Buchwald Catalysts & Ligands
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Phosphine Ligands Kit I 659940-1KT
NACRES: NA.22 General descriptionIt contains a set of seven phosphine ligands with varying steric and electronic properties useful for rapid screening of catalysis conditions. It is in sampler format with individual components packaged for multiple experiments and mini scale-up. The cost of the kit is less than the total cost of individual components.ApplicationCatalysis Screening Kits,Packaging1 kit in glass bottleПараметрыreaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand Quality Level 100, functional group phosphine
Safety Informationpictograms GHS05,GHS07,GHS08 signalword Danger hcodes H302 - H315 - H317 - H318 - H335 - H372 pcodes P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310 - P314 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F 356.0 °F - closed cup Flash Point C 180 °C - closed cup Узнать цену -
Photo KitAlysis™ 24-Green LED Array Z742608-1EA
NACRES: NA.22 General descriptionGreen LED Array for Photo KitAlysis high-throughput screening platform. For use with Photo KitAlysis Starter Kit (Z742612). User guide is provided in the below hyperlink.
Photo KitAlysis Operating Instructions
Features:- Designed and tested by synthetic chemists.
- Controller provides repeatable milliamp selection for photon intensity (sold seperately)
- 527 nm wavelength
- 0-30 mA variable LED output
- Non-magnetic LED base
- Chemically resistant LED cover
- PTFE coated cabling
Photo Kitalysis Starter Kit required for operation (sold separately). Best when used with KitAlysis Benchtop Inertion Box (sold separately).Legal InformationKitAlysis is a trademark of Sigma-Aldrich Co. LLCПараметрыreaction suitability reagent type: catalyst
reaction type: Cross CouplingsQuality Level 100 Узнать цену -
Photo KitAlysis™ 24-White LED Array Z742609-1EA
NACRES: NA.22 General descriptionWhite LED Array for Photo KitAlysis high-throughput screening platform. For use with Photo KitAlysis Starter Kit (Z742612). User guide is provided in the below hyperlink.
Photo KitAlysis Operating Instructions
Features:- Designed and tested by synthetic chemists.
- Controller provides repeatable milliamp selection for photon intensity (sold seperately)
- 0-30 mA variable LED output
- Non-magnetic LED base
- Chemically resistant LED cover
- PTFE coated cabling
Photo Kitalysis Starter Kit required for operation (sold separately). Best when used with KitAlysis Benchtop Inertion Box (sold separately).Legal InformationKitAlysis is a trademark of Sigma-Aldrich Co. LLCПараметрыreaction suitability reagent type: catalyst
reaction type: Cross CouplingsQuality Level 100 Узнать цену -
Photo KitAlysis™ Starter Kit
NACRES: NA.22
Кат. номер Z742612-1EA Z742612-1KT General descriptionPhoto KitAlysis Starter Kit enables screening of 24 micro-scale simultaneous photocatalytic reactions with consistent and reproducible photon intensity. User guide is provided in the below hyperlink.
Photo KitAlysis Operating Instructions
Components:- Photo KitAlysis LED Controller
- Blue LED Array (470 nm)
- Photo KitAlysis Reaction Block
- Torque screwdriver
- Small screwdriver to easily remove torqued screws after reaction is complete
Features:- Designed and tested by synthetic chemists.
- Controller provides repeatable milliamp selection for photon intensity
- 0-30 mA variable LED output
- 3 different LED options: blue (470 nm, included), green (527 nm, sold separately), and white (sold separately)
- Non-magnetic LED base
- Chemically resistant LED cover
- PTFE coated cabling
Designed to be used with Photo KitAlysis High-Throughput Reaction Screening Kit (sold separately).
Best when used with KitAlysis Benchtop Inertion Box (sold separately).Legal InformationKitAlysis is a trademark of Sigma-Aldrich Co. LLCПараметрыreaction suitability reagent type: catalyst
reaction type: Cross CouplingsQuality Level 100 Узнать цену -
Poly(ethylene glycol) triphenylphosphine
CAS Number: 238403-28-6 MDL number: MFCD03100952 PubChem Substance ID: 24877901 NACRES: NA.22
Кат. номер 532649-1G 532649-5G Application- Used as a hydrogenation catalyst in a water/substrate two-phase medium
Packaging1 g in glass bottleПараметрыreaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: solution phase peptide synthesis, reagent type: ligand Quality Level 100, mp 44-46 °C (lit.) functional group phosphine SMILES string OCCO.c1ccc(cc1)P(c2ccccc2)c3ccccc3
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
QPhos Pd G3
Empirical Formula (Hill Notation): C61H60FeNO3PPdS CAS Number: 2021255-91-2 Molecular Weight: 1080.44 MDL number: MFCD12911997
Кат. номер 903027-250MG 903027-1G General descriptionQPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. Qphos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.ApplicationQPhos Pd G3 has been used as a precatalyst for the arylboration of isoprene with regioselectivity,. It may also be used for a variety of aminination and etherifications of aryl halides.Other NotesTechnology Spotlight: G3 and G4 Buchwald Precatalysts,
Regioselective Arylboration of Isoprene and Its Derivatives by Pd/Cu Cooperative Catalysis,
Synthesis of Complex Drug like Molecules by the Use of Highly Functionalized Bench-Stable Organozinc Reagents,Параметрыform powder feature generation 3 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsfunctional group phosphine
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
rac-BINAP Pd G4
Empirical Formula (Hill Notation): C58H47NO3P2PdS CAS Number: 1599466-90-6 Molecular Weight: 1006.43 PubChem Substance ID: 329769806
Кат. номер 900340-250MG 900340-1G ApplicationA powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.Packaging1 g in glass bottle
250 mg in glass bottleПараметрыform powder Quality Level 100, feature generation 4 reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsfunctional group phosphine InChI 1S/C44H32P2.C13H12N.CH4O3S.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h1-32H;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1 Inchi Key JCAKNOAUMBTXEM-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
rac-BINAP-Pd-G3
Empirical Formula (Hill Notation): C57H45NO3P2PdS CAS Number: 2151915-22-7 Molecular Weight: 992.40 PubChem Substance ID: 329768912
Кат. номер 804967-250MG 804967-1G General descriptionrac-BINAP-Pd-G3 is a third generation (G3) Buchwald precatalyst. t is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. rac-BINAP-Pd-G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. ItApplicationPd precatalyst for cross-couplingPackaging1 g in glass bottle
250 mg in glass bottleПараметрыQuality Level 100, assay 95% feature generation 3 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligandmp 175-180 °C functional group phosphine SMILES string CS(O[Pd-2]1([P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=C(C5=C6C(C=CC=C6)=CC=C5P(C7=CC=CC=C7)C8=CC=CC=C8)C9=CC=CC=C9C=C4)C%10=C(C%11=C([NH2+]1)C=CC=C%11)C=CC=C%10)(=O)=O InChI 1S/C44H32P2.C12H10N.CH4O3S.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h1-32H;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1 InChI key BVYJEOTVUJMCBM-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
RockPhos
Empirical Formula (Hill Notation): C31H49OP CAS Number: 1262046-34-3 Molecular Weight: 468.69 MDL number: MFCD20922895 PubChem Substance ID: 329768254 NACRES: NA.22
Кат. номер 791016-500MG 791016-2G ApplicationRockPhos is a biphenyl-based phosphine ligand used with Pd(0) catalyst for carbon-carbon and carbon-heteroatom bond formation reactions.
