formula: (CH3)3P CAS Number: 594-09-2 Molecular Weight: 76.08 Beilstein/REAXYS Number: 969138 EC Number: 209-823-1 MDL number: MFCD00008510 PubChem Substance ID: 24859357 ApplicationTrimethylphosphine (PMe3) is an electron-rich phosphine ligand used as a reagent in Mitsunobu reaction.
It can be used:- In transformation of azides into carbamates; aziridines to azidoalcohols; and ketoximes to ketones with 2,2-dipyridyl diselenide.
- In Aza-Wittig reaction;, C-H bond activation of imines; cross-coupling reactions.
- In the preparation of (cyanomethylene) trimethylphosphorane (CMMP) which is used as a reagent in Mitsunobu type reaction.
- As a reagent in the synthesis of ruthenium trimethylphosphine complexes, which in turn are used as catalysts for hydrogenation of CO2 to formic acid.
Packaging25 g in Sure/Seal™Параметрыvapor pressure 7.24 psi ( 20 °C) Quality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reactionrefractive index n20/D 1.428 (lit.) bp 38-40 °C (lit.) mp 86 °C (lit.) density 0.738 g/mL at 20 °C (lit.) functional group phosphine storage temp. 2-8°C SMILES string CP(C)C InChI 1S/C3H9P/c1-4(2)3/h1-3H3 Inchi Key YWWDBCBWQNCYNR-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07 signalword Danger hcodes H225 - H315 - H319 - H335 pcodes P210 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment Eyeshields,, Faceshields,, Gloves, RIDADR UN 1993BE 3 / PGII WGK Germany WGK 3 Flash Point F -2.2 °F - closed cup Flash Point C -19 °C - closed cup Узнать цену -
Trimethylphosphine solution 324108-100ML
Empirical Formula (Hill Notation): C3H9P Linear Formula: (CH3)3P CAS Number: 594-09-2 Molecular Weight: 76.08 Beilstein/REAXYS Number: 969138 MDL number: MFCD00008510 PubChem Substance ID: 24859423 NACRES: NA.22 General descriptionTrimethylphosphine is the reagent used in Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. Electron diffraction study of trimethylphosphine has been reported.ApplicationTrimethylphosphine (PMe3) solution is the suitable reagent used in the synthesis of Fe/Te cluster type complex, Fe6Te8(PMe3)6. It may be employed as a probe to investigate the acid sites in Y-zeolite. It may be used for the synthesis of hexakis(trimethylphosphine)tris-µ-methylene-diruthenium(III).Packaging100 mL in Sure/Seal™ПараметрыQuality Level 100, reaction suitability reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reactionconcentration 1.0 M in THF density 0.872 g/mL at 25 °C functional group phosphine SMILES string CP(C)C InChI 1S/C3H9P/c1-4(2)3/h1-3H3 InChI key YWWDBCBWQNCYNR-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07,GHS08 signalword Danger hcodes H225 - H302 - H315 - H319 - H335 - H351 pcodes P201 - P210 - P233 - P261 - P280 - P304 + P340 + P312 Target Organs Respiratory system Supp Hazards EUH018 - EUH019 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 1993BF 3 / PGII WGK Germany WGK 3 Flash Point F -22.0 °F - closed cup Flash Point C -30 °C - closed cup Узнать цену -
Trimethylphosphine solution 324116-100ML
Empirical Formula (Hill Notation): C3H9P Linear Formula: (CH3)3P CAS Number: 594-09-2 Molecular Weight: 76.08 Beilstein/REAXYS Number: 969138 MDL number: MFCD00008510 PubChem Substance ID: 24859424 NACRES: NA.22 Packaging100 mL in Sure/Seal™ApplicationReagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.ПараметрыQuality Level 100, reaction suitability reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reactionconcentration 1.0 M in toluene density 0.854 g/mL at 25 °C functional group phosphine SMILES string CP(C)C InChI 1S/C3H9P/c1-4(2)3/h1-3H3 Inchi Key YWWDBCBWQNCYNR-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07,GHS08 signalword Danger hcodes H225 - H304 - H315 - H336 - H361d - H373 - H412 pcodes P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313 Target Organs Central nervous system Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN1993 - class 3 - PG 2 - RQ - VP <= 110kPa - Flammable liquids, n.o.s., HI: all WGK Germany WGK 3 Flash Point F -4.0 °F Flash Point C -20 °C Узнать цену -
Trimethylphosphine solution 901443-25ML
Empirical Formula (Hill Notation): C3H9P Linear Formula: (CH3)3P CAS Number: 594-09-2 Molecular Weight: 76.08 Beilstein/REAXYS Number: 969138 MDL number: MFCD00008510 ApplicationTrimethylphosphine is an electron-rich phosphine ligand used in the Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.Параметрыform liquid Quality Level 100, reaction suitability reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reactionconcentration 0.9 M in 2-methyltetrahydrofuran density 0.838 g/mL functional group phosphine SMILES string CP(C)C InChI 1S/C3H9P/c1-4(2)3/h1-3H3 InChI key YWWDBCBWQNCYNR-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07 signalword Danger hcodes H225 - H302 - H315 - H318 pcodes P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 Supp Hazards EUH019 RIDADR UN 1993BF 3 / PGII WGK Germany WGK 3 Flash Point F 5.0 °F Flash Point C -15 °C Узнать цену -
Trioctylphosphine
Empirical Formula (Hill Notation): C24H51P Linear Formula: [CH3(CH2)7]3P CAS Number: 4731-53-7 Molecular Weight: 370.64 Beilstein/REAXYS Number: 1776995 EC Number: 225-234-2 MDL number: MFCD00015298 PubChem Substance ID: 329763556 NACRES: NA.22