It can also be employed in the:- 2-fluroethoxylation of bromo-chalcones in the presence of palladium catalyst.
- Conversion of aryl chlorides into aryl methoxides using RockPhos Pd G3 as a catalyst.
Packaging2 g in glass bottle
500 mg in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsmp 121-131 °C functional group phosphine storage temp. 15-25°C SMILES string CC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C(C)(C)C)C(C)(C)C)=C(OC)C=C1 InChI 1S/C31H49OP/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13/h15-21H,1-14H3 Inchi Key CVLLAKCGAFNZHJ-UHFFFAOYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
RockPhos Pd G3
Empirical Formula (Hill Notation): C44H62NO4PPdS CAS Number: 2009020-38-4 Molecular Weight: 838.43 MDL number: MFCD27952542 PubChem Substance ID: 329767644 NACRES: NA.22
Кат. номер 773905-100MG 773905-5G 773905-500MG ApplicationBuchwald 3rd Generation Pd Precatalyst containing bulk RockPhos ligand. This system has been shown to be effective for cross-coupling reactions like the arylation of aliphatic alcohols.
Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands,Packaging5 g in glass bottle
100, 500 mg in glass bottleПараметрыfeature generation 3 Quality Level 100, reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 220-250 °C functional group phosphine SMILES string CC1=CC=C(OC)C(P(C(C)(C)C)C(C)(C)C)=C1C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C.NC3=CC=CC=C3C4=CC=CC=C4[Pd]OS(C)(=O)=O InChI 1S/C31H49OP.C12H10N.CH4O3S.Pd/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1 InChI key PANIJJUVUGSZSP-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
RuPhos
Empirical Formula (Hill Notation): C30H43O2P CAS Number: 787618-22-8 Molecular Weight: 466.64 MDL number: MFCD06798294 PubChem Substance ID: 24884189 NACRES: NA.22
Кат. номер 663131-100G 663131-5G 663131-25G 663131-1G Packaging1, 5, 25, 100 g in glass bottleApplicationBulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborates with electron-poor aryl bromides.Legal InformationUsage subject to Patents: EP 1097158; JP 5758844; CA 2336691ПараметрыQuality Level 300 assay 98% reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplinggreener alternative product score old score: 3
new score: 1
Find out more about DOZN™ Scoringgreener alternative product characteristics Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.impurities 1-5% Bis(2,6-Diisopropoxybiphenyl)cyclohexylphosphine mp 123-126 °C functional group phosphine greener alternative category Re-engineered SMILES string CC(C)Oc1cccc(OC(C)C)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4 InChI 1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3 InChI key MXFYYFVVIIWKFE-UHFFFAOYSA-N
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point(F) Not applicable Flash Point(C) Not applicable Узнать цену -
RuPhos Pd G1 Methyl t-Butyl Ether Adduct
Empirical Formula (Hill Notation): C38H53ClNO2PPd · CH3OC4H9 CAS Number: 2361069-97-6 Molecular Weight: 816.83 MDL number: MFCD12545955 PubChem Substance ID: 329762732 NACRES: NA.22
Кат. номер 707589-250MG 707589-1G ApplicationApplication Guide for Palladium Catalyzed Cross-Coupling Reactions,
Catalyst for Buchwald-Hartwig amination reaction.Packaging1 g in glass bottle
250 mg in glass bottleLegal InformationUsage subject to US Patents 6307087 and 6395916.ПараметрыQuality Level 100, assay 95% feature generation 1 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 180-200 °C functional group phosphine SMILES string COC(C)(C)C.NCCc1ccccc1[Pd]Cl.CC(C)Oc2cccc(OC(C)C)c2-c3ccccc3P(C4CCCCC4)C5CCCCC5 InChI 1S/C30H43O2P.C8H10N.C5H12O.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1 InChI key OMMPYFRVDWZBNR-UHFFFAOYSA-M
Safety Informationpictograms GHS05,GHS07 signalword Danger hcodes H314 - H335 pcodes P261 - P271 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 - P403 + P233 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
RuPhos Pd G2
Empirical Formula (Hill Notation): C42H53ClNO2PPd CAS Number: 1375325-68-0 Molecular Weight: 776.72 MDL number: MFCD20264899 PubChem Substance ID: 329766346 NACRES: NA.22
Кат. номер 753246-5G 753246-250MG 753246-1G General descriptionRuPhos Pd G2 is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.ApplicationRuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction.Packaging250 mg in glass bottle
1, 5 g in glass bottleOther NotesMay contain <1% acetone.ПараметрыQuality Level 100, feature generation 2 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 195-197 °C functional group phosphine SMILES string Nc1ccccc1-c2ccccc2[Pd]Cl.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6 InChI 1S/C30H43O2P.C12H10N.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1 InChI key VPDRBFBKNSFRSS-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
RuPhos Pd G4
Empirical Formula (Hill Notation): C44H58NO5PPdS CAS Number: 1599466-85-9 Molecular Weight: 850.39 PubChem Substance ID: 329768858 NACRES: NA.22
Кат. номер 804290-1G 804290-250MG ApplicationA powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.Packaging1 g in glass bottle
250 mg in glass bottleПараметрыassay 95% Quality Level 100, form powder feature generation 4 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligandmp 240 °C functional group phosphine SMILES string CC(OC1=CC=CC(OC(C)C)=C1C2=C([P+](C3CCCCC3)([Pd-2]4(OS(C)(=O)=O)C(C=CC=C5)=C5C6=C([NH+]4C)C=CC=C6)C7CCCCC7)C=CC=C2)C InChI 1S/C30H43O2P.C13H12N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1 InChI key FDRWYHUTZOCVSQ-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
RuPhos-Pd-G3 GT capsule 805653-5EA
Empirical Formula (Hill Notation): C43H56NO5PPdS Molecular Weight: 836.37 PubChem Substance ID: 329768954 NACRES: NA.22 ApplicationConvenient dosable form of RuPhos-Pd-G3Packaging5 ea in glass bottleПараметрыform capsule Quality Level 100, feature generation 3 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligandfunctional group phosphine SMILES string CC(C)OC1=CC=CC(OC(C)C)=C1C2=CC=CC=C2[P+](C3CCCCC3)([Pd-2]4(OS(C)(=O)=O)C(C=CC=C5)=C5C6=C([NH2+]4)C=CC=C6)C7CCCCC7 InChI 1S/C30H43O2P.C12H10N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1 Inchi Key AXZLIMCJMPNFFU-UHFFFAOYSA-M
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P280 - P304 + P340 + P312 - P305 + P351 + P338 - P337 + P313 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
SPhos
Empirical Formula (Hill Notation): C26H35O2P CAS Number: 657408-07-6 Molecular Weight: 410.53 MDL number: MFCD05861611 PubChem Substance ID: 24882907 NACRES: NA.22
Кат. номер 638072-100G 638072-1G 638072-5G 638072-500G 638072-25G General descriptionSPhos [2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.ApplicationSPhos may be used as a ligand in the following processes:- Palladium catalyzed Suzuki-Miyaura cross-coupling reaction between Boc-protected aminomethyltrifluoroborate and aryl chlorides or hetaryl chlorides to form the corresponding aminomethylarenes.
- Palladium catalyzed Suzuki-Miyaura cross-coupling reaction between 4-methyl-substituted piperidinylzinc reagent and different aryl or heteroaryl iodides to form various substituted piperidines.
- Intramolecular Suzuki-Miyaura coupling to form the 18-membered macrocyclic ring during the multi-step synthesis of riccardin C.
Utilized in conjunction with palladium to form a highly active catalyst for C-N bond formation.
Highly universal ligand for Suzuki-Miyaura coupling; aryl chlorides, hindered biaryls, heterobiaryls.Packaging1, 5, 25, 100, 500 g in glass bottleLegal InformationUsage subject to Patents: US 6307087; EP 1097158; JP 5758844; CA 2336691ПараметрыQuality Level 300 assay 98% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Kumada Coupling, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplinggreener alternative product score old score: 10
new score: 1
Find out more about DOZN™ Scoringgreener alternative product characteristics Waste Prevention
Less Hazardous Chemical Syntheses
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.mp 164-166 °C (lit.) functional group phosphine greener alternative category Re-engineered SMILES string COc1cccc(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4 InChI 1S/C26H35O2P/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21/h9-11,16-21H,3-8,12-15H2,1-2H3 InChI key VNFWTIYUKDMAOP-UHFFFAOYSA-N
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SPhos Pd G1, Methyl t-Butyl Ether Adduct
Empirical Formula (Hill Notation): C39H57ClNO3PPd Linear Formula: C34H45ClNO2PPd · CH3OC4H9 Molecular Weight: 760.72 MDL number: MFCD15144765 PubChem Substance ID: 329762493 NACRES: NA.22
Кат. номер 704946-1G 704946-250MG ApplicationApplication Guide for Palladium Catalyzed Cross-Coupling Reactions,
Catalyst for C-N bond forming reaction.Packaging1 g in glass bottle
250 mg in glass bottleLegal InformationUsage subject to US Patents 6307087 and 6395916.Параметрыfeature generation 1 Quality Level 100, reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 160-170 °C functional group phosphine SMILES string COC(C)(C)C.NCCc1ccccc1[Pd]Cl.COc2cccc(OC)c2-c3ccccc3P(C4CCCCC4)C5CCCCC5 InChI 1S/C26H35O2P.C8H10N.C5H12O.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1 Inchi Key CLLOZWOLUBODPC-UHFFFAOYSA-M
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
SPhos Pd G2
Empirical Formula (Hill Notation): C38H45ClNO2PPd CAS Number: 1375325-64-6 Molecular Weight: 720.62 MDL number: MFCD20264897 PubChem Substance ID: 329766331
Кат. номер 753009-250MG 753009-1G 753009-5G General descriptionSPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.ApplicationApplication in Suzuki-Miyaura coupling:- Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
- Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.
- Suzuki–Miyaura coupling of -borylated porphyrins with 2-iodoaniline.