Кат. номер 718165-500ML 718165-2L 718165-100ML ApplicationTrioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides. It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.Packaging100, 500 mL in Sure/Seal™
2 L in Sure/Seal™ПараметрыQuality Level 100 assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand refractive index n20/D 1.468 (lit.) bp 284-291 °C/50 mmHg (lit.) density 0.831 g/mL at 25 °C (lit.) functional group phosphine SMILES string CCCCCCCCP(CCCCCCCC)CCCCCCCC InChI 1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3 InChI key RMZAYIKUYWXQPB-UHFFFAOYSA-N
Safety InformationPictograms GHS05 Signal Word Danger Hazard Statements H314 Precautionary Statements P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 RIDADR UN 1760 8 / PGII WGK Germany WGK 2 Flash Point(F) 296.6 °F - closed cup Flash Point(C) 147 °C - closed cup Узнать цену -
Trioctylphosphine oxide
Empirical Formula (Hill Notation): C24H51OP Linear Formula: [CH3(CH2)7]3PO CAS Number: 78-50-2 Molecular Weight: 386.63 Beilstein/REAXYS Number: 1796648 EC Number: 201-121-3 MDL number: MFCD00002083 PubChem Substance ID: 24861379 NACRES: NA.22
Кат. номер 346187-100G 346187-500G Packaging100, 500 g in glass bottleApplicationUsed as an extraction or stabilizing agent; also useful as a capping ligand for the production of quantum dots such as CdSe.Legal InformationTOPO is a registered trademark of Life TechnologiesПараметрыgrade technical grade Quality Level 100, assay 90% reaction suitability reagent type: ligand bp 201-202 °C/2 mmHg (lit.) mp 50-52 °C (lit.) functional group phosphine SMILES string CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC InChI 1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3 Inchi Key ZMBHCYHQLYEYDV-UHFFFAOYSA-N
Safety Informationpictograms GHS05 signalword Danger hcodes H315 - H318 pcodes P280 - P305 + P351 + P338 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 2 Flash Point F 230.0 °F - closed cup Flash Point C 110 °C - closed cup Узнать цену -
Triphenylphosphine
Empirical Formula (Hill Notation): C18H15P Linear Formula: (C6H5)3P CAS Number: 603-35-0 Molecular Weight: 262.29 Beilstein/REAXYS Number: 610776 EC Number: 210-036-0 MDL number: MFCD00003043 PubChem Substance ID: 24900530
Кат. номер T84409-VAR T84409-100G T84409-10KG T84409-500G T84409-1KG T84409-25G T84409-1G General descriptionRhodium and triphenylphosphine catalyst system has been used for the hydroformylation of soybean, safflower and linseed oils and their methyl esters. Polymer supported triphenylphosphine has been reported to efficiently catalyze the -addition of pronucleophiles to alkynoate. Triphenylphosphine reacts with hydrated ruthenium trichloride in methanol to afford [RuCl2(PPh3)4], [RuCl2(PPh3)3] and [RuCl3(PPh3)2CH3OH]. It participates in the Heck reaction of 4-bromoanisole and ethyl acrylate in ionic liquids.ApplicationTriphenylphosphine was used in the synthesis of mono-6-amino-deoxy-6-cyclodextrin. It was also employed as catalyst during the synthesis of C-aryl furanosides.Packaging1, 25, 100, 500 g in poly bottle
1 kg in poly bottle
10 kg in poly drumLegal InformationReagentPlus is a registered trademark of Sigma-Aldrich Co. LLCПараметрыvapor density 9 (vs air) Quality Level 200 vapor pressure 5 mmHg ( 20 °C) product line ReagentPlus® assay 99% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsbp 377 °C (lit.) mp 79-81 °C (lit.) functional group phosphine SMILES string c1ccc(cc1)P(c2ccccc2)c3ccccc3 InChI 1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H InChI key RIOQSEWOXXDEQQ-UHFFFAOYSA-N
Safety InformationPictograms GHS05,GHS07,GHS08 Signal Word Danger Hazard Statements H302 - H317 - H318 - H372 Precautionary Statements P260 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P314 Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves RIDADR NONH for all modes of transport WGK Germany WGK 2 Flash Point(F) 356.0 °F - closed cup Flash Point(C) 180 °C - closed cup Узнать цену -
Triphenylphosphine hydrobromide
Empirical Formula (Hill Notation): C18H16BrP Linear Formula: (C6H5)3P · HBr CAS Number: 6399-81-1 Molecular Weight: 343.20 Beilstein/REAXYS Number: 3633387 EC Number: 229-012-6 MDL number: MFCD00035107 PubChem Substance ID: 24860541 NACRES: NA.22
Кат. номер 338389-25G 338389-5G Packaging5, 25 g in glass bottleApplicationUsed as mild source of anhydrous HBr; catalyst for formation of THP ethers from tertiary alcohols; preparation of phosphonium salts.ПараметрыQuality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 196 °C (dec.) (lit.) functional group phosphine SMILES string Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3 InChI 1S/C18H15P.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H InChI key CMSYDJVRTHCWFP-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN 3261 8 / PGIII WGK Germany WGK 3 Узнать цену -
Triphenylphosphine oxide
Empirical Formula (Hill Notation): C18H15OP Linear Formula: (C6H5)3PO CAS Number: 791-28-6 Molecular Weight: 278.28 Beilstein/REAXYS Number: 745854 EC Number: 212-338-8 MDL number: MFCD00002080 PubChem Substance ID: 24900532 NACRES: NA.22
Кат. номер T84603-25G T84603-100G ApplicationTriphenylphosphine oxide can be used:- As a catalyst in Appel-type chlorination reaction of acyclic primary and secondary alcohols.