Packaging250 mg in glass bottle
1, 5 g in glass bottleПараметрыQuality Level 100, feature generation 2 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 218 °C (dec.) functional group phosphine SMILES string COC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]Cl)C=CC=C6)C=CC=C5 InChI 1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1 InChI key NOMWEFBAPVZIIP-UHFFFAOYSA-M
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SPhos Pd G4
Empirical Formula (Hill Notation): C40H50NO5PPdS CAS Number: 1599466-87-1 Molecular Weight: 794.29 PubChem Substance ID: 329768857 NACRES: NA.22
Кат. номер 804282-100MG 804282-1G 804282-100G General descriptionSPhos Pd G4 is a versatile 4th generation palladium precatalyst developed by Buchwald group.Packaging1 g in glass bottle
100 mg in glass bottleПараметрыassay 95% Quality Level 100, form powder feature generation 4 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsfunctional group phosphine SMILES string CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.COC3=CC=CC(OC)=C3C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6 InChI 1S/C26H35O2P.C13H12N.CH4O3S.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h9-11,16-21H,3-8,12-15H2,1-2H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1 Inchi Key ISSWOKPFLWDXSU-UHFFFAOYSA-M
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SPhos-Pd-G2 GT capsule 805483-5EA
Empirical Formula (Hill Notation): C38H45ClNO2PPd Molecular Weight: 720.62 MDL number: MFCD20264897 PubChem Substance ID: 329768941 NACRES: NA.22 ApplicationConvenient dosable form of SPhos-Pd-G2.Packaging5 ea in glass bottleПараметрыform capsule Quality Level 100, feature generation 2 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reagent type: ligand functional group phosphine InChI 1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1 Inchi Key NOMWEFBAPVZIIP-UHFFFAOYSA-M
Safety InformationRIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
SPhos-Pd-G3 GT capsule 805645-5EA
Empirical Formula (Hill Notation): C39H48NO5PPdS Molecular Weight: 780.26 PubChem Substance ID: 329768953 NACRES: NA.22 ApplicationConvenient dosable form of SPhos-Pd-G3Packaging5 ea in glass bottleПараметрыform capsule Quality Level 100, feature generation 3 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligandfunctional group phosphine SMILES string COC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5.C InChI 1S/C26H35O2P.C12H10N.CH4O3S.CH4.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);1H4;/q;;;;+1/p-1 InChI key MKKSNXJKLSKZMC-UHFFFAOYSA-M
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
sSPhos
Empirical Formula (Hill Notation): C26H34NaO5PS · xH2O CAS Number: 1049726-96-6 Molecular Weight: 512.57 (anhydrous basis) MDL number: MFCD07781994 PubChem Substance ID: 24885361 NACRES: NA.22
Кат. номер 677280-2G 677280-500MG 677280-10G Packaging2, 10 g in glass bottle
500 mg in glass bottleApplicationSulfonated ligand for palladium-catalyzed Suzuki-Miyaura coupling under aqueous conditions facilitating isolation of the organic products.Legal InformationUsage subject to US Patents 6307087 and 6395916.Параметрыreaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Suzuki-Miyaura CouplingQuality Level 100, functional group phosphine SMILES string O.[Na+].COc1ccc(c(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4)S([O-])(=O)=O InChI 1S/C26H35O5PS.Na.H2O/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);;1H2/q;+1;/p-1 InChI key MAPQBSXKBDVINV-UHFFFAOYSA-M
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
sSPhos Pd G2
Empirical Formula (Hill Notation): C38H44ClNNaO5PPdS CAS Number: 2375242-78-5 Molecular Weight: 822.66 MDL number: MFCD22377809 PubChem Substance ID: 329767044 NACRES: NA.22
Кат. номер 763314-500MG 763314-100MG ПараметрыQuality Level 100, assay 95% feature generation 2 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 193-194 °C (decomposition) functional group phosphine SMILES string [Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O InChI 1S/C26H35O5PS.C12H10N.ClH.Na.Pd/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);1-6,8-9H,13H2;1H;;/q;;;2*+1/p-2 InChI key MWQYWXJKMDRSJN-UHFFFAOYSA-L
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t-BuDavePhos
Empirical Formula (Hill Notation): C22H32NP CAS Number: 224311-49-3 Molecular Weight: 341.47 MDL number: MFCD03426986 PubChem Substance ID: 329761782 NACRES: NA.22
Кат. номер 695874-5G 695874-250MG 695874-1G Параметрыreaction suitability reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond FormationQuality Level 100, mp 114-118 °C functional group phosphine SMILES string CN(C)c1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C InChI 1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3 InChI key PHLPNEHPCYZBNZ-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 - H413 pcodes P273 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
t-BuDavePhos Pd G4
Empirical Formula (Hill Notation): C36H47N2O3PPdS CAS Number: 1507403-97-5 Molecular Weight: 725.23
Кат. номер 903663-250MG 903663-1G General descriptiontBuDavePhos Pd G4 is a fourth generation (G4) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuDavePhos Pd G4 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.ApplicationtBuDavePhos Pd G4 will be used for a variety of C-C and C-N cross-coupling reactions.Other NotesTechnology Spotlight: G3 and G4 Buchwald Precatalysts,Параметрыform powder or crystals feature generation 4 reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp >300 °C functional group phosphine
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tBuMePhos
Empirical Formula (Hill Notation): C21H29P CAS Number: 255837-19-5 Molecular Weight: 312.43 MDL number: MFCD03453047 PubChem Substance ID: 329761725 NACRES: NA.22
Кат. номер 695211-500MG 695211-1G Packaging1 g in glass bottle
500 mg in glass bottleApplicationA ligand for the palladium-catalyzed monoarylation of malonate esters, 1,3-diketones and isolated nitroalkanes.Legal InformationUsage subject to US Patents 6307087 and 6395916.Параметрыreaction suitability reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: ReductionsQuality Level 100, mp 90-95 °C functional group phosphine SMILES string Cc1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C InChI 1S/C21H29P/c1-16-12-8-9-13-17(16)18-14-10-11-15-19(18)22(20(2,3)4)21(5,6)7/h8-15H,1-7H3 InChI key UJONYAVMBYXBJQ-UHFFFAOYSA-N
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tBuXPhos
Empirical Formula (Hill Notation): C29H45P CAS Number: 564483-19-8 Molecular Weight: 424.64 MDL number: MFCD06411306 PubChem Substance ID: 24882908
Кат. номер 638080-5G 638080-500G 638080-25G 638080-100G 638080-1G General descriptiontBuXPhos [2-Di-tert-butylphosphino-2,4,6-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.ApplicationtBuXPhos is a ligand for Pd-catalyzed C-O and C-N bond formation.