- As a catalyst in stereoselective poly and dibromination of ,-unsaturated esters and ,-unsaturated -ketoester compounds.
- As a promotor in the diastereoselective synthesis of -ribofuranosides through ribofuranosylation of alcohols with ribofuranosyl iodides.
Packaging25, 100 g in poly bottleПараметрыQuality Level 200 assay 98% reaction suitability reagent type: ligand
reaction type: Coupling Reactions, reagent type: ligand
reaction type: Epoxidations, reagent type: ligand
reaction type: Michael Reactionmp 150-157 °C (lit.) functional group phosphine SMILES string O=P(c1ccccc1)(c2ccccc2)c3ccccc3 InChI 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H InChI key FIQMHBFVRAXMOP-UHFFFAOYSA-N
Safety InformationPictograms GHS07 Signal Word Warning Hazard Statements H302 - H412 Precautionary Statements P264 - P270 - P273 - P301 + P312 - P501 Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves RIDADR NONH for all modes of transport WGK Germany WGK 2 Flash Point(F) 356.0 °F Flash Point(C) 180 °C Узнать цену -
Triphenylphosphine oxide, polymer-bound
MDL number: MFCD07371303 PubChem Substance ID: 24884104 NACRES: NA.22
Кат. номер 655430-25G 655430-5G Packaging5, 25 g in glass bottleApplicationDehydrating reagentПараметрыQuality Level 100, crosslinking 2 % cross-linked with divinylbenzene reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: solution phase peptide synthesis, reagent type: ligand extent of labeling 2.5-3.0 mmol/g P loading particle size 200-400 mesh functional group phosphine
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Triphenylphosphine, polymer-bound
Empirical Formula (Hill Notation): C18H15P Linear Formula: -C6H4P(C6H5)2 CAS Number: 39319-11-4 Molecular Weight: 262.29 MDL number: MFCD00148025 PubChem Substance ID: 57653515 NACRES: NA.22
Кат. номер 93093-INTR 93093-5G 93093-25G 93093-1G ApplicationPolymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:- For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
- To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
- To isomerize (Z)-nitro olefins to the (E)-isomers.
- To prepare polymer-bound ylides which are useful in Wittig reactions.
- To convert alcohols or carboxylic acids to the corresponding chlorides.
- In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl -amino acids and primary amines to form the corresponding amides.
Packaging5, 25 g in glass bottleOther NotesPolymer-bound triphenylphosphine is used for preparing polymer-bound yields which are highly useful for Wittig reactions; removal of the polymer at the end of the reaction removes all the phosphine oxide.Параметрыreaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: solution phase peptide synthesis, reagent type: ligand Quality Level 200, extent of labeling ~3 mmol/g triphenylphosphine loading matrix crosslinked with 2% DVB particle size 100-200 mesh functional group phosphine oxide SMILES string c1ccc(cc1)P(c2ccccc2)c3ccccc3
Safety InformationPersonal Protective Equipment dust mask type N95 (US),, Eyeshields,, Faceshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
Triphenylphosphineimine hemisulfate salt SYX00009-1G
Empirical Formula (Hill Notation): C18H16NP · 0.5 H2SO4 CAS Number: 109724-97-2 Molecular Weight: 326.34 MDL number: MFCD22123305 PubChem Substance ID: 329826137 Other NotesPlease note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICHS STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.Legal InformationProduct of SynthonixПараметрыreaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand functional group phosphine SMILES string OS(O)(=O)=O.N=P(c1ccccc1)(c2ccccc2)c3ccccc3.N=P(c4ccccc4)(c5ccccc5)c6ccccc6 InChI 1S/2C18H16NP.H2O4S/c2*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-5(2,3)4/h2*1-15,19H;(H2,1,2,3,4) InChI key TYWKDQRXQIUMQQ-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tripropylphosphine
Empirical Formula (Hill Notation): C9H21P Linear Formula: (CH3CH2CH2)3P CAS Number: 2234-97-1 Molecular Weight: 160.24 EC Number: 218-786-0 MDL number: MFCD00015217 PubChem Substance ID: 24860445 NACRES: NA.22
Кат. номер 336971-25G 336971-5G ПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand refractive index n20/D 1.4584 (lit.) bp 72-74 °C/12 mmHg (lit.) density 0.801 g/mL at 25 °C (lit.) functional group phosphine SMILES string CCCP(CCC)CCC InChI 1S/C9H21P/c1-4-7-10(8-5-2)9-6-3/h4-9H2,1-3H3 InChI key KCTAHLRCZMOTKM-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05 signalword Danger hcodes H250 - H314 pcodes P222 - P231 - P280 - P305 + P351 + P338 - P310 - P422 Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F 143.6 °F - closed cup Flash Point C 62 °C - closed cup Узнать цену -
Tris(1-pyrrolidinyl)phosphine
Empirical Formula (Hill Notation): C12H24N3P CAS Number: 5666-12-6 Molecular Weight: 241.31 Beilstein/REAXYS Number: 1343311 MDL number: MFCD01863555 PubChem Substance ID: 329767760 NACRES: NA.22
Кат. номер 775444-500MG 775444-2.5G ApplicationMonodentate P-donor ligand.
Used as a phosphitylation reagent for oligonucleotide synthesis.Packaging2.5 g in glass bottle
500 mg in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand refractive index n20/D 1.528, n20/D 1.53 (lit.) bp 104 °C/0.1 mmHg (lit.) density 1.041 at 25 °C, 1.049 g/mL at 25 °C (lit.) functional group phosphine SMILES string C1CCN(C1)P(N2CCCC2)N3CCCC3 InChI 1S/C12H24N3P/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15/h1-12H2 InChI key PXFLCAQHOZXYED-UHFFFAOYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 209.8 °F Flash Point C 98.8 °C Узнать цену -
Tris(2,4,6-trimethoxyphenyl)phosphine
Empirical Formula (Hill Notation): C27H33O9P Linear Formula: [(CH3O)3C6H2]3P CAS Number: 91608-15-0 Molecular Weight: 532.52 MDL number: MFCD00145467 PubChem Substance ID: 24864423 NACRES: NA.22
Кат. номер 392081-5G 392081-25G ApplicationHighly basic arylphosphine.Packaging5 g in glass bottleПараметрыreaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 155-160 °C (lit.) functional group phosphine SMILES string COc1cc(OC)c(P(c2c(OC)cc(OC)cc2OC)c3c(OC)cc(OC)cc3OC)c(OC)c1 InChI 1S/C27H33O9P/c1-28-16-10-19(31-4)25(20(11-16)32-5)37(26-21(33-6)12-17(29-2)13-22(26)34-7)27-23(35-8)14-18(30-3)15-24(27)36-9/h10-15H,1-9H3 Inchi Key JQKHNBQZGUKYPX-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(2,4,6-trimethylphenyl)phosphine
Empirical Formula (Hill Notation): C27H33P Linear Formula: [(CH3)3C6H2]3P CAS Number: 23897-15-6 Molecular Weight: 388.52 MDL number: MFCD00014912 PubChem Substance ID: 24864641 NACRES: NA.22
Кат. номер 395080-1G 395080-5G ПараметрыQuality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 185-188 °C (lit.) functional group phosphine SMILES string Cc1cc(C)c(P(c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)c(C)c1 InChI 1S/C27H33P/c1-16-10-19(4)25(20(5)11-16)28(26-21(6)12-17(2)13-22(26)7)27-23(8)14-18(3)15-24(27)9/h10-15H,1-9H3 Inchi Key IDXDWPWXHTXJMZ-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(3,5-dimethylphenyl)phosphine 698253-1G
Empirical Formula (Hill Notation): C24H27P Linear Formula: [(CH3)2C6H3]3P CAS Number: 69227-47-0 Molecular Weight: 346.44 MDL number: MFCD03094579 PubChem Substance ID: 329761997 NACRES: NA.22 ApplicationCatalyst for:- Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
- Highly selective rhodium-catalyzed hydrogenation reactions
- Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysisPackaging1 g in glass bottleПараметрыQuality Level 100, assay 96% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 160-165 °C functional group phosphine SMILES string Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3 InChI 1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3 Inchi Key XRALRSQLQXKXKP-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(4-chlorophenyl)phosphine
Empirical Formula (Hill Notation): C18H12Cl3P Linear Formula: (ClC6H4)3P CAS Number: 1159-54-2 Molecular Weight: 365.62 EC Number: 214-596-7 MDL number: MFCD00013639 PubChem Substance ID: 24854999 NACRES: NA.22
Кат. номер 249491-1G 249491-5G ApplicationCatalyst for:- Preparation of chromans and (E,E)-1,3-dienes via reaction of -substituted allenoates with aldehydes
- Solvent-free Heck reactions
Cocatalyst in:- Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
- Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
- Rhodium-catalyzed hydrogenation reactions
- Platinum-catalyzed allylation reactions
Packaging1 g in glass bottleПараметрыQuality Level 100, assay 95% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsmp 100-103 °C (lit.) functional group phosphine SMILES string Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3 InChI 1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H InChI key IQKSLJOIKWOGIZ-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(4-fluorophenyl)phosphine
Empirical Formula (Hill Notation): C18H12F3P Linear Formula: (FC6H4)3P CAS Number: 18437-78-0 Molecular Weight: 316.26 Beilstein/REAXYS Number: 919838 MDL number: MFCD00013553 PubChem Substance ID: 24864642 NACRES: NA.22
Кат. номер 395099-5G 395099-1G General descriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.ApplicationLigand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.
Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids,Packaging5 g in glass bottleПараметрыQuality Level 200, assay 98% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry,.mp 79-83 °C (lit.) functional group phosphine SMILES string Fc1ccc(cc1)P(c2ccc(F)cc2)c3ccc(F)cc3 InChI 1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H Inchi Key GEPJPYNDFSOARB-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(4-methoxy-3,5-dimethylphenyl)phosphine 698261-500MG
Empirical Formula (Hill Notation): C27H33O3P CAS Number: 121898-64-4 Molecular Weight: 436.52 MDL number: MFCD03840342 PubChem Substance ID: 329761998 NACRES: NA.22 ApplicationCatalyst for carbocyanation of alkynesPackaging500 mg in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 174-179 °C functional group phosphine SMILES string COc1c(C)cc(cc1C)P(c2cc(C)c(OC)c(C)c2)c3cc(C)c(OC)c(C)c3 InChI 1S/C27H33O3P/c1-16-10-22(11-17(2)25(16)28-7)31(23-12-18(3)26(29-8)19(4)13-23)24-14-20(5)27(30-9)21(6)15-24/h10-15H,1-9H3 InChI key BDGUINGZRGNLPD-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 - H413 pcodes P273 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(4-methoxyphenyl)phosphine
Empirical Formula (Hill Notation): C21H21O3P Linear Formula: (CH3OC6H4)3P CAS Number: 855-38-9 Molecular Weight: 352.36 EC Number: 212-723-0 MDL number: MFCD00014896 PubChem Substance ID: 24864644 NACRES: NA.22
Кат. номер 395102-5G 395102-1G ПараметрыQuality Level 200, assay 95% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsmp 131-134 °C (lit.) functional group phosphine SMILES string COc1ccc(cc1)P(c2ccc(OC)cc2)c3ccc(OC)cc3 InChI 1S/C21H21O3P/c1-22-16-4-10-19(11-5-16)25(20-12-6-17(23-2)7-13-20)21-14-8-18(24-3)9-15-21/h4-15H,1-3H3 Inchi Key UYUUAUOYLFIRJG-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(4-trifluoromethylphenyl)phosphine
Empirical Formula (Hill Notation): C21H12F9P Linear Formula: ((CF3)C6H4)3P CAS Number: 13406-29-6 Molecular Weight: 466.28 MDL number: MFCD00058883 PubChem Substance ID: 24884812 NACRES: NA.22
Кат. номер 666629-1G 666629-5G ПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 70-75 °C functional group phosphine SMILES string FC(F)(F)c1ccc(cc1)P(c2ccc(cc2)C(F)(F)F)c3ccc(cc3)C(F)(F)F InChI 1S/C21H12F9P/c22-19(23,24)13-1-7-16(8-2-13)31(17-9-3-14(4-10-17)20(25,26)27)18-11-5-15(6-12-18)21(28,29)30/h1-12H Inchi Key PXYCJKZSCDFXLR-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 - H413 pcodes P273 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(diethylamino)phosphine
Empirical Formula (Hill Notation): C12H30N3P Linear Formula: P[N(C2H5)2]3 CAS Number: 2283-11-6 Molecular Weight: 247.36 Beilstein/REAXYS Number: 636187 EC Number: 218-920-8 MDL number: MFCD00009041 PubChem Substance ID: 24855300 NACRES: NA.22
Кат. номер 253189-5G 253189-25G ApplicationTris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize:- 1,1-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.
- 1-Aminomethylisatins by treating with isatin and primary and secondary amines.
It can also be used in the deoxygenation of some cyclic -diketones using fullerene C60.Packaging5, 25 g in glass bottleПараметрыQuality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand refractive index n20/D 1.475 (lit.) bp 80-90 °C/10 mmHg (lit.) density 0.903 g/mL at 25 °C (lit.) functional group phosphine SMILES string CCN(CC)P(N(CC)CC)N(CC)CC InChI 1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3 Inchi Key FDIOSTIIZGWENY-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07 signalword Warning hcodes H226 - H315 - H319 - H335 pcodes P210 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment Eyeshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 1993C 3 / PGIII WGK Germany WGK 3 Flash Point F 138.2 °F - closed cup Flash Point C 59 °C - closed cup Узнать цену -
Tris(dimethylamino)phosphine
Empirical Formula (Hill Notation): C6H18N3P Linear Formula: P[N(CH3)2]3 CAS Number: 1608-26-0 Molecular Weight: 163.20 Beilstein/REAXYS Number: 906778 MDL number: MFCD00008301 PubChem Substance ID: 24864511 NACRES: NA.22
Кат. номер 393290-INTR 393290-25ML 393290-5ML ApplicationTris(dimethylamino)phosphine can be used as a:- Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.
- Phosphorus source along with InCl3 in the synthesis of InP colloidal quantum dots (QDs).
- Deoxygenating agent for some -dicarbonyl compounds in the presence of fullerene C60.
Tris(dimethylamino)phosphine can be used a reagent in combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; for hydroxyl group activation; dehydrations.Packaging5, 25 mL in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reagent type: ligand
reaction type: Reductions, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Wittig Reactionrefractive index n20/D 1.463 (lit.) bp 48-50 °C/12 mmHg (lit.) density 0.898 g/mL at 25 °C (lit.) functional group phosphine SMILES string CN(C)P(N(C)C)N(C)C InChI 1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3 InChI key XVDBWWRIXBMVJV-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS08 signalword Danger hcodes H226 - H340 - H350 pcodes P201 - P210 - P308 + P313 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 1993C 3 / PGIII WGK Germany WGK 3 Flash Point F 80.6 °F - closed cup Flash Point C 27 °C - closed cup Узнать цену -
Tris(hydroxymethyl)phosphine 177881-25G
Empirical Formula (Hill Notation): C3H9O3P Linear Formula: (HOCH2)3P CAS Number: 2767-80-8 Molecular Weight: 124.08 EC Number: 220-445-6 MDL number: MFCD00055382 PubChem Substance ID: 24850698 NACRES: NA.22 Параметрыassay 90% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand bp 111-113 °C/2.5 mmHg (lit.) mp 48-56 °C (lit.) functional group phosphine SMILES string OCP(CO)CO InChI 1S/C3H9O3P/c4-1-7(2-5)3-6/h4-6H,1-3H2 InChI key JMXMXKRNIYCNRV-UHFFFAOYSA-N
Safety Informationpictograms GHS05,GHS06 signalword Danger hcodes H301 - H315 - H318 - H335 pcodes P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310 Target Organs Respiratory system RIDADR UN 2811 6.1 / PGIII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(o-methoxyphenyl)phosphine 710563-1G
Empirical Formula (Hill Notation): C21H21O3P CAS Number: 4731-65-1 Molecular Weight: 352.36 EC Number: 225-235-8 MDL number: MFCD00014892 PubChem Substance ID: 329762934 NACRES: NA.22 ApplicationCatalyst for:- Allylic substitution of simple alkenes