It can be used in the following reactions:- Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
- Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
- Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.
tBuXPhos has been used in the preparation of [tBuXPhosAu(MeCN)]BAr4F, a gold catalyst for the intermolecular [2+2] cycloaddition of terminal arylalkynes with substituted alkenes to form functionalized cyclobutenes with high regioselectivity.Packaging1, 5, 25, 100, 500 g in glass bottleLegal InformationUsage subject to Patents: EP 1097158; JP 5758844; CA 2336691ПараметрыQuality Level 300, assay 98% reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Carboxylations, reagent type: ligand
reaction type: Decarboxylationsgreener alternative product score old score: 12
new score: 1
Find out more about DOZN™ Scoring,greener alternative product characteristics Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry,.mp 148-151 °C (lit.) functional group phosphine greener alternative category Re-engineered, SMILES string CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C(C)(C)C)C(C)(C)C InChI 1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3 InChI key SACNIGZYDTUHKB-UHFFFAOYSA-N
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tBuXPhos Pd G1
Empirical Formula (Hill Notation): C37H55ClNPPd CAS Number: 1142811-12-8 Molecular Weight: 686.69 MDL number: MFCD12911909 PubChem Substance ID: 329762821 NACRES: NA.22
Кат. номер 708739-1G 708739-250MG ApplicationCatalyst for C-C bond and C-N bond formation.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions,Packaging1 g in glass bottle
250 mg in glass bottleLegal InformationUsage subject to US Patents 6307087 and 6395916.Параметрыfeature generation 1 Quality Level 100, reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplingsmp 150-159 °C functional group phosphine SMILES string NCCc1ccccc1[Pd]Cl.CC(C)c2cc(C(C)C)c(c(c2)C(C)C)-c3ccccc3P(C(C)(C)C)C(C)(C)C InChI 1S/C29H45P.C8H10N.ClH.Pd/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12;9-7-6-8-4-2-1-3-5-8;;/h13-21H,1-12H3;1-4H,6-7,9H2;1H;/q;;;+1/p-1 Inchi Key LQRWNWRVOIDQOD-UHFFFAOYSA-M
Safety Informationpictograms GHS07,GHS08 signalword Warning hcodes H315 - H319 - H335 - H351 pcodes P201 - P302 + P352 - P305 + P351 + P338 - P308 + P313 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
tert-Butyldicyclohexylphosphine
Empirical Formula (Hill Notation): C16H31P CAS Number: 93634-87-8 Molecular Weight: 254.39 MDL number: MFCD03426984 PubChem Substance ID: 24883844 NACRES: NA.22
Кат. номер 651605-1G 651605-5G General descriptiontert-Butyldicyclohexylphosphine is a bulky, electron-rich phosphine ligand.Applicationtert-Butyldicyclohexylphosphine may be used as a ligand for:- Intermolecular palladium-catalyzed arylation of electron-rich, five-membered heterocycles by aryl chlorides.
- Palladium-catalyzed ortho-arylation of benzoic acids by aryl chloride.
Packaging1, 5 g in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand density 0.939 g/mL at 25 °C (lit.) functional group phosphine SMILES string CC(C)(C)P(C1CCCCC1)C2CCCCC2 InChI 1S/C16H31P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h14-15H,4-13H2,1-3H3 InChI key MQYZHXLHUNLBQH-UHFFFAOYSA-N
Safety Informationpictograms GHS02 signalword Danger hcodes H250 pcodes P222 - P231 - P422 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
tert-Butyldicyclohexylphosphonium tetrafluoroborate
Empirical Formula (Hill Notation): C16H32BF4P CAS Number: 1220349-00-7 Molecular Weight: 342.20 MDL number: MFCD17677173 PubChem Substance ID: 329764469
Кат. номер 729337-250MG 729337-1G Параметрыassay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 221-231 °C functional group phosphine SMILES string F[B-](F)(F)F.CC(C)(C)[PH+](C1CCCCC1)C2CCCCC2 InChI 1S/C16H31P.BF4/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15;2-1(3,4)5/h14-15H,4-13H2,1-3H3;/q;-1/p+1 Inchi Key XOMLPCCNVCCMRG-UHFFFAOYSA-O
Safety InformationRIDADR NONH for all modes of transport WGK Germany nwg Узнать цену -
tert-Butyldiphenylphosphine
Empirical Formula (Hill Notation): C16H19P Linear Formula: (C6H5)2PC(CH3)3 CAS Number: 6002-34-2 Molecular Weight: 242.30 EC Number: 227-848-6 MDL number: MFCD00015004 PubChem Substance ID: 24881351 NACRES: NA.22
Кат. номер 591688-1G 591688-5G ApplicationCatalyst for:- Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
- Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
- Palladium to form a catalyst for methoxycarbonylation reactions
- Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
- Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
- Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
- Monodentate P-Donor Ligands (LKB-P)
Packaging1, 5 g in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsbp 144-146 °C/2 mmHg (lit.) mp 52-57 °C (lit.) functional group phosphine SMILES string CC(C)(C)P(c1ccccc1)c2ccccc2 InChI 1S/C16H19P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3 InChI key QZUPHAGRBBOLTB-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, multi-purpose combination respirator cartridge (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tetrapropylphosphonium bromide 804428-500MG
Empirical Formula (Hill Notation): C12H28BrP CAS Number: 63462-98-6 Molecular Weight: 283.23 PubChem Substance ID: 329768869 NACRES: NA.22 ПараметрыQuality Level 100, assay 95% form powder and chunks reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 221-226 °C functional group phosphine SMILES string CCC[P+](CCC)(CCC)CCC.[Br-] InChI 1S/C12H28P.BrH/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H/q+1;/p-1 InChI key SMGSPBKMKYMJPQ-UHFFFAOYSA-M