- Suzuki coupling reactions
- Telomerization of 1,3-butadiene with various alcohols
- Hydrogenation of quinolines
- Amination / direct arylation
Packaging1 g in glass bottleПараметрыQuality Level 100, assay 96% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 198-204 °C functional group phosphine SMILES string COc1ccccc1P(c2ccccc2OC)c3ccccc3OC InChI 1S/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3 InChI key IIOSDXGZLBPOHD-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 - H413 pcodes P273 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(pentafluorophenyl)phosphine
Empirical Formula (Hill Notation): C18F15P Linear Formula: (C6F5)3P CAS Number: 1259-35-4 Molecular Weight: 532.14 Beilstein/REAXYS Number: 773243 EC Number: 215-021-2 MDL number: MFCD00079654 PubChem Substance ID: 24857475 NACRES: NA.22
Кат. номер 290572-1G 290572-5G ПараметрыQuality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 108-110 °C (lit.) functional group phosphine SMILES string Fc1c(F)c(F)c(P(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F InChI 1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33 Inchi Key FQLSDFNKTNBQLC-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris(trimethylsilyl)phosphine
Empirical Formula (Hill Notation): C9H27PSi3 Linear Formula: [(CH3)3Si]3P CAS Number: 15573-38-3 Molecular Weight: 250.54 MDL number: MFCD00015487 PubChem Substance ID: 24860167
Кат. номер 333670-250MG 333670-1G 333670-1G-PW ApplicationTris(trimethylsilyl)phosphine (P(TMS)3) can be used as a precursor for the syntheses of:- Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
- Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.
Packaging1 g in ampuleПараметрыQuality Level 100, assay 95% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand refractive index n20/D 1.502 (lit.) bp 243-244 °C (lit.) density 0.863 g/mL at 25 °C (lit.) functional group phosphine storage temp. 2-8°C SMILES string C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C InChI 1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3 Inchi Key OUMZKMRZMVDEOF-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07 signalword Danger hcodes H250 - H261 - H315 - H319 - H335 pcodes P210 - P231 + P232 - P280 - P302 + P334 - P370 + P378 - P422 Target Organs Respiratory system Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris[2-(diphenylphosphino)ethyl]phosphine 327697-1G
Empirical Formula (Hill Notation): C42H42P4 Linear Formula: [(C6H5)2PCH2CH2]3P CAS Number: 23582-03-8 Molecular Weight: 670.68 EC Number: 245-754-3 MDL number: MFCD00010009 PubChem Substance ID: 24859679 NACRES: NA.22 General descriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.ApplicationLigand used in iron-catalyzed, greener reduction of aldehydes to alcohols under transfer hydrogenation conditions.
Fast and selective iron-catalyzed transfer hydrogenations of aldehydes,Packaging1 g in glass bottleПараметрыQuality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry,.mp 134-135 °C (lit.) functional group phosphine SMILES string C(CP(c1ccccc1)c2ccccc2)P(CCP(c3ccccc3)c4ccccc4)CCP(c5ccccc5)c6ccccc6 InChI 1S/C42H42P4/c1-7-19-37(20-8-1)44(38-21-9-2-10-22-38)34-31-43(32-35-45(39-23-11-3-12-24-39)40-25-13-4-14-26-40)33-36-46(41-27-15-5-16-28-41)42-29-17-6-18-30-42/h1-30H,31-36H2 InChI key TVLNGWSWPKIYAO-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 + H312 + H332 - H315 - H319 - H335 pcodes P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR UN 2811 6.1 / PGIII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tris[3,5-bis(trifluoromethyl)phenyl]phosphine 74231-500MG-F
Empirical Formula (Hill Notation): C24H9F18P CAS Number: 175136-62-6 Molecular Weight: 670.27 Beilstein/REAXYS Number: 6556841 MDL number: MFCD00042428 PubChem Substance ID: 57652507 NACRES: NA.22 Packaging500 mg in poly bottleOther NotesPhosphine with enhanced solubility in solventsПараметрыQuality Level 100, assay ≥95.0% (GC) reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand color yellow-brown functional group phosphine SMILES string FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F InChI 1S/C24H9F18P/c25-19(26,27)10-1-11(20(28,29)30)5-16(4-10)43(17-6-12(21(31,32)33)2-13(7-17)22(34,35)36)18-8-14(23(37,38)39)3-15(9-18)24(40,41)42/h1-9H Inchi Key ITJHLZVYLDBFOJ-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
TrixiePhos 710342-500MG
Empirical Formula (Hill Notation): C28H31P CAS Number: 255836-67-0 Molecular Weight: 398.52 MDL number: MFCD03094576 PubChem Substance ID: 329762917 NACRES: NA.22 ПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsmp 144-148 °C functional group phosphine SMILES string CC(C)(C)P(c1ccc2ccccc2c1-c3cccc4ccccc34)C(C)(C)C InChI 1S/C28H31P/c1-27(2,3)29(28(4,5)6)25-19-18-21-13-8-10-16-23(21)26(25)24-17-11-14-20-12-7-9-15-22(20)24/h7-19H,1-6H3 Inchi Key QGBQGMHXBSLYLZ-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
vBRIDP 711179-500MG
Empirical Formula (Hill Notation): C23H31P CAS Number: 384842-25-5 Molecular Weight: 338.47 MDL number: MFCD16621412 PubChem Substance ID: 329763036 NACRES: NA.22 ApplicationTakasago Ligands and Complexes for Asymmetric Reactions,
Catalyst for:- Preparation of biphenyls
- Amination of aryl bromides and chlorides
Packaging500 mg in glass bottleLegal InformationSold in collaboration with Takasago for research purposes only. US6455720ПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 130-133 °C functional group phosphine storage temp. 2-8°C SMILES string C\C(P(C(C)(C)C)C(C)(C)C)=C(/c1ccccc1)c2ccccc2 InChI 1S/C23H31P/c1-18(24(22(2,3)4)23(5,6)7)21(19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,1-7H3 Inchi Key CYGZMOQFIMJEIT-UHFFFAOYSA-N
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Xantphos
Empirical Formula (Hill Notation): C39H32OP2 CAS Number: 161265-03-8 Molecular Weight: 578.62 MDL number: MFCD00233866 PubChem Substance ID: 24874555 NACRES: NA.22
Кат. номер 526460-1G 526460-5G 526460-25G Packaging1, 5, 25 g in glass bottleApplicationLigand used in a synthesis of heterocycles by palladium-catalyzed C-N cross coupling of 3-bromothiophenes with 2-aminopyridines. Also used in a ruthenium-catalyzed alkylation of active methylene compounds with alcohols.
Metal chelating ligand for catalysis.ПараметрыQuality Level 300 assay 97% reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation, reagent type: ligand
reaction type: Hydroformylations, reagent type: ligand
reaction type: Miyaura Borylation Reaction, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingmp 224-228 °C (lit.) functional group phosphine SMILES string CC1(C)c2cccc(P(c3ccccc3)c4ccccc4)c2Oc5c(cccc15)P(c6ccccc6)c7ccccc7 InChI 1S/C39H32OP2/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3 InChI key CXNIUSPIQKWYAI-UHFFFAOYSA-N
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XantPhos Pd G4
Empirical Formula (Hill Notation): C53H47NO4P2PdS CAS Number: 1621274-19-8 Molecular Weight: 962.38 PubChem Substance ID: 329769801 NACRES: NA.22
Кат. номер 900329-250MG 900329-1G ApplicationA powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.Packaging1 g in glass bottle
250 mg in glass bottleПараметрыform powder Quality Level 100, feature generation 4 reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsfunctional group phosphine InChI 1S/C39H32OP2.C13H12N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h3-28H,1-2H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1 Inchi Key NUVUSIVUZZFNLV-UHFFFAOYSA-M
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XPhos
Empirical Formula (Hill Notation): C33H49P CAS Number: 564483-18-7 Molecular Weight: 476.72 MDL number: MFCD04117682 PubChem Substance ID: 24882906 NACRES: NA.22
Кат. номер 638064-100G 638064-12MG-KC 638064-5G 638064-25G 638064-500G 638064-1G General descriptionXPhos [2-Dicyclohexylphosphino-2,4,6-triisopropylbiphenyl] is an air-stable electron-rich biaryl monophosphine ligand2 developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.ApplicationPreferred ligand for greener Sonogashira coupling in TPGS-750-M.
XPhos may be used as a ligand in the following reactions:- Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides.
- Along with pre-milled palladium(II) acetate as a pre-catalyst for the Stille cross-coupling of aryl chlorides with tributylarylstannanes to form the corresponding biaryl compounds.
- Along with platinum chloride to catalyze the hydrosilylation of terminal arylalkynes with silanes to form functionalized -(E)-vinylsilanes.
Ligand used in a Pd-catalyzed Suzuki coupling leading to C-15 analogs of vindoline.
Direct annulation of 2-haloanilines to indoles and tryptophans catalyzed by Pd. Synthesis of regioregular polythiophenes.
Preferred ligand for greener Sonogashira coupling in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Ligand for increased scope of Pd-catalyzed amination and amidation via arene sulfonates, aryl halides.Packaging1, 5, 25, 100, 500 g in glass bottleLegal InformationUsage subject to US Patent 7,223,879
Usage subject to US Patents 6307087 and 6395916.ПараметрыQuality Level 300 assay 98% reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-C Bond Formation, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Hiyama Coupling, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplinggreener alternative product score old score: 2
new score: 1
Find out more about DOZN™ Scoringgreener alternative product characteristics Waste Prevention
Atom Economy
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.mp 187-190 °C (lit.) functional group phosphine greener alternative category Re-engineered SMILES string CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C3CCCCC3)C4CCCCC4 InChI 1S/C33H49P/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3 InChI key UGOMMVLRQDMAQQ-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields, Gloves, type N95 (US) RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point(F) Not applicable Flash Point(C) Not applicable Узнать цену -
XPhos Pd G1
Empirical Formula (Hill Notation): C41H59ClNPPd CAS Number: 1028206-56-5 Molecular Weight: 738.76 MDL number: MFCD13194128 PubChem Substance ID: 329762494 NACRES: NA.22
Кат. номер 704954-25G 704954-250MG 704954-1G General descriptionMaterial may contain up to 5% pentaneApplicationApplication Guide for Palladium Catalyzed Cross-Coupling Reactions,
Catalyst used for:- Amination / cyclization reactions
- C-N bond-forming reactions via packed-bed microreactors
- Boration of aryl chlorides
- Arylation of oxazole
- Cross-coupling reactions
Packaging250 mg in glass bottle
1, 25 g in glass bottleLegal InformationUsage subject to US Patents 6307087 and 6395916.Параметрыfeature generation 1 Quality Level 100, reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 205-210 °C functional group phosphine SMILES string NCCc1ccccc1[Pd]Cl.CC(C)c2cc(C(C)C)c(c(c2)C(C)C)-c3ccccc3P(C4CCCCC4)C5CCCCC5 InChI 1S/C33H49P.C8H10N.ClH.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;9-7-6-8-4-2-1-3-5-8;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-4H,6-7,9H2;1H;/q;;;+1/p-1 Inchi Key HTAJCNQBAFZEJO-UHFFFAOYSA-M
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 - H412 pcodes P261 - P264 - P271 - P273 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
XPhos Pd G2
Empirical Formula (Hill Notation): C45H59ClNPPd CAS Number: 1310584-14-5 Molecular Weight: 786.80 PubChem Substance ID: 329765534 NACRES: NA.22
Кат. номер 741825-500G 741825-1G 741825-250MG 741825-25G 741825-100G 741825-10G 741825-5G General descriptionXPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwalds 2nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.Application2nd Generation Buchwald Precatalysts- Widely used for Suzuki-Miyaura cross-coupling reactions
XPhos Pd G2 was employed as catalyst in the following reactions:- Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
- Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
- Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.