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tri(2-furyl)phosphine
Empirical Formula (Hill Notation): C12H9O3P CAS Number: 5518-52-5 Molecular Weight: 232.17 Beilstein/REAXYS Number: 1577564 MDL number: MFCD00151857 PubChem Substance ID: 24863985 NACRES: NA.22
Кат. номер 383767-1G 383767-250MG ПараметрыQuality Level 100, assay 99% reaction suitability reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Cycloisomerizations, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Oxidations, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingbp 136 °C/4 mmHg (lit.) mp 59-64 °C (lit.) functional group phosphine SMILES string c1coc(c1)P(c2ccco2)c3ccco3 InChI 1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H InChI key DLQYXUGCCKQSRJ-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tri(p-tolyl)phosphine
Empirical Formula (Hill Notation): C21H21P Linear Formula: (CH3C6H4)3P CAS Number: 1038-95-5 Molecular Weight: 304.37 Beilstein/REAXYS Number: 651045 EC Number: 213-863-5 MDL number: MFCD00008542 PubChem Substance ID: 24857296 NACRES: NA.22
Кат. номер 287830-5G 287830-1G ПараметрыQuality Level 100, assay 98% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsmp 144-148 °C (lit.) functional group phosphine SMILES string Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc(C)cc3 InChI 1S/C21H21P/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21/h4-15H,1-3H3 Inchi Key WXAZIUYTQHYBFW-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H315 - H319 - H335 pcodes P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tri-1-naphthylphosphine
Empirical Formula (Hill Notation): C30H21P Linear Formula: (C10H7)3P CAS Number: 3411-48-1 Molecular Weight: 412.46 MDL number: MFCD00046400 PubChem Substance ID: 24884894 NACRES: NA.22
Кат. номер 667218-1G 667218-5G ПараметрыQuality Level 200, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 261-265 °C functional group phosphine SMILES string c1ccc2c(cccc2c1)P(c3cccc4ccccc34)c5cccc6ccccc56 InChI 1S/C30H21P/c1-4-16-25-22(10-1)13-7-19-28(25)31(29-20-8-14-23-11-2-5-17-26(23)29)30-21-9-15-24-12-3-6-18-27(24)30/h1-21H InChI key DMEUUKUNSVFYAA-UHFFFAOYSA-N
Safety Informationpictograms GHS07 signalword Warning hcodes H302 Personal Protective Equipment dust mask type N95 (US),, Eyeshields,, Gloves, RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tri-n-butylphosphine
Empirical Formula (Hill Notation): C12H27P Linear Formula: [CH3(CH2)3]3P CAS Number: 998-40-3 Molecular Weight: 202.32 Beilstein/REAXYS Number: 1738261 EC Number: 213-651-2 MDL number: MFCD00009462 PubChem Substance ID: 329764649 NACRES: NA.22
Кат. номер 731374-25G 731374-100G ApplicationCatalyst for:- Domino reactions of activated conjugated dienes with ,unsaturated--ketoesters
- [3+2]-Cycloadditions
- Umpolung addition reactions
- Reductive carbonylation
- Allylation reactions
Packaging25, 100 g in Sure/Seal™Параметрыvapor density 9 (vs air) Quality Level 100, assay 99% autoignition temp. 392 °F reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand refractive index n20/D 1.462 (lit.) bp 150 °C/50 mmHg (lit.) density 0.81 g/mL at 25 °C (lit.) functional group phosphine SMILES string CCCCP(CCCC)CCCC InChI 1S/C12H27P/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3 InChI key TUQOTMZNTHZOKS-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07,GHS09 signalword Danger hcodes H251 - H302 - H314 - H411 pcodes P235 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 RIDADR UN 3254 4.2 / PGI WGK Germany WGK 3 Узнать цену -
Tri-tert-butylphosphine
Empirical Formula (Hill Notation): C12H27P Linear Formula: [(CH3)3C]3P CAS Number: 13716-12-6 Molecular Weight: 202.32 Beilstein/REAXYS Number: 1738613 EC Number: 237-266-4 MDL number: MFCD00015006 PubChem Substance ID: 24880600 NACRES: NA.22
Кат. номер 570958-10G 570958-5G 570958-1G Packaging1, 5, 10 g in glass bottleApplicationPreferred ligand in the palladium-catalyzed coupling of arylboronic acids with phenyliodonium ylides of hydroxyquinones. Also used with Pd2(dba)3 for the -arylation of trimethylsilyl enol ethers with aryl halides.ПараметрыQuality Level 100 assay 98% reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingbp 102-103 °C/13 mmHg (lit.) mp 30-35 °C (lit.) density 0.834 g/mL at 20 °C (lit.) functional group phosphine SMILES string CC(C)(C)P(C(C)(C)C)C(C)(C)C InChI 1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3 InChI key BWHDROKFUHTORW-UHFFFAOYSA-N
Safety InformationPictograms GHS02,GHS05 Signal Word Danger Hazard Statements H250 - H314 Precautionary Statements P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges RIDADR UN 2846 4.2 / PGI WGK Germany WGK 3 Flash Point(F) 1.4 °F Flash Point(C) -17 °C Узнать цену -
Tri-tert-butylphosphine solution
Empirical Formula (Hill Notation): C12H27P CAS Number: 13716-12-6 Molecular Weight: 202.32 MDL number: MFCD00015006 PubChem Substance ID: 24884097 NACRES: NA.22
Кат. номер 655325-10ML 655325-25ML 655325-50ML ApplicationTri-tert-butylphosphine is a suitable ligand for palladium-catalyzed coupling reactions such as:- Heck Reactions
- Negishi cross-coupling
- Stille reactions
- Sonogashira reactions
Packaging10 mL in glass bottle
50 mL in glass bottle