Packaging250 mg in glass bottle
1, 5, 10, 25, 100, 500 g in glass bottleПараметрыQuality Level 100 assay 98% feature generation 2 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 202-210 °C functional group phosphine SMILES string Nc1ccccc1-c2ccccc2[Pd]Cl.Nc3ccccc3-c4ccccc4[Pd]Cl.CC(C)c5cc(C(C)C)c(-c6cccc(c6)P(C7CCCCC7)C8CCCCC8)c(c5)C(C)C.CC(C)c9cc(C(C)C)c(c(c9)C(C)C)-c%10ccccc%10P(C%11CCCCC%11)C%12CCCCC%12 InChI 1S/2C33H49P.2C12H10N.2ClH.2Pd/c1-23(2)27-21-31(24(3)4)33(32(22-27)25(5)6)26-14-13-19-30(20-26)34(28-15-9-7-10-16-28)29-17-11-8-12-18-29;1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;2*13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;;/h13-14,19-25,28-29H,7-12,15-18H2,1-6H3;13-14,19-25,27-28H,7-12,15-18H2,1-6H3;2*1-6,8-9H,13H2;2*1H;;/q;;;;;;2*+1/p-2 InChI key HMRJFNBZAWHTGN-UHFFFAOYSA-L
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XPhos Pd G3
Empirical Formula (Hill Notation): C46H62NO3PPdS CAS Number: 1445085-55-1 Molecular Weight: 846.45 MDL number: MFCD22666043 PubChem Substance ID: 329767048 NACRES: NA.22
Кат. номер 763381-5G 763381-250MG 763381-1G General descriptionXPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.ApplicationXPhos Pd G3 may be used in the following reactions:- Cyanation reaction of heterocyclic halides.
- Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
- Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.
Packaging250 mg in glass bottle
1, 5 g in glass bottleПараметрыQuality Level 100 assay 98% feature generation 3 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 146-151 °C (decomposition) functional group phosphine SMILES string CC(C)C(C=C1C(C)C)=CC(C(C)C)=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5 InChI 1S/C33H49P.C12H10N.CH4O3S.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1 InChI key NKKHABPORDUWIG-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point(F) Not applicable Flash Point(C) Not applicable Узнать цену -
XPhos-Pd-G2 GT capsule 805637-5EA
Empirical Formula (Hill Notation): C45H59ClNPPd Molecular Weight: 786.80 PubChem Substance ID: 329768952 NACRES: NA.22 ApplicationConvenient dosable form of XPhos-Pd-G2Packaging5 ea in glass bottleПараметрыform capsule Quality Level 100, feature generation 2 reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsfunctional group phosphine SMILES string CC(C)C(C=C1C(C)C)=CC(C(C)C)=C1C2=CC=CC=C2C(C3CCCCC3)C4CCCCC4.NC5=C(C6=C([Pd]Cl)C=CC=C6)C=CC=C5 InChI 1S/C34H50.C12H10N.ClH.Pd/c1-23(2)28-21-31(24(3)4)34(32(22-28)25(5)6)30-20-14-13-19-29(30)33(26-15-9-7-10-16-26)27-17-11-8-12-18-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h13-14,19-27,33H,7-12,15-18H2,1-6H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1 InChI key ZKKCVBQNSHPVBL-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
[(1,3,5,7-Tetramethyl-6-phenyl-2,4,6-trioxa-6-phosphaadamantane)-2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonate
Empirical Formula (Hill Notation): C29H34NO6PPdS CAS Number: 2230788-58-4 Molecular Weight: 662.04 PubChem Substance ID: 329767006 NACRES: NA.22
Кат. номер 762822-2G 762822-500MG General descriptionThis material can form rotamers.Packaging2 g in glass bottle
500 mg in glass bottleПараметрыreaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross CouplingsQuality Level 100, mp 130-136 °C (decomposition) functional group phosphine storage temp. 2-8°C SMILES string CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC34CC5(C)OC(C)(CC(C)(O3)P5c6ccccc6)O4 InChI 1S/C16H21O3P.C12H10N.CH4O3S.Pd/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h5-9H,10-11H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1 InChI key PBZIJOKKZYPPSJ-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену
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В случае любых неполадок за свой счет выполним ремонт в сервисном центре или на заводе-изготовителе. Или бесплатно заменим прибор на новый.
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