25 mL in Sure/Seal™ПараметрыQuality Level 100, reaction suitability reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingconcentration 1.0 M in toluene density 0.861 g/mL at 25 °C functional group phosphine SMILES string CC(C)(C)P(C(C)(C)C)C(C)(C)C InChI 1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3 Inchi Key BWHDROKFUHTORW-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07,GHS08 signalword Danger hcodes H225 - H304 - H314 - H336 - H361d - H373 - H412 pcodes P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 Target Organs Central nervous system Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F 39.2 °F Flash Point C 4 °C Узнать цену -
Tri-tert-butylphosphine solution 901441-25ML
Empirical Formula (Hill Notation): C12H27P CAS Number: 13716-12-6 Molecular Weight: 202.32 MDL number: MFCD00015006 ApplicationValuable ligand for several coupling reactions. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.Параметрыform liquid Quality Level 100, reaction suitability reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingconcentration 1.0 M in 2-methyltetrahydrofuran density 0.853 g/mL functional group phosphine SMILES string CC(C)(C)P(C(C)(C)C)C(C)(C)C InChI 1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3 InChI key BWHDROKFUHTORW-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07 signalword Danger hcodes H225 - H250 - H302 - H314 pcodes P210 - P231 - P280 - P305 + P351 + P338 - P370 + P378 - P422 Supp Hazards EUH019 RIDADR UN 2845 4.2 WGK Germany WGK 3 Flash Point F 6.8 °F Flash Point C -14 °C Узнать цену -
Triallylphosphine 336939-5G
Empirical Formula (Hill Notation): C9H15P Linear Formula: (CH2=CHCH2)3P CAS Number: 16523-89-0 Molecular Weight: 154.19 EC Number: 240-591-4 MDL number: MFCD00014956 PubChem Substance ID: 24860442 NACRES: NA.22 ApplicationCatalyst in Negishi phosphine ligand-containing palladium-catalyzed cross-coupling reactionsPackaging5 g in glass bottleПараметрыQuality Level 100, assay 95% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand bp 70 °C/10 mmHg (lit.) density 0.861 g/mL at 25 °C (lit.) functional group phosphine storage temp. 2-8°C SMILES string C=CCP(CC=C)CC=C InChI 1S/C9H15P/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2 Inchi Key GNFABDZKXNKQKN-UHFFFAOYSA-N
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, multi-purpose combination respirator cartridge (US), RIDADR UN 3334 WGK Germany WGK 3 Flash Point F 203.0 °F - closed cup Flash Point C 95 °C - closed cup Узнать цену -
Tributylphosphine
Empirical Formula (Hill Notation): C12H27P Linear Formula: [CH3(CH2)3]3P CAS Number: 998-40-3 Molecular Weight: 202.32 Beilstein/REAXYS Number: 1738261 EC Number: 213-651-2 MDL number: MFCD00009462 PubChem Substance ID: 329752742 NACRES: NA.22
Кат. номер 247049-PZ 247049-100G 247049-500G Packaging100, 500 g in Sure/Seal™ApplicationUsed with platinum (II) or (IV) in an intermolecular hydroamination of unactivated alkenes.
1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.Параметрыvapor density 9 (vs air) Quality Level 200, assay 97% autoignition temp. 392 °F reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Acetylations, reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Stille Couplingimpurities <1% TBP oxide, 5% TBP isomers refractive index n20/D 1.462 (lit.) bp 150 °C/50 mmHg (lit.) density 0.81 g/mL at 25 °C (lit.) functional group phosphine SMILES string CCCCP(CCCC)CCCC InChI 1S/C12H27P/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3 InChI key TUQOTMZNTHZOKS-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS05,GHS07,GHS09 signalword Danger hcodes H251 - H302 - H314 - H411 pcodes P235 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 Personal Protective Equipment Faceshields,, Gloves,, Goggles,, type ABEK (EN14387) respirator filter, RIDADR UN 3254 4.2 / PGI WGK Germany WGK 3 Узнать цену -
Tributylphosphine oxide
Empirical Formula (Hill Notation): C12H27OP Linear Formula: [CH3(CH2)3]3P(O) CAS Number: 814-29-9 Molecular Weight: 218.32 EC Number: 212-394-3 MDL number: MFCD00002082 PubChem Substance ID: 24850419 NACRES: NA.22
Кат. номер 172766-25G 172766-5G ПараметрыQuality Level 100, assay 95% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand bp 150 °C/1.5 mmHg (lit.) mp 64-69 °C (lit.) functional group phosphine SMILES string CCCCP(=O)(CCCC)CCCC InChI 1S/C12H27OP/c1-4-7-10-14(13,11-8-5-2)12-9-6-3/h4-12H2,1-3H3 Inchi Key MNZAKDODWSQONA-UHFFFAOYSA-N
Safety Informationpictograms GHS05,GHS07 signalword Danger hcodes H302 + H312 + H332 - H314 pcodes P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN 1759 8 / PGII WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tributylphosphine tetrafluoroborate
Empirical Formula (Hill Notation): C12H28BF4P Linear Formula: [CH3(CH2)3]3P · HBF4 CAS Number: 113978-91-9 Molecular Weight: 290.13 MDL number: MFCD05664257 PubChem Substance ID: 24880864 NACRES: NA.22
Кат. номер 576492-5G 576492-1G General descriptionMay contain approximately 5% of other butyl isomers.Packaging5 g in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand mp 50-53 °C (lit.) functional group phosphine SMILES string F[B-](F)(F)F.[H][P+](CCCC)(CCCC)CCCC InChI 1S/C12H27P.BF4/c1-4-7-10-13(11-8-5-2)12-9-6-3;2-1(3,4)5/h4-12H2,1-3H3;/q;-1/p+1 InChI key NCHAZLRRIGGCER-UHFFFAOYSA-O
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tricyclohexylphosphine
Empirical Formula (Hill Notation): C18H33P Linear Formula: (C6H11)3P CAS Number: 2622-14-2 Molecular Weight: 280.43 EC Number: 220-069-2 MDL number: MFCD00003853 PubChem Substance ID: 24855848 NACRES: NA.22
Кат. номер 261971-250G 261971-5G 261971-25G 261971-1G Packaging1, 5, 25, 250 g in glass bottleApplicationLigand used in the Pd-catalyzed coupling of malononitrile with aryl halides. Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.
This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.ПараметрыQuality Level 100 reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Hiyama Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingmp 81-83 °C (lit.) functional group phosphine SMILES string C1CCC(CC1)P(C2CCCCC2)C3CCCCC3 InChI 1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2 InChI key WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Safety InformationPictograms GHS07 Signal Word Warning Hazard Statements H315 - H319 - H335 Precautionary Statements P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 Target Organs Respiratory system Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves RIDADR NONH for all modes of transport WGK Germany WGK 3 Узнать цену -
Tricyclohexylphosphine solution
Empirical Formula (Hill Notation): C18H33P Linear Formula: (C6H11)3P CAS Number: 2622-14-2 Molecular Weight: 280.43 Beilstein/REAXYS Number: 957171 MDL number: MFCD00003853 PubChem Substance ID: 24869033 NACRES: NA.22
Кат. номер 455164-100G 455164-500G ApplicationCatalyst for:- Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
- Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
- Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
- Synthesis of (-)-Exiguolide and its analogues
- Allylation of zinc enolates
Reagent used as a ligand for a range of metal-catalyzed organic transformations.Packaging100, 500 g in glass bottleПараметрыQuality Level 100, reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsconcentration 20 wt. % in toluene functional group phosphine SMILES string C1CCC(CC1)P(C2CCCCC2)C3CCCCC3 InChI 1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2 Inchi Key WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07,GHS08 signalword Danger hcodes H225 - H304 - H315 - H319 - H335 - H336 - H361d - H373 - H412 pcodes P210 - P273 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 - P331 Target Organs Central nervous system Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN1294 - class 3 - PG 2 - Toluene, solution WGK Germany WGK 3 Flash Point F 51.8 °F - closed cup Flash Point C 11 °C - closed cup Узнать цену -
Tricyclohexylphosphine solution 592285-100ML
Empirical Formula (Hill Notation): C18H33P Linear Formula: (C6H11)3P CAS Number: 2622-14-2 Molecular Weight: 280.43 Beilstein/REAXYS Number: 957171 MDL number: MFCD00003853 PubChem Substance ID: 24881380 NACRES: NA.22 ApplicationCatalyst for:- Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
- Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
- Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
- Synthesis of (-)-Exiguolide and its analogues
- Allylation of zinc enolates
Packaging100 mL in Sure/Seal™ПараметрыQuality Level 100, reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsconcentration 1 M in toluene density 0.901 g/mL at 25 °C functional group phosphine SMILES string C1CCC(CC1)P(C2CCCCC2)C3CCCCC3 InChI 1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2 Inchi Key WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Safety Informationpictograms GHS02,GHS07,GHS08 signalword Danger hcodes H225 - H304 - H315 - H319 - H335 - H336 - H361d - H373 - H412 pcodes P210 - P273 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 - P331 Target Organs Central nervous system Personal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type ABEK (EN14387) respirator filter, RIDADR UN1294 - class 3 - PG 2 - Toluene, solution WGK Germany WGK 3 Flash Point F 39.2 °F - closed cup Flash Point C 4 °C - closed cup Узнать цену -
Tricyclohexylphosphine tetrafluoroborate
Empirical Formula (Hill Notation): C18H33P · HBF4 Linear Formula: (C6H11)3P · HBF4 CAS Number: 58656-04-5 Molecular Weight: 368.24 MDL number: MFCD03840580 PubChem Substance ID: 24882425 NACRES: NA.22
Кат. номер 631493-1G 631493-5G General descriptionTricyclohexylphosphine tetrafluoroborate (PCy3·HBF4) is an inexpensive and air-stable phosphine ligand, commonly used in cross-coupling reactions.ApplicationTricyclohexylphosphine tetrafluoroborate may be used in the following processes:- As a ligand for preparing C-homoaporphine alkaloids via microwave-assisted direct-arylation.
- To synthesize poly-[9,9-bis(3-propylamide-2-methylpropyl sulfonic acid) fluorene]-co-(4,4-diphenyl) (PFDBSO3H), which can be employed as a template and doping agent for enhancing the conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) films.
- To improve the reactivity of palladium-catalyzed Suzuki-Miyaura cross-coupling reaction between MIDA boronates and less activated alkenyl tosylates.
Used with Ru(cod)Cl dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.Packaging1, 5 g in glass bottleПараметрыQuality Level 100, assay 97% reaction suitability reaction type: Cross Couplings, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Couplingmp 164 °C (lit.) functional group phosphine SMILES string F[B-](F)(F)F.[H][P+](C1CCCCC1)(C2CCCCC2)C3CCCCC3 InChI 1S/C18H33P.BF4/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1(3,4)5/h16-18H,1-15H2;/q;-1/p+1 InChI key MYSMMEUXKHJYKH-UHFFFAOYSA-O
Safety InformationPersonal Protective Equipment Eyeshields,, Gloves,, type N95 (US), RIDADR NONH for all modes of transport WGK Germany WGK 3 Flash Point F Not applicable Flash Point C Not applicable Узнать цену -
Tricyclopentylphosphine tetrafluoroborate 673951-1G
Empirical Formula (Hill Notation): C15H28BF4P CAS Number: 610756-04-2 Molecular Weight: 326.16 MDL number: MFCD08705305 PubChem Substance ID: 24885190 General descriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here, for more information.ApplicationCatalyst for alkane C-H arylation from aryl chlorides
Used with Ru(cod)Cl dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.
Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen,Packaging1 g in poly bottleПараметрыQuality Level 100, assay 95% reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplingsgreener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry,.mp 246-264 °C functional group phosphine SMILES string F[B-](F)(F)F.C1CCC(C1)[PH+](C2CCCC2)C3CCCC3 InChI 1S/C15H27P.BF4/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;2-1(3,4)5/h13-15H,1-12H2;/q;-1/p+1 Inchi Key KTDMVANQORSVPI-UHFFFAOYSA-O
Safety InformationPersonal Protective Equipment Eyeshields,, Faceshields,, Gloves,, type P1 (EN143) respirator filter,, type P3 (EN 143) respirator cartridges, RIDADR UN 3261 8 / PGII Flash Point F Not applicable Flash Point C Not applicable Узнать цену
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